The Asymmetric Suzuki Coupling Route to Axially Chiral Biaryls

European Journal of Organic Chemistry - Tập 2005 Số 20 - Trang 4223-4229 - 2005
Olivier Baudoin1
1Institut de Chimie des Substances Naturelles, CNRS, Avenue de la Terrasse, 91198 Gif‐sur‐Yvette (France), Fax: (+33) 1‐69077247

Tóm tắt

AbstractAxially chiral biaryls are ubiquitous structural motifs in biologically active natural products or ligands for homogeneous catalysis. Their properties relate to the particular spatial arrangement of the two aromatic residues and therefore the control of their absolute configuration constitutes an issue of major importance. The asymmetric Suzuki–Miyaura coupling has recently emerged as an attractive alternative to standard methods for the control of biaryl axial chirality. Recent diastereo‐ and enantioselective approaches, as well as some applications in target‐oriented synthesis, are commented on in this microreview. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

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European Journal of Organic Chemistry

Tập 2005 Số 20

4223-4229

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