The O-V (Oxygen-Vanadium) system

H. A. Wriedt1
1Pittsburgh

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W.H. Zachariasen, “The Crystal Structure of Sesquioxides and Compounds of the TypeABO3,”Skrifter, Norske Videnskaps-Akad. Oslo, I, Mat.-Nat. Kl. (4), 165 p (1928). in German. (Crys Structure; Experimental)

W. Klemm and L. Grimm, “Knowledge of the Lower Vanadium Oxides,”Z. Anorg. Allg. Chem., 250, 42–55 (1942) in German. (Equi Diagram; Experimental)

F. Aebi, “Phase Investigations in the System Vanadium-Oxygen and the Crystal Structure of V12O26,”Helv. Chim. Acta, 31(1), 8–21 (1948) in German. (Crys Structure; Experimental)

A. Byström, K.-A. Wilhelmi, and O. Brotzen, “Vanadium Pentoxide—A Compound with Five-Coordinated Vanadium Atoms,”Acta Chem. Scand., 4, 1119–1130 (1950). (Crys Structure; Experimental)

A.U. Seybolt and H.T. Sumsion, “Vanadium-Oxygen Solid Solutions,”Trans. AIME, 197, 292–299 (1953). (Equi Diagram; Experimental; #)

W. Rostoker and A.S. Yamamoto, “A Contribution to the Vanadium-Oxygen Phase Diagram,”Trans. ASM, 47, 1003–1017 (1955). (Equi Diagram; Experimental; #)

A. Burdese, “Research on the Oxide Compounds of Vanadium,”Ann. Chim., 47, 785–796 (1957) in Italian. (Equi Diagram; Experimental)

E. Vol’f, S.S. Tolkachev, and I.I. Kozhina, “X-Ray Diffraction Investigation of Peroxides of Titanium and Vanadium”,Vestn. Leningr. Univ., (10),Fiz. Khim., (2), 87–92 (1959) in Russian. (Crys Structure; Experimental).

H.G. Bachmann, F.R. Ahmed, and W.H. Barnes, “The Crystal Structure of Vanadium Pentoxide,”Z. Kristallogr., 115, 110–131 (1961). (Crys Structure; Experimental)

S. Westman, “On the Lower Oxides of Vanadium,”Acta Chem. Scand., 17(3), 749–752 (1963). (Equi Diagram; Experimental)

J. Haemers, “On the Electrical Conductivity of V2O3,”Compt. Rend. Acad. Sci. (Paris), 259, 3740–3743 (1964). (Equi Diagram; Experimental)

R. Roy, S. Kachi, G.J. McCarthy, O. Muller, and W.B. White, First Quarterly Report on Crystal Chemistry Studies, Pennsylvania State Univ., Mater. Res. Lab., 24 Aug 1965; Clearinghouse Fed. Sci. Tech. Inf. Rep. AD627406 (1966). (Equi Diagram; Experimental)

J. Tudo and G. Tridot, “On the System Vanadium-Oxygen: Existence of a New Phase with the Composition VO2.33,”Compt. Rend. Acad. Sci. (Paris), 261, 2911–2914 (1965) in French. (Equi Diagram; Experimental)

S. Kachi and R. Roy, “Phase Equilibrium Studies and Transitions in the System V2O3-V2O5,” Second Quarterly Report on Crystal Chemistry Studies, Pennsylvania State Univ., Mater. Res. Lab., Jan 1966; Clearinghouse Fed. Sci. Tech. Inf. Rep. AD627468 (1966). (Equi Diagram; Experimental)

T. Toda, K. Kosuge, and S. Kachi, “Phase Diagram of the System V6O13, V3O7, and V2O5,”Nippon Kagaku Zasshi, 87, 1311–1314 (1966) in Japanese. (Equi Diagram; Experimental; #)

T. Katsura and M. Hasegawa, “Equilibria in the V2O3-VO2 System at 1600 °K,”Bull. Chem. Soc. Jpn., 40(3), 561–569 (1967). (Equi Diagram; Experimental)

T.N. Kennedy, R. Hakim, and J.D. Mackenzie, “Preparation and Properties of Crystalline and Amorphous Vanadium Pentoxide,”Mater. Res. Bull., 2, 193–201 (1967). (Crys Structure; Experimental)

F. Théobald, R. Cabala, and J. Bernard, “On the Preparation and Properties of New Phases of the Vanadium-Oxygen System with Compositions near V12O26,”Compt. Rend. Acad. Sci. (Paris) C, 266, 1534–1537 (1968) in French. (Meta Phases; Experimental)

M. Cambini, M. Heerschap, and R. Gevers, “On the First Vanadium-Oxygen Suboxide Phase (VO x ) by Means of Electron Microscopy, Electron Diffraction, and X-Ray Diffraction,”Mater. Res. Bull., 4, 633–642 (1969). (Equi Diagram; Experimental)

J.S. Anderson and A.S. Khan, “Phase Equilibria in the Vanadium-Oxygen System,”J. Less-Common Met., 22, 209–218 (1970). (Equi Diagram; Experimental)

B. Anderson and J. Gjønnes, “Ordered Phases in the Monoxide Region of the Vanadium-Oxygen System,”Acta Chem. Scand., 24(6), 2250–2252 (1970). (Crys Structure; Experimental)

M.D. Banus and T.B. Reed, “Structural, Electrical, and Magnetic Properties of Vacancy Stabilized Cubic ‘TiO’ and ‘VO,’”The Chemistry of Extended Defects in Non-Metallic Solids, L. Eyring and M. O’Keeffe, Ed., American Elsevier, New York, 488–521 (1970). (Crys Structure; Experimental)

P.D. Dernier, “The Crystal Structure of V2O3 and (V0.962Cr0.038)2O3 near the Metal-Insulator Transition,”J. Phys. Chem. Solids, 31, 2569–2575 (1970). (Crys Structure; Experimental)

J.L. Henry, S.A. O’Hare, R.A. McCune, and M.P. Krug, “The Vanadium-Oxygen System: Phase Relations in the Vanadium-Rich Region below 1200 °C,”J. Less-Common Met., 21, 115–135 (1970). (Equi Diagram, Crys Structure; Experimental; #)

D.B. McWhan and J.P. Remeika, “Metal-Insulator Transition in (V1-x Cr x )2O3,”Phys. Rev. B, 2(9), 3734–3750 (1970). (Crys Structure; Experimental)

T. Sata and Y. Ito, “Reduction of V2O5 under Hydrogen Atmosphere and Phase Relations of the V2O5-V2O3 System,”Bull. Tokyo Inst. Tech., (98), 1–13 (1970). (Equi Diagram; Experimental)

M. Wakihara and T. Katsura, “Thermodynamic Properties of the V2O3-V4O7 System at Temperatures from 1400 to 1700 °K,”Metall. Trans., 1, 363–366 (1970). (Equi Diagram; Experimental)

K.-A. Wilhelmi and K. Waltersson, “On the Crystal Structure of a New Vanadium Oxide, V4O9,”Acta Chem. Scand., 24(9), 3409–3411 (1970). (Crys Structure; Experimental)

D.G. Alexander and O.N. Carlson, “The V-VO Phase System,”Metall. Trans., 2, 2805–2811 (1971). (Equi Diagram, Crys Structure; Experimental; #)

P.S. Bell and M.H. Lewis, “Non-Stoichiometric Vacancy Order in Vanadium Monoxide,”Phys. Status Solidi (a), 7, 431–439 (1971). (Equi Diagram; Experimental; #)

H. Reuther and G. Brauer, “On the Cubic Vanadium Monoxide,”Z. Anorg. Allg. Chem., 384, 155–159 (1971) in German. (Crys Structure; Experimental)

H. Suito and D.R. Gaskell, “The Thermodynamics of Melts in the System VO2-V2O5,”Metall. Trans., 2, 3299–3303 (1971). (Equi Diagram; Experimental)

K.-A. Wilhelmi, K. Waltersson, and L. Kihlborg, “A Refinement of the Crystal Structure of V6O13,”Acta Chem. Scand., 25, 2675–2687 (1971). (Crys Structure; Experimental)

T.V. Charlu and O.J. Kleppa, “High Temperature Combustion Calorimetry. II. Enthalpies of Formation of Vanadium Oxides,”High Temp. Sci., 5, 260–268 (1973). (Thermo; Experimental)

B.L. Chamberland, “New Defect Vanadium Dioxide Phases,”J. Solid State Chem., 7, 377–384 (1973). (Meta Phases; Experimental)

K. Hiraga and M. Hirabayashi, “Long Range Ordering of Interstitial Oxygen in Vanadium near V4O,”J. Phys. Soc. Jpn., 34(4), 965–972 (1973). (Equi Diagram, Crys Structure; Experimental)

S. Kachi, K. Kosuge, and H. Okinaka, “Metal-Insulator Transition in V n O2n−1,”J. Solid State Chem., 6, 258–270 (1973). (Crys Structure; Review)

I. Kawada, M. Nakano, M. Saeki, M. Ishii, N. Kimizuka, and M. Nakahira, “Phase Transition of V6O13,”J. Less-Common Met., 32, 171–172 (1973). (Crys Structure; Experimental)

N.P. Slyusar’, A.D. Krivorotenko, E.N. Fomichev, A.A. Kalashnik, and V.P. Bondarenko, “An Experimental Study of the Enthalpies of Vanadium Trioxide (V2O3) and Pentoxide (V2O5) at High Temperatures,”Zh. Fiz. Khim., 47(10), 2706 (1973) in Russian; TR:Russ. J. Phys. Chem., 47(10), 1525 (1973). (Thermo; Experimental)

M. Hirabayashi, S. Yamaguchi, H. Asano, and K. Hiraga, “Order-Disorder Transformations of Interstitial Solutes in Transition Metals of IV and V Groups,”Order-Disorder Transformations in Alloys, H. Warlimont, Ed., Springer Verlag, Berlin, 266–305 (1974). (Crys Structure; Review)

J. Muller and J.C. Joubert, “Synthesis in Hydrothermal Conditions and Characterization of the Vanadium Oxyhydride V3+OOH and of a New Allotropic Variety of the Dioxide VO2,”J. Solid State Chem., 11, 79–87 (1974) in French. (Meta Phases; Experimental)

K. Waltersson, B. Forslund, K.-A. Wilhelmi, S. Andersson, and J. Galy, “The Crystal Structure of V3O7,”Acta Crystallogr. B, 30, 2644–2652 (1974). (Crys Structure; Experimental)

D. Watanabe, B. Andersson, J. Gjöones, and O. Terasaki, “Determination of Structure Factors of Disordered Vanadium Monoxide Crystals by the Intersecting Kikuchi-Line and Critical-Voltage Methods,”Acta Crystallogr. A, 30, 772–776 (1974). (Crys Structure; Experimental)

E. Fromm and R. Kirchheim, “EMF Measurements in the Oxygen Systems of the Va-Metals with a ThO2-Y2O3 Solid Electrolyte.”Z. Metallkd., 66, 144–150 (1975) in German. (Equi Diagram, Thermo; Experimental)

K. Hiraga and M. Hirabayashi, “Crystal Structure of Vanadium Suboxide V2O1 ± x,”J. Solid State Chem., 14, 219–228 (1975). (Crys Structure; Experimental)

K. Hiraga and M. Hirabayashi, “Crystal Structure and Phase Transformation of the Vanadium-Oxygen System near VO0.1,”Trans Jpn. Inst. Met., 16, 431–440 (1975). (Equi Diagram, Crys Structure; Experimental)

H. Oppermann, W. Reichelt, and E. Wolf, “Thermal Analysis in the System VO2-VO2.5,”Thermal Analysis, 1, Proc. Fourth Int. Conf. Therm. Anal., 1974, I. Buzas, Ed., 403–413 (1975). (Equi Diagram; Experimental)

H. Oppermann, W. Reichelt, V. Gerlach, E. Wolf, W. Brückner, W. Moldenauer, and H. Wich, “The Range of Homogeneity of VO2 and the Influence of the Composition of the Physical Properties. I. The Preparation of Defined VO2 and the Determination of Its Phase Boundaries,”Phys. Status Solidi (a), 28, 439–446 (1975). (Equi Diagram; Experimental)

I.A. Vasil’eva, I.S. Sukhushina, and R.F. Balabaeva, “Thermodynamic Properties of V n O2n−1 (n=4 to 9) at High Temperatures and at 298.15 K,”J. Chem. Thermodyn., 7, 319–328 (1975). (Thermo; Experimental)

H. Horiuchi, N. Morimoto, and M. Tokonami, “Crystal Structures of V n O2n−1(2 ≤n ≤ 7),”J. Solid State Chem., 17, 407–424 (1976). (Crys Structure; Experimental)

G.L. Steckel and C.J. Altstetter, “Solubility and Thermodynamic Properties of Vanadium-Oxygen Solid Solutions,”Acta Metall., 24, 1131–1136 (1976). (Equi Diagram, Thermo; Experimental)

F. Théobald, R. Cabala, and J. Bernard, “Test of the Structure of VO2(B),”J. Solid State Chem., 17, 431–438 (1976) in French. (Meta Phases; Experimental)

I.A. Vasil’eva and Zh.V. Granovskaya, “Thermodynamic Properties in the Region of Homogeneity of Vanadium Monoxides and the Oxide VO0.54 in the Range 1173–1373 K and at 298 K,”Zh. Fiz. Khim., 50(6), 1450–1453 (1976) in Russian; TR:Russ. J. Phys. Chem., 50(6), 876–878 (1976). (Equi Diagram; Experimental)

R. Dziembaj and J. Piwowarczyk, “Oxygen Equilibrium Pressure above the V2O5−x Oxide System at 600 °C (x < 0.43),”J. Solid State Chem., 21, 387–392 (1977). (Thermo Diagram; Experimental)

G. Grymonprez, L. Fiermans, and J. Vennik, “Structural Properties of Vanadium Oxides,”Acta Crystallogr. A, 33, 834–837 (1977). (Meta Phases; Experimental)

H. Oppermann, W. Reichelt, G. Krabbes, and E. Wolf, “On the Transport System V-O-Te-Cl and the Transport Behavior of the Vanadium Oxides with TeCl4. (II) The Chemical Transport of the Magnéli Phases VnO2n−1, of V6O11, and of V2O5,”Krist. Tech., 12(9), 919–928 (1977) in German. (Equi Diagram; Experimental)

J.R. Gannon and R.J.D. Tilley, “Microstructures Occurring in Reduced Vanadium Dioxide,”J. Solid State Chem., 25, 301–307 (1978). (Equi Diagram; Experimental)

D. Kucharczyk and T. Niklewski, “Accurate X-Ray Determination of the Lattice Parameters and the Thermal Expansion Coefficients of VO2 near the Transition Temperature,”J. Appl. Crystallogr., 12, 370–373 (1979). (Crys Structure; Experimental)

J.F. Smith, “Analysis of the Thermodynamics and Phase Relationships of a Portion of the Vanadium-Oxygen System,” Iowa State Univ. Sci. Technol., Rep. IS-M-212, CONF-790560-1 (1979). (Thermo; Review; #)

M.P. Arbuzov, N.T. Bugaichuk, and B.V. Khaenko, “Crystal-Geometrical Characteristics of Phases of the Series ∼ V4O-V2O,” VINITI Dep. Pub. No. 3127–80 (1980) in Russian. (Crys Structure; Review)

S. Åsbrink, “The Crystal Structure of and Valency Distribution in the Low-Temperature Modification of V3O5. The Decisive Importance of a Few Very Weak Reflexions in a Crystal-Structure Determination,”Acta Crystallogr. B, 36, 1332–1339 (1980). (Crys Structure; Experimental)

I.A. Vasil’eva and I.S. Sukhushina, “Thermodynamic Properties of the Oxide V3O7,”Zh. Fiz. Khim., 54(9), 2251–2254 (1980) in Russian; TR:Russ. J. Phys. Chem., 54(9), 1284–1286 (1980). (Thermo; Experimental)

M.P. Arbuzov, N.T. Bugaichuk, and B.V. Khaenko, “Phase Relations in Alloys Based on Vanadium Monoxide,”Izv. Akad. Nauk SSSR, Neorg. Mater., 17(3), 448–451 (1981) in Russian; TR:Inorg. Mater., 17(3), 300–302 (1981). (Equi Diagram; Experimental; #)

H. Kuwamoto, N. Otsuka, and H. Sato, “Growth of Single Phase, Single Crystals of V9O17,”J. Solid State Chem., 36, 133–138 (1981). (Crys Structure; Experimental)

S.-H. Hong and S. Åsbrink, “The Structure of the High-Temperature Modification of V3O5 at 458 K,”Acta Crystallogr. B, 38, 713–719 (1982). (Crys Structure; Experimental)

M.H. Rand, “The V-V2O3”, Comm. Eur. Commun., Rep. EUR 7820, Pt. 2, 16-1-16-20 (1982) (Equi Diagram, Thermo; Review).

I.A. Vasil’eva and A.N. Seregin, “Partial Thermodynamic Properties of Vanadium Oxides in the Homogeneity Region of the γ- and δ-Phases,”Zh. Fiz. Khim., 56(6), 1374–1377 (1982) in Russian; TR:Russ. J. Phys. Chem., 56(6), 837–839 (1982). (Thermo; Experimental)

I.A. Vasil’eva and A.N. Seregin, “Thermodynamic Formation Functions of Oxides in the V-VO System,”Zh. Fiz. Khim., 57(7), 1624–1627 (1983) in Russian; TR:Russ. J. Phys. Chem., 57(7), 987–988 (1983). (Thermo; Theory)

M.J. Ferrante and R.V. Mrazek, “High-Temperature Relative Enthalpies of V2O5,” U.S. Bur. Mines Rep. Inv. RI9039 (1986). (Thermo; Experimental)