Tailored water and hydroxide transport at a quasi-two-phase interface of membrane electrode assembly electrolyzer for CO electroreduction

Joule - Tập 7 - Trang 2349-2360 - 2023
Wenhao Ren1, Wenchao Ma1, Xile Hu1
1Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), ISIC-LSCI, 1015 Lausanne, Switzerland

Tài liệu tham khảo

Ross, 2019, Designing materials for electrochemical carbon dioxide recycling, Nat. Catal., 2, 648, 10.1038/s41929-019-0306-7 Jin, 2021, Advances and challenges for the electrochemical reduction of CO2 to CO: from fundamentals to industrialization, Angew. Chem. Int. Ed., 133, 20795, 10.1002/ange.202101818 Rabinowitz, 2020, The future of low-temperature carbon dioxide electrolysis depends on solving one basic problem, Nat. Commun., 11, 10.1038/s41467-020-19135-8 Gu, 2022, Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium, Nat. Catal., 5, 268, 10.1038/s41929-022-00761-y Huang, 2021, CO2 electrolysis to multicarbon products in strong acid, Science, 372, 1074, 10.1126/science.abg6582 Ma, 2021, Electrocatalytic reduction of CO2 and CO to multi-carbon compounds over Cu-based catalysts, Chem. Soc. Rev., 50, 12897, 10.1039/D1CS00535A Ozden, 2021, Cascade CO2 electroreduction enables efficient carbonate-free production of ethylene, Joule, 5, 706, 10.1016/j.joule.2021.01.007 Jouny, 2018, High-rate electroreduction of carbon monoxide to multi-carbon products, Nat. Catal., 1, 748, 10.1038/s41929-018-0133-2 Jouny, 2019, Carbon monoxide electroreduction as an emerging platform for carbon utilization, Nat. Catal., 2, 1062, 10.1038/s41929-019-0388-2 Wang, 2022, Efficient electrosynthesis of n-propanol from carbon monoxide using a Ag–Ru–Cu catalyst, Nat. Energy, 7, 170, 10.1038/s41560-021-00967-7 Zhu, 2021, Direct and continuous generation of pure acetic acid solutions via electrocatalytic carbon monoxide reduction, Proc. Natl. Acad. Sci. USA, 118, 10.1073/pnas.2010868118 Rong, 2021, Size-dependent activity and selectivity of atomic-level copper nanoclusters during CO/CO2 electroreduction, Angew. Chem. Int. Ed., 60, 466, 10.1002/anie.202011836 Wang, 2019, Electrochemically converting carbon monoxide to liquid fuels by directing selectivity with electrode surface area, Nat. Catal., 2, 702, 10.1038/s41929-019-0301-z Gu, 2019, Atomically dispersed Fe3+ sites catalyze efficient CO2 electroreduction to CO, Science, 364, 1091, 10.1126/science.aaw7515 Lees, 2022, Gas diffusion electrodes and membranes for CO2 reduction electrolysers, Nat. Rev. Mater., 7, 55, 10.1038/s41578-021-00356-2 Xing, 2021, Enhancing carbon dioxide gas-diffusion electrolysis by creating a hydrophobic catalyst microenvironment, Nat. Commun., 12, 10.1038/s41467-020-20397-5 García de Arquer, 2020, CO2 electrolysis to multicarbon products at activities greater than 1 A cm−2, Science, 367, 661, 10.1126/science.aay4217 Wakerley, 2022, Gas diffusion electrodes, reactor designs and key metrics of low-temperature CO2 electrolysers, Nat. Energy, 7, 130, 10.1038/s41560-021-00973-9 Li, 2020, Highly quaternized polystyrene ionomers for high performance anion exchange membrane water electrolysers, Nat. Energy, 5, 378, 10.1038/s41560-020-0577-x Jiao, 2021, Designing the next generation of proton-exchange membrane fuel cells, Nature, 595, 361, 10.1038/s41586-021-03482-7 Zhao, 2020, In situ topotactic transformation of an interstitial alloy for CO electroreduction, Adv. Mater., 32, 10.1002/adma.202002382 Ji, 2020, Selective CO-to-acetate electroproduction via intermediate adsorption tuning on ordered Cu-Pd sites, Nat. Catal., 5, 251, 10.1038/s41929-022-00757-8 Zhou, 2022, Production of C3–C6 acetate esters via CO electroreduction in a membrane electrode assembly cell, Angew. Chem. Int. Ed., 61, 10.1002/anie.202202859 Li, 2014, Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper, Nature, 508, 504, 10.1038/nature13249 Mistry, 2016, Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene, Nat. Commun., 7 Lin, 2020, Operando time-resolved X-ray absorption spectroscopy reveals the chemical nature enabling highly selective CO2 reduction, Nat. Commun., 11, 10.1038/s41467-020-17231-3 Ren, 2022, A cation concentration gradient approach to tune the selectivity and activity of CO2 electroreduction, Angew. Chem. Int. Ed., 61, 10.1002/anie.202214173 Kim, 2015, The effect of binder content on the performance of a high temperature polymer electrolyte membrane fuel cell produced with reactive spray deposition technology, Electrochim. Acta, 177, 190, 10.1016/j.electacta.2015.02.025 Kim, 2021, Tailored catalyst microenvironments for CO2 electroreduction to multicarbon products on copper using bilayer ionomer coatings, Nat. Energy, 6, 1026, 10.1038/s41560-021-00920-8 Suo, 2015, “Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries, Science, 350, 938, 10.1126/science.aab1595 El-Nagar, 2023, Unintended cation crossover influences CO2 reduction selectivity in Cu-based zero-gap electrolysers, Nat. Commun., 14, 10.1038/s41467-023-37520-x Li, 2021, The role of electrode wettability in electrochemical reduction of carbon dioxide, J. Mater. Chem. A, 9, 19369, 10.1039/D1TA03636J Chen, 2021, High-performance anion exchange membrane water electrolyzers with a current density of 7.68 A cm−2 and a durability of 1000 hours, Energy Environ. Sci., 14, 6338, 10.1039/D1EE02642A Li, 2020, Molecular tuning of CO2-to-ethylene conversion, Nature, 577, 509, 10.1038/s41586-019-1782-2 Ma, 2023, Copper lattice tension boosts full-cell CO electrolysis to multi-carbon olefins and oxygenates, Chem, 9, 2161, 10.1016/j.chempr.2023.03.022 Jin, 2023, Constrained C2 adsorbate orientation enables CO-to-acetate electroreduction, Nature, 617, 724, 10.1038/s41586-023-05918-8 Zhai, 2021, Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting, Nat. Commun., 12, 10.1038/s41467-021-24828-9 Disch, 2022, High-resolution neutron imaging of salt precipitation and water transport in zero-gap CO2 electrolysis, Nat. Commun., 13, 10.1038/s41467-022-33694-y Lu, 2015, Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities, Nat. Commun., 6, 10.1038/ncomms7616