Temperature dependence of electromechanical properties of PLZT x/57/43 ceramics
Tóm tắt
The compositions of lead lanthanum zirconate titanate PLZT [Pb(Zr0.57Ti0.43)O3 + x at% of La, where x = 3, 5, 6, 10 and 12] have been synthesized using mixed oxide route. The temperature dependent electromechanical parameters have been determined using vector impedance spectroscopy (VIS). The charge constant d
31 and elastic compliance s
11
show a peak in all the samples at a temperature T
mt much below the ferroelectric — paraelectric transition temperature, whereas the series resonance frequency f
s
shows a dip at these temperatures. The Poisson’s ratio σ
E
increases with temperature T showing a broad peak at a temperature higher than T
mt
. The voltage constant g
31 decreases and the planar coupling coefficient K
p
remains constant up to half of the T
mt
and then falls sharply with T. Half of the T
mt
can, therefore, be used for specifying the working temperature limit of the piezoceramics for the device applications.