The Crystal Structure of Bis(diethylammonium) Hexachloridoplumbate(IV) Derived From Powder Diffraction Data and its Relation to Structurally Related Hexachloridometallate Salts

Springer Science and Business Media LLC - Tập 47 - Trang 173-181 - 2017
A. Ouasri1,2, A. Rhandour1, S. Schloots3, G. J. Reiss3
1Equipe de Physico-Chimie des Matériaux Inorganiques, Faculté des Sciences, Université Ibn Tofail, Kénitra, Morocco
2Département de Physique-Chimie, Centre Régional des Métiers de l'Education, et de la Formation, Souissi Rabat, Morocco
3Institut für Anorganische Chemie und Strukturchemie, Lehrstuhl II: Material- und Strukturforschung, Heinrich-Heine-Universität, Düsseldorf, Germany

Tóm tắt

Bis(diethylammonium) hexachloridoplumbate(IV) was obtained by the reaction of PbO2 and (C2H5)2NH2Cl in hydrochloric acid solution. From the obtained crystalline powder a Rietveld refinement verified the structure of bis(diethylammonium) hexachloridoplumbate(IV) to be isotypic to the corresponding tin(IV) and platinum(IV) salts. The hexachloridoplumbate(IV) anions act as fourfold hydrogen bond acceptors and the diethylammonium cations as twofold hydrogen bond donors to form a two-dimensional framework perpendicular to the [−101] direction. Similar two-dimensional framework structures are well known for several hexahalogenidometallate salts, which are discussed. The infrared spectrum recorded at room temperature is provided and discussed on the basis of the structural data of the (C2H5)2NH2 + cation and its connection to [PbCl6]2− anions in the title compound.

Tài liệu tham khảo

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