The Cu−Si (Copper-Silicon) system

07Rud: E. Rudolfi, “Silicides of Copper,”Z. Anorg. Chem., 53, 216–227 (1907) in German. (Equi Diagram; Experimental; Indicates presence of a phase diagram)

19San: M.A. Sanfourche, “On the Alloys Copper-Silicon,”Rev. Metall., 16, 246–256 (1919) in French. (Equi Diagram; Experimental)

27Cor: M.G. Corson, “Merit in Copper-Silicon Alloys,”Iron Age, 119, 353–356 (1927). (Equi Diagram; Experimental)

28Mat: K. Matuyama, “On the Equilibrium Diagram of the Copper-Silicon System,”Sci. Rep. Res. Inst. Tohoku Univ., 17, 665–673 (1928). (Equi Diagram; Experimental)

28Smi: C.S. Smith, “The α Phase Boundary of the Copper-Silicon System,”J. Inst. Met., 40, 359–370 (1928). (Equi Diagram; Experimental)

Indicates key paper. 29Smi: C.S. Smith, “The Constitution of the Copper-Silicon System,”Trans. AIME, 83, 414–439 (1929). (Equi Diagram; Experimental)

31Arr: S. Arrhenius and A. Westgren, “X-Ray Analysis of Copper-Silicon Alloys,”Z. Phys. Chem., B14, 66–79 (1931) in German. (Crys Structure, Equi Diagram; Experimental)

31Cre: E. Crepaz, “On the Alloys Copper-Nickel-Silicon Rich in Copper,”Metall. Ital., 23, 711–716 (1931) in Italian. (Equi Diagram; Experimental)

31Iok: K. Iokibé, “On the Equilibrium Diagram of the Copper-Silicon System,”Kinzoku-no-Kenkyu, 8, 433–456 (1931) in Japanese. (Equi Diagram; Experimental)

31Kai: H.F. Kaiser and C.S. Barrett, “Lattice Parameters of Solid Solutions of Silicon in Copper,”Phys. Rev., 37, 1697 (1931). (Crys Structure; Experimental)

38Isa: T. Isawa, “On the Phase Diagram of the Copper-Rich Copper-Silicon System. I.,”J. Jpn. Inst. Met., 2, 400–409 (1938) in Japanese. (Crys Structure, Equi Diagram; Experimental)

38Oka: M. Okamoto, “On the κ Phase Adjacent to α Phase in the Copper-Silicon System,”Sci. Rep. Res. Inst. Tohoku Univ., 27, 155–161 (1938). (Equi Diagram; Experimental)

Indicates key paper. 40And: A.G.H. Andersen, “The Alpha Solubility Limit and the First Intermediary Phase in the Copper-Silicon System,”Trans. AIME, 137, 331–350 (1940). (Crys Structure, Equi Diagram; Experimental)

40Isa: T. Isawa, “On the Phase Diagram of the Copper-Rich Copper-Silicon System. II.,”J. Jpn. Inst. Met., 4, 398–404 (1940) in Japanese. (Crys Structure, Equi Diagram; Experimental)

Indicates key paper. 40Smi: C.S. Smith, “Constitution and Microstructure of Copper-Rich Silicon-Copper Alloys,”Trans. AIME, 137, 313–329 (1940). (Equi Diagram; Experimental)

40Tak: N. Takamoto, “Confirmation of α+γ Eutectoid in Cu−Si System,”J. Jpn. Inst. Met., 4, 198–200 (1940) in Japanese. (Equi Diagram; Experimental)

49Hib: W.R. Hibbard, Jr., G.H. Eichelman, Jr., and W.P. Saunders, “The Kappa Eutectoid Transformation in the Copper-Silicon System,”Trans. AIME, 180, 92–100 (1949). (Meta Phases, Equi Diagram; Experimental)

50Bar: C.S. Barrett, “Faults in the Structure of Copper-Silicon Alloys,”Trans. AIME, 188, 123–135 (1950). (Meta Phases; Experimental)

50Now: H. Nowotny and H. Bittner, “A Contribution to the Problem of Anomalous Diamagnetism,”Monatsh. Chem., 81, 887–906 (1950) in German. (Equi Diagram, Crys Structure; Experimental)

51Hof: W. Hofmann, J. Ziegler, and H. Hanemann, “Transformations in the System Copper-Silicon,”Z. Metallkd., 42, 55–57 (1951). (Meta Phases; Experimental)

53Hop: A.D. Hopkins, “The Copper-Silicon Eutectoid Transformation,”J. Inst. Met., 82, 163–165 (1953–54). (Meta Phases, Equi Diagram; Experimental)

53Thu: C.D. Thurmond and J.D. Struthers, “Equilibrium Thermochemistry of Solid and Liquid Alloys of Germanium and of Silicon. II.,”J. Phys. Chem., 57, 831–834 (1953). (Equi Diagram; Experimental)

56San: K. Sano, K. Okajima, and N. Okuda, “Thermodynamic Studies on the Formation of Molten Silicon Alloys Using the Galvanic Cells. (I) The System Copper-Silicon,”Mem. Fac. Eng. Nagoya Univ., 8, 127–130 (1956). (Thermo; Experimental)

56Str: J.D. Struthers, “Solubility and Diffusivity of Gold, Iron, and Copper in Silicon,”J. Appl. Phys., 27, 1560 (1956). (Equi Diagram; Experimental)

57Col: C.B. Collins and R.O. Carlson, “Properties of Silicon Doped with Iron or Copper,”Phys. Rev., 108, 1409–1414 (1957). (Equi Diagram; Experimental)

60Mim: G. Mima and M. Hasegawa, “The Diagram of Cu−Si−Zn Alloys III,”Technol. Rep. Osaka Univ., 10, 157–169 (1960). (Equi Diagram; Experimental)

60Thu: C.D. Thurmond and M. Kowalchik, “Germanium and Silicon Liquidus Curves,”Bell Sys. Tech. J., 39, 169–204 (1960). (Thermo; Theory)

60Tru: F.A. Trumbore, “Solid Solubilities of Impurity Elements in Germanium and Silicon,”Bell Sys. Tech. J., 39, 205–233 (1960). (Equi Diagram; Theory)

Indicates key paper. 61Dre: G.A. Dreyer and D.H. Polonis, “Aging of Supersaturated Alpha Phase in a Cu−Si Alloy,”Trans. Metall. Soc. AIME, 221, 1074–1080 (1961). (Meta Phases; Experimental)

61Fol: J.H. Foley and G.V. Raynor, “Lattice Spacings in the System Copper + Germanium + Silicon,”Trans. Faraday Soc., 57, 51–60 (1961). (Crys Structure; Experimental)

62Nik: Yu.P. Nikitin, “Activities of Silicon in the Copper-Silicon-Nickel Alloys,”Izv. V.U.Z. Tsvetn. Metall., 2(2), 56–57 (1962) in Russian. (Thermo; Experimental)

64Bow: P.J. Bowles, H.F. Ramstad, and F.D. Richardson, “Activities of Silicon in Metals and Alloys,”J. Iron Steel Inst., 202, 113–121 (1964). (Thermo; Experimental)

Indicates key paper. 64Hal: R.N. Hall and J.H. Racette, “Diffusion and Solubility of Copper in Extrinsic and Intrinsic Germanium, Silicon, and Gallium Arsenide,”J. Appl. Phys., 35, 379–397 (1964). (Equi Diagram; Experimental)

65Kas: M.B. Kasen, R. Taggart, and D.H. Polonis, “Some Aspects of the fcc→cph Transformation in a Cu−Si Alloys,”Can. Metall. Quart., 4, 269–278 (1965). (Meta Phases; Experimental)

66Dah: S.D. Dahlgren, W.F. Flanagan, and D.H. Polonis, “An X-Ray Study of the fcc→cph Transformation in a Cu−Si Alloy,”Trans. Metall. Soc. AIME, 236, 1071–1077 (1966). (Meta Phases; Experimental)

67Gro: J. Gronostajski, “Transformations Occurring in the Course of Isothermic Annealing of Undercooled Phases α and κ in Cu−Si Alloys,”Arch. Hutn., 12, 309–329 (1967) in Polish. (Meta Phases; Experimental)

67Kas: M.B. Kasen, R. Taggart, and D.H. Polonis, “Strain-Induced Phase Transformation in Metastable Cu−Si Solid Solutions,”Trans. ASM, 60, 144–151 (1967). (Meta Phases; Experimental)

Indicates key paper. 68Dor1: R.C. Dorward and J.S. Kirkaldy, “Thermodynamic Properties of Copper and Gold in Silicon and Germanium,”Trans. Metall. Soc. AIME, 242, 2055–2061 (1968). (Equi Diagram; Experimental)

68Dor2: R.C. Dorward and J.S. Kirkaldy, “Effect of Grain-Boundaries on the Solubility of Copper in Silicon,”J. Mat. Sci., 3, 502–506 (1968). (Equi Diagram; Experimental)

69Gie: B.C. Giessen, “Constitution of Non-Equilibrium Alloys after Rapid Quenching from the Melt,”Development in the Structural Chemistry of Alloy Phases, Plenum Press, New York, 227–281 (1969). (Meta Phases; Experimental)

Indicates key paper. 69Muk: K.P. Mukherjee, J. Bandyopadhyaya, and K.P. Gupta, “Phase Relationship and Crystal Structure of Intermediate Phases in the Cu−Si System in the Composition Range of 17 to 25 At.% Si,”Trans. Metall. Soc. AIME, 245, 2335–2338 (1969). (Crys Structure; Experimental)

70Bos: J.R. Bosnell and U.C. Voisey, “The Influence of Contact Materials on the Conduction Crystallization Temperature and Electrical Properties of Amorphous Germanium, Silicon and Boron Films,”Thin Solid Films, 6, 161–166 (1970). (Meta Phases; Experimental)

70Rao: M.V. Rao and W.A. Tiller, “Excess Free Energies in the Ge, Si and Ga Binary Systems—the α Parameter Approach”,J. Phys. Chem. Solids, 31, 191–198 (1970). (Thermo; Theory)

73Bar: I. Barin and O. Knacke,Thermochemical Properties of Inorganic Substances, Springer-Verlag, New York (1973). (Thermo; Compilation)

73Cha: T.G. Chart, “Thermochemical Data for Transition Metal-Silicon Systems,”High Temp.-High Pressures, 5, 241–252 (1973). (Thermo; Review)

73Pol: A.F. Polesya and V.N. Gudzenko, “Formation of Metastable Phases in the Cu−Ge and Cu−Si Alloys by Rapid Solidification from the Liquid State,”Izv. Akad. Nauk SSSR, Met., (5), 221–224 (1973) in Russian. (Meta Phases; Experimental)

75Lys: L.I. Lysak, B.I. Nikolin, and A.I. Ustinov, “Multilayer Martensitic γ′ Phase in the Cu−Si Alloys,”Dokl. Akad. Nauk SSSR, 222, 329–332 (1975) in Russian. (Meta Phases; Experimental)

76Bla: J.L. Blattner, “The Relative Ion Current Technique for Mass-Spectrometer Measurements of the Thermodynamic Properties of Molten Alloys,” Ph.D. thesis, Colorado School of Mines (1976). (Thermo; Experimental)

76Lys: L.I. Lysak, B.I. Nikolin, and A.I. Ustinov, “Phase Transformations in a Copper-Silicon Alloy,”Fiz. Met. Metalloved., 42, 601–608 (1976) in Russian; TR:Phys. Met. Metallogr. USSR, 42, 133–140 (1976). (Meta Phases; Experimental)

77Bar: I. Barin, O. Knacke, and O. Kubaschewski,Thermochemical Properties of Inorganic Substances (Supplement), Springer-Verlag, New York (1977). (Thermo; Compilation)

77Igu: Y. Iguchi, H. Shimoji, S. Ban-ya, and T. Fuwa, “Calorimetric Study of Heat of Mixing of Copper Alloys at 1120 °C,”J. Iron Steel Inst. Jpn., 63, 275–284 (1977) in Japanese. (Thermo; Experimental)

78Sol: J.K. Solberg, “The Crystal Structure of η Cu3Si Precipitates in Silicon,”Acta Crystallogr., A34, 684–698 (1978). (Crys Structure; Experimental)

79Cas: R. Castanet, “Thermodynamic Investigation of Copper+Silicon Melts,”J. Chem. Thermodyn., 11, 787–791 (1979). (Thermo; Experimental)

79Kau: L. Kaufman, “Coupled Phase Diagrams and Thermochemical Data for Transition Metal Binary Systems VI,”Calphad, 3, 45–76 (1979). (Thermo, Equi Diagram; Theory; Indicates presence of a phase diagram)

79Lys: L.I. Lysak and A.I. Ustinov, “Formation Mechanism of Martensitic Structures in a Copper-Silicon Alloy,”Fiz. Met. Metalloved., 44, 1050–1059 (1979) in Russian; TR:Phys. Met. Metallogr. (USSR), 44, 131–140 (1979). (Meta Phases; Experimental)

80Nay: P.K.K. Nayar and I.S. Batra, “Structural Transformation in Splat Cooled Copper 8 wt.% Silicon Alloys,”Trans. Indian Inst. Met., 33, 247–249 (1980). (Meta Phases; Experimental)

81Arp: I. Arpshofen, M.J. Pool, U. Gerling, F. Sommer, E. Schultheiss, and B. Predel, “Experimental Determination of the Integral Enthalpy of Mixing in the Binary Systems Pd−Cu and Si−Cu at 1600 K,”Z. Metallkd., 72, 842–846 (1981) in German. (Thermo; Experimental)

81Rie: G. Riekert, P. Lamparter, and S. Steeb, “The Determination of Thermodynamic Properties of Melts from the Cu−Si System by Mass Spectrometry,”Z. Naturforsch., 36a, 447–453 (1981). (Thermo; Experimental)

Indicates key paper. 82Bat: G.I. Batalin and V.S. Sudavtsova, “Thermodynamic Properties of Alloys of the Copper-Silicon System,”Izv. Akad. Nauk SSSR, Neorg. Mater., 18, 155–157 (1982) in Russian. (Thermo; Experimental)

82Ber: C. Bergman, R. Castanet, H. Saîd, M. Gilbert, and J.-C. Mathieu, “Configurational Entropy and the Regular Associated Model for Compound-Forming Binary Systems in the Liquid State,”J. Less-Common Met., 85, 121–135 (1982). (Thermo; Theory)