The Development of Polydimethysiloxane/ZnO–GO Antifouling Coatings

Journal of Cluster Science - Tập 33 - Trang 2407-2417 - 2021
Xiaoxue Zhang1, Erland Årstøl2, Marianne Nymark3, Maxime Fages-Lartaud2, Øyvind Mikkelsen1
1Department of Chemistry, Norwegian University of Science and Technology, Trondheim, Norway
2Department of Biotechnology and Food Science, Norwegian University of Science and Technology, Trondheim, Norway
3Department of Biology, Norwegian University of Science and Technology, Trondheim, Norway

Tóm tắt

The development of antifouling coating for sensor is desirable because the biofilm can shorten sensor’s life and cause inaccurate reading. In this study, a facile one-pot reaction was used to synthesized ZnO–graphene oxide (GO) (ZnO–GO) nanocomposites. Different amount of ZnO–GO was incorporated in the polydimethylsiloxane (PDMS) matrix respectively though a simple solution mixing method, in order to create PDMS/ZnO–GO nanocomposite (PZGO). The coating was obtained directly by spin coating of PZGO/tetrahydrofuran suspension. The hydrophobicity, surface roughness (Ra), surface free-energy (SFE) and nanoscale structure were investigated as antifouling factors. Antifouling tests were performed using two marine microorganisms, the cyanobacterium Synechococcus sp. Strain PCC 7002 and the diatom Phaeodactylum tricornutum. PZGO0.2 (mass ratio of ZnO–GO to PDMS: 0.2 wt%) displayed excellent antifouling property with 8.5% of Synechococcus sp. Strain PCC 7002 biofilm coverage, while PZGO0.1 (mass ratio of ZnO–GO to PDMS: 0.1 wt%) showed 2.4% P. tricornutum biofilm coverage. The antifouling property of the synthesized PZGO nanocomposite can be attributed to its high Ra and hydrophobicity which was caused by the good dispersion of ZnO–GO in PDMS matrix. This study suggests a potential of PZGO nanocomposite for sensor’s antifouling coating, which could contribute to improve sensor’s durability relating to biofouling in future.

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