The Crystal Structure of Bis(diethylammonium) Hexachloridoplumbate(IV) Derived From Powder Diffraction Data and its Relation to Structurally Related Hexachloridometallate Salts
Tóm tắt
Bis(diethylammonium) hexachloridoplumbate(IV) was obtained by the reaction of PbO2 and (C2H5)2NH2Cl in hydrochloric acid solution. From the obtained crystalline powder a Rietveld refinement verified the structure of bis(diethylammonium) hexachloridoplumbate(IV) to be isotypic to the corresponding tin(IV) and platinum(IV) salts. The hexachloridoplumbate(IV) anions act as fourfold hydrogen bond acceptors and the diethylammonium cations as twofold hydrogen bond donors to form a two-dimensional framework perpendicular to the [−101] direction. Similar two-dimensional framework structures are well known for several hexahalogenidometallate salts, which are discussed. The infrared spectrum recorded at room temperature is provided and discussed on the basis of the structural data of the (C2H5)2NH2
+ cation and its connection to [PbCl6]2− anions in the title compound.
Tài liệu tham khảo
Knop O, Cameron TS, James MA, Falk M (1983) Alkylammonium hexachlorostannates(IV), (RnNH4–n)2SnCl6: crystal structure, infrared spectrum, and hydrogen bonding. Can J Chem 61:1620–1646
Ben Ghozlen MH, Daoud A, Bates JW (1981) Dimethylammonium hexachlorostannate(IV). Acta Crystallogr B 37:1415–1416
Ouasri A, Rhandour A, Dhamelincourt M-C, Dhamelinecourt P, Mazzah A (2002) Vibrational study of (CH3)4NSbCl6 and [(CH3)4N]2SiF6. J Spectrochim Acta Part A 58:2779–2788
Ouasri A, Rhandour A, Dhamelincourt M-C, Dhamelinecourt P, Mazzah A (2002) Structural and vibrational study of hydrazinium hexafluorosilicate. J Raman Spectrosc 33:726–729
Ouasri A, Rhandour A, Dhamelincourt M-C, Dhamelinecourt P, Mazzah A (2003) The infrared and Raman spectra of ethylammonium hexafluorosilicate [C2H5NH3]2SiF6. J Spectrochim Acta Part A 59:357–362
Ouasri A, Rhandour A, Dhamelincourt M-C, Dhamelinecourt P, Mazzah A (2003) Structure and vibrational study of the trimethylammonium hexafluorosilicate [(CH3)3NH]2SiF6 compound. J Spectrochim Acta Part A 59:851–857
Jeghnou H, Ouasri A, Rhandour A, Dhamelincourt M-C, Dhamelincourt P, Mazzah A (2003) Structural phase transition in (n-C4H9NH3)2SiF6: DSC and Raman studies. J Raman Spectrosc 34:126–130
[8] Jeghnou H, Ouasri A, Rhandour A, Dhamelincourt M-C, Dhamelincourt P, Mazzah A (2003) Structural phase transitions in [C6H5NH3]2SiF6: differential scanning calorimetry and Raman studies. J Raman Spectrosc 34:399–403
Jalbout AF, Jiang Z-Y, Ouasri A, Jeghnou H, Rhandour A, Dhamelincourt M-C, Dhamelincourt P, Mazzah A (2003) Theoretical and experimental vibrational analysis of [C6H5NH3]2SiF6. J Vib Spectros 33:21–30
Jalbout AF, Ouasri A, Jeghnou A, Rhandour A (2007) Experimental and theoretical studies of monoalkylammonium hexafluorosilicate [CH3(CH2)nNH3]2SiF6 (n = 2, 3) and ethylammonium hexafluorosilicate [(C2H5)2NH2]2SiF6. J Vib Spectrosc 44:94–100
Reiss GJ, Helmbrecht C (2012) Bis(diisopropylammonium) hexachloridostannate (IV). Acta Crystallogr E68:m1402-m1403
Cameron TS, James MA, Knop O, Falk M (1983) Bis(diethylammonium) hexachlorostannate(IV), (Et2NH2)2SnCl6, and tris(di-n-propylammonium) hexachlorostannate(IV) chloride, (n-Pr2NH2)3(SnCl6)Cl: crystal structure and hydrogen bonding. Can J Chem 61:2192–2198
Daszkiewicz M (2015) X-ray, vibrational and theoretical studies of weak hydrogen bonds in bis(4-nitroanilinium) hexachloridostannate. Spectrochim Acta A 139:102–107
Daszkiewicz M (2014) Weak hydrogen bonds in bis(3-nitroanilinium) hexachloridostannate monohydrate. X-ray, vibrational and theoretical studies. Spectrochim Acta A 131:335–341.
Hajji R, Oueslati A, Hajlaoui F, Bulou A, Hlel F (2015) Structural characterization, thermal, ac conductivity and dielectric properties of (C7H12N2)2[SnCl6]Cl2·1.5H2O. Phase Transit 89:1–20.
Reiss GJ (2002) The pseudosymmetric structure of bis(diisopropylammonium) hexachloroiridate(IV) and its relationship to potassium hexachloroiridate(III). Acta Crystallogr E58:m47–m50
Reiner T, Waibel M, Marziale AN, Jantke D, Kiefer FJ, Fässler TF, Eppinger J (2010) η 6-Arene complexes of ruthenium and osmium with pendant donor functionalities. J Organomet Chem 695:2667–2672
Spek AL, Veldman N, Velders AH, Reedijk J (2005) Bis(6,8-Dimethyl-(1,2,4)triazolo(4,3-b)pyridazinium)hexachlororuthenium(IV), YARREP, private communication to the Cambridge structural database
Bokach NA, Pakhomova TB, Kukushkin VY, Haukka M, Pombeiro AJL (2003) Hydrolytic metal-mediated coupling of dialkylcyanamides at a Pt(IV) center giving a new family of diimino ligands. Inorg Chem 42:7560–7568
Reiss GJ, Engel JS (2002) Hydrogen bonded 1,10-diammoniodecane - an example of an organo-template for the crystal engineering of polymeric polyiodides. CrystEngComm 4:155–161
Reiss GJ, Konietzny S (2002) How realistic are alternating C–C bond lengths in bis(s-cis-butadiene) transition metal-complexes? J Chem Soc Dalton Trans. 862–864. doi:10.1039/B109454H
Reiss GJ (2002) A reinvestigation of Wilm’s salt, - synthesis, structure, spectroscopy and thermal analysis. Z Kristallogr 217:550–556
Grell J, Bernstein J, Tinhofer G (2002) Investigation of hydrogen bond patterns: a review of mathematical tools for the graph set approach. Crystallogr Rev 8:1–56
Etter MC, MacDonald JC, Bernstein J (1990) Graph-set analysis of hydrogen-bond patterns in organic crystals. Acta Crystallogr B 46:256–262
Grell J, Bernstein J, Tinhofer G (1999) Graph-set analysis of hydrogen-bond patterns: some mathematical concepts. Acta Crystallogr B55:1030–1043
Holl K, Thewalt U (1986) S4N4 und seine Derivate: Isolierung und Struktur von S4N4H+[SnCl5(H2O)]– und (S3N2NH2 +)2 [SnCl6]2–. Z Naturforsch B 41:581–586
Kahrovic E, Orioli P, Bruni B, Di Vaira M, Messori L (2003) Crystallographic evidence for decomposition of dimethylformamide in the presence of ruthenium(III) chloride. Inorg Chim Acta 355:420–423
Xu W, Lin JL, Tetrakis(dimethylammonium) hexachlorotungstate(III) chloride. Acta Crystallogr E63:m767–m769
Lima-de-Faria J, Hellner E, Liebau F, Makovicky E, Parthé E (1990) Nomenclature of inorganic structure types. Report of the International Union of Crystallography Commission on Crystallographic Nomenclature Subcommittee on the Nomenclature of Inorganic Structure Types. Acta Crystallogr A 46:1–11
Bianga CM, Eggeling J, Reiss GJ (2013) Dimethylphosphoryl methanaminium nitrate. Acta Crystallogr. E69:o1639–o1640
Coelho AA (2012) TOPAS, academic version 5. Brisbane
Young RA (1995) The rietveld method, IUCr monographs on crystallography. Oxford University Press, Oxford
Järvinen M (1993) Application of symmetrized harmonics expansion to correction of the preferred orientation effect. J Appl Crystallogr 26:525–531
Dinnebier RE (1999) Rigid bodies in powder diffraction: a practical guide. Powder Diffract 14:84–92
Whealy RD, Lee DR (1967) Hexachloroplumbate(IV) salts. Inorg Chim Acta 1:397–398
Dobrzycki L, Wozniak K (2009) 1D vs 2D crystal architecture of hybrid inorganic–organic structures with benzidine dication. J Mol Struct 921:18–33
Dobrzycki L, Wozniak K (2008) Inorganic–organic hybrid salts of diaminobenzenes and related cation. CrystEngComm 10:577–589
Geselle M, Fuess H (1995) Hexakis(2-chloroethylammonium) hexachloroplumbate(II) chloride. Acta Crystallogr C 51:242–244
Gillon AL, Lewis GR, Orpen AG, Rotter S, Starbuck J, Wang X-M, Rodriguez-Martin Y, Ruiz-Perez C (2000) Organic-inorganic hybrid solids: control of perhalometallate solid state structures. J Chem Soc Dalton Trans 21:3897–3905