The Large-Scale Synthesis of Vinyl-Functionalized Silicon Quantum Dot and Its Application in Miniemulsion Polymerization

Journal of Nanomaterials - Tập 2016 - Trang 1-7 - 2016
Mai Xuân Dũng1, Quang-Bac Hoang1
1Department of Chemistry, Hanoi Pedagogical University No. 2, 32 Nguyen Van Linh, Xuan Hoa, Phuc Yen, Vinh Phuc, Vietnam

Tóm tắt

Stable luminescence, size-tunability, and biocompatibility encourage the deployment of Cd-free NPs into diverse biological applications. Here we report one-pot synthesis of blue-emitting and polymerizable silicon quantum dots (Si QDs) from which water-soluble Si QDs embedded polystyrene nanoparticles (SiQD@PS NPs) were prepared using a miniemulsion polymerization approach. The hydrodynamic size of NPs was controlled by KOH to oleic acid molar ratio. Studies on the photoluminescence properties of SiQD@PS NPs in different conditions reveal that they exhibit two-photon luminescence property and high stability against pH and UV exposure. These NPs add new size regime to the Si QDs based luminescent makers for bioimaging and therapy applications.

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