The Role of One- and Two-Electron Transfer Reactions in Forming Thermodynamically Unstable Intermediates as Barriers in Multi-Electron Redox Reactions

Anschutz P, Sundby B, Lefrançois L, Luther GW, Mucci A (2000) Interactions between metal oxides and species of nitrogen and iodine in bioturbated marine sediments. Geochim Cosmochim Acta 64:2751–2763

Armstrong FA (2008) Why did nature choose manganese to make oxygen? Philos Trans R Soc B Biol Sci 363:1263–1270

Barnese K, Gralla EB, Cabelli DE, Valentine JS (2008) Manganous phosphate acts as a superoxide dismutase. J Am Chem Soc 130:4604–4606

Beal EJ, House CH, Orphan VJ (2009) Manganese- and iron-dependent marine methane oxidation. Science 325:184–187

Britto DT, Kronzucker HJ (2002) NH4 + toxicity in higher plants: a critical review. J Plant Physiol 159:567–584

Cotton FA, Wilkinson G (1999) Advanced inorganic chemistry. Wiley, New York

Das S, Incarvito CD, Crabtree RH, Brudvig GW (2006) Molecular recognition in the selective oxygenation of saturated C–H bonds by a dimanganese catalyst. Science 312:1941–1943

dos Santos Afonso M, Stumm W (1992) Reductive dissolution of iron(III) (hydr)oxides by hydrogen sulfide. Langmuir 8:1671–1675

Drath M, Kloft N, Batschauer A, Marin K, Novak J, Forchhammer K (2008) Ammonia triggers photodamage of photosystem II in the cyanobacterium Synechocystis sp. Strain PCC 6803. Plant Physiol 147:206–215

Duckworth OW, Sposito G (2005) Siderophore—Manganese(III) interactions. I. Air oxidation of manganese(II) promoted by desferrioxamine B. Environ Sci Technol 39:6037–6044

Ehrlich S, Butler I, Halicz L, Rickard D, Oldroyd A, Matthews A (2004) Experimental study of the copper isotope fractionation between aqueous Cu(II) and covellite, CuS. Chem Geol 209:259–269

Ewing G (1975) Structure and properties of van der Waals molecules. Acc Chem Res 8:185–192

Froelich PN, Klinkhammer GP, Bender ML, Luedtke NA, Heath GR, Cullen D, Dauphin P, Hammond D, Hartman B, Maynard V (1979) Early oxidation of organic matter in pelagic sediments of the eastern equatorial Atlantic: suboxic diagenesis. Geochim Cosmochim Acta 43:1075–1090

Gimarc BM (1979) Molecular structure and bonding: the qualitative molecular orbital approach. Academic Press, New York

González-Davila M, Santana-Casiano JM, Miller FJ (2005) Oxidation of iron (II) nanomolar with H2O2 in seawater. Geochim Cosmochim Acta 69:83–93

Hakemian AS, Rosenzweig AC (2007) The biochemistry of methane oxidation. Annu Rev Biochem 76:223–241

Hansen HCB, Boorgaard OK, Sorensen J (1994) Evaluation of the free energy of formation of Fe(II)-Fe(II) hydroxide-sulphate (green rust) and its reduction of nitrite. Geochim Cosmochim Acta 58:2599–2608

Herszage J, dos Santos Afonso M (2003) Mechanism of hydrogen sulfide oxidation by manganese(IV) oxide in aqueous solutions. Langmuir 19:9684–9692

Hulth S, Aller RC, Canfield DE, Dalsgaard T, Engström P, Gilbert F, Sundbäck K, Thamdrup B (2005) Nitrogen removal in marine environments: recent finding and future research challenges. Mar Chem 94:125–145

Karlsson A, Parales JV, Parales RE, Gibson DT, Eklund H, Ramaswamy S (2003) Crystal structure of naphthalene dioxygenase: side-on biding of dioxygen to iron. Science 299:1039–1042

Keener WK, Russell SA, Arp DJ (1998) Kinetic characterization of the inactivation of ammonia monooxygenase in Nitrosomonas europaea by alkyne, aniline and cyclopropane derivatives. Biochim Biophys Acta 1388:373–385

Kostka JE, Luther GW, Nealson KH (1995) Chemical and biological reduction of Mn(III)-pyrophosphate complexes: potential importance of dissolved Mn(III) as an environmental oxidant. Geochimica Cosmochimica Acta 59:885–894

Kuypers MMM, Slieker AO, Lavik G, Schmid M, Jorgensen BB, Kuenen JG, Sinninghe Damsté JS, Strous M, Jetten MSM (2003) Anaerobic ammonium oxidation by anammox bacteria in the Black Sea. Nature 422:608–611

Laha S, Luthy RG (1990) Oxidation of aniline and other primary aromatic amines by manganese dioxide. Environ Sci Technol 24:363–373

Luther GW (2005) Manganese(II) oxidation and Mn(IV) reduction in the environment—two-one-electron transfer steps versus a single two-electron step. Geomicrobiol J 22:195–203

Luther GW, Ferdelman TG (1993) Voltammetric characterization of iron (II) sulfide complexes in laboratory solutions and in marine waters and porewaters. Environ Sci Technol 27:1154–1163

Luther GW, Popp JI (2002) Kinetics of the abiotic reduction of polymeric manganese dioxide by nitrite: an anaerobic nitrification reaction. Aquat Geochem 8:15–36

Luther GW, Kostka JE, Church TM, Sulzberger B, Stumm W (1992) Seasonal iron cycling in the salt marsh sedimentary environment: the importance of ligand complexes with Fe(II) and Fe(III) in the dissolution of Fe(III) minerals and pyrite, respectively. Mar Chem 40:81–103

Luther GW, Wu J, Cullen J (1995) Redox chemistry of iodine in seawater: frontier molecular orbital theory considerations, In: Huang CP, O’Melia CR, Morgan JJ (eds) Aquatic chemistry: interfacial and interspecies processes, Advances in Chemistry Series, American Chemical Society, Washington, DC, vol 244, 135–155

Luther GW, Sundby B, Lewis BL, Brendel PJ, Silverberg N (1997) Interactions of manganese with the nitrogen cycle: alternative pathways to dinitrogen. Geochim Cosmochim Acta 61:4043–4052

Luther GW, Theberge SM, Rozan TF, Rickard D, Rowlands C, Oldroyd A (2002) Aqueous copper sulfide clusters as intermediates during copper sulfide formation. Environ Sci Technol 36:394–402

Maloy JT (1985) Nitrogen chemistry. In: Bard AJ, Parsons R, Jordan J (eds) Standard potentials in aqueous solution, 1st edn. M. Dekker, New York, pp 127–139

Martell AE, Motekaitis RJ, Chen D, Hancock RD, McManus D (1996) Selection of new Fe(III)/Fe(II) chelating agents as catalysts for the oxidation of hydrogen sulfide to sulfur by air. Can J Chem 74:1872–1879

Millero FJ, Sotonlongo S, Izaguirre M (1987a) The oxidation kinetics of Fe(II) in seawater. Geochim Cosmochim Acta 51:793–801

Millero FJ, Hubinger S, Fernandez M, Garnett S (1987b) Oxidation of H2S in seawater as a function of temperature, pH, and ionic strength. Environ Sci Technol 21:439–443

Morgan JJ (2005) Kinetics of reaction between O2 and Mn(II) species in aqueous solution. Geochim Cosmochim Acta 69:35–48

Nico PS, Anastasio C, Zasoski RJ (2002) Rapid photo-oxidation of Mn(II) by humic substances. Geochim Cosmochim Acta 66:4047–4056

Postma D (1990) Kinetics of nitrate reduction by detrital Fe(II)-silicates. Geochim Cosmochim Acta 54:903–908

Rickard D, Luther GW (2007) Chemistry of iron sulfides. Chem Rev 107:514–562

Rohde JU, In JH, Lim MH, Brennessel WW, Bukowski MR, Stubna A, Munck E, Nam W, Que L (2003) Crystallographic and spectroscopic characterization of a nonheme Fe(IV) = O complex. Science 299:1037–1039

Shiemke AK, Arp DJ, Sayavedra-Soto LA (2004) Inhibition of membrane-bound methane monooxygenase and ammonia monooxygenase by diphenyliodonium: implications for electron transfer. J Bacteriol 186:928–937

Shu L, Nesheim JC, Kauffmann K, Münck E, Lipscomb JD, Que L (1997) An Fe 2 IV O2 diamond core structure for the key intermediate Q of methane monooxygenase. Science 275:515–518

Stanbury D (1989) Reduction potentials involving inorganic free radicals in aqueous solution. In: Sykes AG (ed) Advances in inorganic chemistry, vol 33. Academic Press, New York, pp 69–138

Straub KL, Benz M, Schink B, Widdel F (1996) Anaerobic, nitrate-dependent microbial oxidation of ferrous iron. Appl Environ Microbiol 62:1458–1460

Stumm W, Morgan JJ (1996) Aquatic chemistry, 3rd edn. Wiley, New York

Suslick KS, Watson RA (1991) Photochemical reduction of nitrate and nitrite by manganese and iron porphyrins. Inorg Chem 30:912–919

Tebo BM, Bargar JR, Clement BG, Dick GJ, Murray KJ, Parker D, Verity R, Webb SM (2004) Biogenic manganese oxides: properties and mechanisms of formation. Annu Rev Earth Planet Sci 32:287–328

Trouwborst RE, Clement BG, Tebo BM, Glazer BT, Luther GW (2006) Soluble Mn(III) in suboxic zones. Science 313:1955–1957

Vazquez FG, Zhang J, Millero FJ (1989) Effect of metals on the rate of the oxidation of H2S in seawater. Geophys Res Lett 16:1363–1366

Von Langen PJ, Johnson KS, Coale KH, Elrod VA (1997) Oxidation kinetics of manganese (II) in seawater at nanomolar concentration. Geochim Cosmochim Acta 61:4945–4954

Wallar BJ, Lipscomb JD (1996) Dioxygen activation by enzymes containing binuclear non-heme iron clusters. Chem Rev 96:2625–2657

Wanat A, Schneppensieper T, Stochel G, van Eldik R, Bill E, Wieghardt K (2002) Kinetics, mechanism, and spectroscopy of the reversible binding of nitric oxide to aquated iron(II): an undergraduate text book reaction revisited. Inorg Chem 41:4–10

Wehrli B (1990) Redox reactions of metal ions at mineral surfaces. In: Stumm W (ed) Aquatic chemical kinetics” Chapter 11. Wiley, New York, pp 311–336

Whitaker M, Bergmann D, Arciero D, Hooper AB (2000) Electron transfer during the oxidation of ammonia by the chemolithotrophic bacterium Nitrosomonas europaea (2000). Biochim Biophys Acta 1459:346–355

Yao W, Millero FJ (1993) The rate of sulfide oxidation by δMnO2 in seawater. Geochim Cosmochim Acta 57:3359–3365

Yao W, Millero FJ (1996) Oxidation of hydrogen sulfide by hydrous Fe(III) oxides in seawater. Mar Chem 52:1–16