Synthesis, particle shape characterization, magnetic properties and surface modification of superparamagnetic iron oxide nanochains

Materials Characterization - Tập 148 - Trang 123-133 - 2019
Marin Tadic1, Slavko Kralj2, Lazar Kopanja3,4
1Condensed Matter Physics Laboratory, Vinca Institute, University of Belgrade, Mike Petrovica Alasa 12-14, POB 522, 11001 Belgrade, Serbia
2Jožef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia
3Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, PO Box 3503, 11120 Belgrade, Serbia
4Faculty of Mathematics and Computer Science, Alfa BK University, Palmira Toljatija 3, 11070 Belgrade, Serbia

Tài liệu tham khảo

Malik, 2017, Hybrid magnetic iron oxide nanoparticles with tunable field-directed self-assembly, Nanoscale, 9, 14405, 10.1039/C7NR04518B Zeng, 2018, Analysis of the formation process and performance of magnetic Fe3O4@ Poly (4-vinylpyridine) absorbent prepared by in-situ synthesis, J. Mater. Sci. Technol., 34, 999, 10.1016/j.jmst.2017.07.007 Tang, 2015, Magnetic field induced controllable self-assembly of maghemite nanocrystals: from 3D arrays to 1D nanochains, Appl. Surf. Sci., 347, 202, 10.1016/j.apsusc.2015.04.066 Iacob, 2015, Superparamagnetic amorphous iron oxide nanowires self-assembled into ordered layered structures, RSC Adv., 5, 62563, 10.1039/C5RA10469F Zeleňáková, 2014, Superferromagnetism in chain-like Fe@SiO2 nanoparticle ensembles, J. Appl. Phys., 116, 33907, 10.1063/1.4890354 Qiu, 2017, Controlled crystal growth orientation and surface charge effects in self-assembled nickel oxide nanoflakes and their activity for the oxygen evolution reaction, Int. J. Hydrog. Energy, 42, 28397, 10.1016/j.ijhydene.2017.09.117 Zhuang, 2017, Alcohol-assisted self-assembled 3D hierarchical iron (hydr) oxide nanostructures for water treatment, CrystEngComm, 19, 5926, 10.1039/C7CE01320E Edla, 2017, 3D hierarchical nanostructures of iron oxides coatings prepared by pulsed laser deposition for photocatalytic water purification, Appl. Catal. B Environ., 219, 401, 10.1016/j.apcatb.2017.07.063 Brunner, 2017, Self-assembled magnetite Mesocrystalline films: toward structural evolution from 2D to 3D superlattices, Adv. Mater. Interfaces, 4 Fu, 2016, Field-induced self-assembly of iron oxide nanoparticles investigated using small-angle neutron scattering, Nanoscale, 8, 18541, 10.1039/C6NR06275J Toulemon, 2016, Enhanced collective magnetic properties in 2D monolayers of Iron oxide nanoparticles favored by local order and local 1D shape anisotropy, Langmuir, 32, 1621, 10.1021/acs.langmuir.5b04145 Yuan, 2017, Facile assembly of aligned magnetic nanoparticle chains in polymer nanocomposite films by magnetic flow coating, ACS Appl. Mater. Interfaces, 9, 11290, 10.1021/acsami.7b02186 Wang, 2018, A review of Fe3O4 thin films: synthesis, modification and applications, J. Mater. Sci. Technol., 34, 1259, 10.1016/j.jmst.2018.01.011 Liu, 2018, Synthesis and magnetic properties of shuriken-like nickel nanoparticles, J. Mater. Sci.Technol., 34, 836, 10.1016/j.jmst.2017.04.006 Xue, 2017, Theoretical study of the self-assembly and optical properties of 1D chains of magnetic–Plasmonic nanoparticles, J. Phys. Chem. C, 121, 9489, 10.1021/acs.jpcc.7b00824 Zhang, 2017, XMCD and XMCD-PEEM studies on magnetic-field-assisted self-assembled 1D Nanochains of spherical ferrite particles, Adv. Funct. Mater., 27 Martinez-Boubeta, 2013, Learning from nature to improve the heat generation of iron-oxide nanoparticles for magnetic hyperthermia applications, Sci. Rep., 3, 1652, 10.1038/srep01652 Jiang, 2017, Magnetically assembled iron oxide nanoparticle coatings and their integration with pseudo-spin-valve thin films, J. Mater. Chem. C, 5, 252, 10.1039/C6TC03918A Chen, 2016, Self-assembled superparamagnetic iron oxide nanoclusters for universal cell labeling and MRI, Nanoscale Res. Lett., 11, 263, 10.1186/s11671-016-1479-5 Yuan, 2015, Flexible one-dimensional nanostructures: a review, J. Mater. Sci., 31, 607 Lupan, 2017, Localized synthesis of iron oxide nanowires and fabrication of high performance nanosensors based on a single Fe2O3 nanowire, Small, 13, 1602868, 10.1002/smll.201602868 Maccato, 2018, Magnetic properties of ε iron (III) oxide nanorod arrays functionalized with gold and copper (II) oxide, Appl. Surf. Sci., 427, 890, 10.1016/j.apsusc.2017.09.015 Zhong, 2015, Novel iron oxide nanotube arrays as high-performance anodes for lithium ion batteries, J. Power Sources, 296, 255, 10.1016/j.jpowsour.2015.07.051 Dhak, 2017, Linear-chain assemblies of iron oxide nanoparticles, J. Magn. Magn. Mater., 433, 47, 10.1016/j.jmmm.2017.02.050 He, 2016, Manipulating the dimensional assembly pattern and crystalline structures of iron oxide nanostructures with a functional polyolefin, Nanoscale, 8, 1915, 10.1039/C5NR07213A Wang, 2018, Facile one-pot synthesis of chain-like titanium dioxide nanostructure arrays for efficient ultraviolet sensing, Appl. Surf. Sci., 449, 239, 10.1016/j.apsusc.2017.09.005 Das, 2016, Tunable high aspect ratio iron oxide nanorods for enhanced hyperthermia, J. Phys. Chem. C, 120, 10086, 10.1021/acs.jpcc.6b02006 Tahir, 2016, Hierachical Ni@Fe2O3 superparticles through epitaxial growth of γ-Fe2O3 nanorods on in situ formed Ni nanoplates, Nanoscale, 8, 9548, 10.1039/C6NR00065G Cortés-Llanos, 2017, Thermal route for the synthesis of maghemite/hematite core/shell nanowires, J. Phys. Chem. C, 121, 23158, 10.1021/acs.jpcc.7b02625 Yousefi, 2018, Maghemite Nanorods and Nanospheres: synthesis and comparative physical and biological properties, Bionanoscience, 8, 95, 10.1007/s12668-017-0431-1 Martín, 2016, Magnetism in living magnetically-induced bacteria, RSC Adv., 6, 95220, 10.1039/C6RA20295K Shokrollahi, 2017, A review of the magnetic properties, synthesis methods and applications of maghemite, J. Magn. Magn. Mater., 426, 74, 10.1016/j.jmmm.2016.11.033 Xu, 2015, Controllable fabrication of nickel nanoparticle chains based on electrochemical corrosion, J. Mater. Chem. C, 3, 2072, 10.1039/C4TC02450H Zhu, 2017, Preparation of superparamagnetic and flexible γ-Fe2O3 nanowire arrays in an anodic aluminum oxide template, J. Mater. Sci., 52, 12717, 10.1007/s10853-017-1383-0 Sundar, 2016, Facile biosurfactant assisted biocompatible α-Fe2O3 nanorods and nanospheres synthesis, magneto physicochemical characteristics and their enhanced biomolecules sensing ability, RSC Adv., 6, 77133, 10.1039/C6RA15290B Khan, 2017, Fabrication, morphological, structural and magnetic properties of electrodeposited Fe3Pt nanowires and nanotubes, J. Magn. Magn. Mater., 424, 410, 10.1016/j.jmmm.2016.10.051 Peddis, 2016, Studying nanoparticles' 3D shape by aspect maps: determination of the morphology of bacterial magnetic nanoparticles, Faraday Discuss., 191, 177, 10.1039/C6FD00059B Tuček, 2015, Zeta-Fe2O3 a new stable polymorph in iron(III) oxide family, Sci. Rep., 5, 15091, 10.1038/srep15091 López-Sánchez, 2016, Growth, structure and magnetism of ε-Fe2O3 in nanoparticle form, RSC Adv., 6, 46380, 10.1039/C6RA01912A Balaev, 2013, Surface effects and magnetic ordering in few-nanometer-sized ε-Fe2O3 particles, J. Appl. Phys., 114, 10.1063/1.4827839 Bukhtiyarova, 2011, Facile synthesis of nanosized ε-Fe2O3 particles on the silica support, J. Nanopart. Res., 13, 5527, 10.1007/s11051-011-0542-5 García-Muñoz, 2017, Unveiling a new high-temperature ordered magnetic phase in ε-Fe2O3, Chem. Mater., 29, 9705, 10.1021/acs.chemmater.7b03417 Shanenkov, 2017, Influence of oxygen concentration on plasma dynamic synthesis product in Fe-O system, Solid State Phenom., 265, 652, 10.4028/www.scientific.net/SSP.265.652 Yakushkin, 2017, Evolution of the Fe3+ ion local environment during the phase transition ε-Fe2O3→α-Fe2O3, J. Supercond. Nov. Magn., 1 Sivkov, 2016, Plasma dynamic synthesis and obtaining ultrafine powders of iron oxides with high content of ε-Fe2O3, J. Magn. Magn. Mater., 405, 158, 10.1016/j.jmmm.2015.12.072 López-Sánchez, 2017, Origin of the magnetic transition at 100 K in ε-Fe2O3 nanoparticles studied by X-ray absorption fine structure spectroscopy, J. Phys. Condens. Matter, 29, 10.1088/1361-648X/aa904b Tadic, 2017, Synthesis of metastable hard-magnetic ε-Fe2O3 nanoparticles from silica-coated akaganeite nanorods, Nanoscale, 9, 10579, 10.1039/C7NR03639F López-Sánchez, 2016, Sol–gel synthesis and micro-Raman characterization of ε-Fe2O3 micro- and nanoparticles, Chem. Mater., 28, 511, 10.1021/acs.chemmater.5b03566 Bahiraei, 2018, Preparation and characterization of γ-Fe2O3 nanoparticles and investigation of its adsorption performance for sulfide, sulfite and thiosulfate from aqueous solutions using ultrasonic assisted method: modeling and optimization, Ultrason. Sonochem., 40, 1049, 10.1016/j.ultsonch.2017.08.035 Rajput, 2017, Lead (Pb2+) and copper (Cu2+) remediation from water using superparamagnetic maghemite (γ-Fe2O3) nanoparticles synthesized by flame spray pyrolysis (FSP), J. Colloid Interface Sci., 492, 176, 10.1016/j.jcis.2016.11.095 Meng, 2017, One-pot synthesis of Fe2O3 loaded SiO2 hollow particles as effective visible light photo-Fenton catalyst, J. Alloys Compd., 722, 8, 10.1016/j.jallcom.2017.06.077 Saad, 2017, Synthesis of carbon loaded γ-Fe2O3 nanocomposite and their applicability for the selective removal of binary mixture of dyes by ultrasonic adsorption based on response surface methodology, Ultrason. Sonochem., 36, 393, 10.1016/j.ultsonch.2016.12.010 Bahari, 2017, Characteristics of Fe3O4, α-Fe2O3, and γ-Fe2O3 nanoparticles as suitable candidates in the field of nanomedicine, J. Supercond. Nov. Magn., 30, 2165, 10.1007/s10948-017-4014-8 Lee, 2017, Tubular superstructures composed of α-Fe2O3 nanoparticles from pyrolysis of metal–organic frameworks in a confined space: effect on morphology, particle size, and magnetic properties, Cryst. Growth Des., 17, 4496, 10.1021/acs.cgd.7b00547 Jaafarzadeh, 2017, Catalytic degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) by nano-Fe2O3 activated peroxymonosulfate: influential factors and mechanism determination, Chemosphere, 169, 568, 10.1016/j.chemosphere.2016.11.038 Vasiliev, 2017, Magnetism of natural composite of halloysite clay nanotubes Al2Si2O5 (OH) 4 and amorphous hematite Fe2O3, Mater. Charact., 129, 179, 10.1016/j.matchar.2017.04.028 Mansour, 2017, Structural, optical, magnetic and electrical properties of hematite (α-Fe2O3) nanoparticles synthesized by two methods: polyol and precipitation, Appl. Phys. A, 123, 787, 10.1007/s00339-017-1408-1 Jesus, 2018, Anisotropic growth of α-Fe2O3 nanostructures, Ceram. Int., 44, 3585, 10.1016/j.ceramint.2017.11.068 Chen, 2017, Nanocasting synthesis, magnetic interaction and gas-sensing properties of dispersed, bundled and assembled α-Fe2O3 nanowires, J. Alloys Compd., 705, 138, 10.1016/j.jallcom.2017.01.118 Baratella, 2017, Electrostatically stabilized hybrids of carbon and maghemite nanoparticles: electrochemical study and application, Phys. Chem. Chem. Phys., 19, 11668, 10.1039/C7CP01486D Hasanpour, 2017, Template synthesis of maghemite nanoparticle in carboxymethyl cellulose and its application for electrochemical cabergoline sensing, Mater. Sci. Eng. C., 76, 88, 10.1016/j.msec.2017.02.128 Richard, 2016, USPIO size control through microwave nonaqueous sol-gel method for neoangiogenesis T2 MRI contrast agent, Nanomedicine, 21, 2769 Jahangirian, 2017, A review of drug delivery systems based on nanotechnology and green chemistry: green nanomedicine, Int. J. Nanomedicine, 12, 2957, 10.2147/IJN.S127683 Otieno, 2016, Bioconjugation of antibodies and enzyme labels onto magnetic beads, Methods Enzymol., 571, 135, 10.1016/bs.mie.2015.10.005 Richard, 2017, Iron oxide nanoparticle surface decorated with cRGD peptides for magnetic resonance imaging of brain tumors, Biochim. Biophys. Acta, Gen. Subj., 1861, 1515, 10.1016/j.bbagen.2016.12.020 Farzin, 2017, Multifunctional magnetic nanostructured hardystonite scaffold for hyperthermia, drug delivery and tissue engineering applications, Mater. Sci. Eng. C., 70, 21, 10.1016/j.msec.2016.08.060 Guibert, 2017, Magnetic fluid hyperthermia probed by both calorimetric and dynamic hysteresis measurements, J. Magn. Magn. Mater., 421, 384, 10.1016/j.jmmm.2016.08.015 Grau-Crespo, 2010, Vacancy ordering and electronic structure of γ-Fe2O3 (maghemite): a theoretical investigation, J. Phys. Condens. Matter., 22, 10.1088/0953-8984/22/25/255401 Waifalkar, 2016, Immobilization of invertase on chitosan coated γ-Fe2O3 magnetic nanoparticles to facilitate magnetic separation, J. Colloid Interface Sci., 482, 159, 10.1016/j.jcis.2016.07.082 Zulfiqar, 2016, Variation of structural, dielectric and magnetic properties of PVP coated γ-Fe2O3 nanoparticles, J. Mater. Sci. Mater. Electron., 27, 12490, 10.1007/s10854-016-5634-7 Nedelcu, 2015, Structural characterization of copolymer embedded magnetic nanoparticles, Appl. Surf. Sci., 352, 109, 10.1016/j.apsusc.2015.04.191 Stier, 2018, Implications of a temperature-dependent magnetic anisotropy for superparamagnetic switching, J. Magn. Magn. Mater., 447, 96, 10.1016/j.jmmm.2017.09.068 Saravanan, 2016, Investigation of polymer dynamics in chitosan-maghemite nanocomposites: a potential green superparamagnetic material, J. Polym. Res., 23, 104, 10.1007/s10965-016-0998-1 Kopáni, 2017, Magnetic properties of iron oxides in the human globus pallidus, J. Bioanal. Biomed., 9, 080, 10.4172/1948-593X.1000158 Bezverkhyy, 2016, Preparation of magnetic composites of MIL-53(Fe) or MIL-100(Fe) via partial transformation of their framework into γ-Fe2O3, J. Mater. Chem. A, 4, 8141, 10.1039/C6TA00383D Tronc, 2000, Surface-related properties of γ-Fe2O3 nanoparticles, J. Magn. Magn. Mater., 221, 63, 10.1016/S0304-8853(00)00369-3 Morales, 1999, Surface and internal spin canting in γ-Fe2O3 nanoparticles, Chem. Mater., 11, 3058, 10.1021/cm991018f Ramos Guivar, 2016, Vacancy ordered γ-Fe2O3 nanoparticles functionalized with nanohydroxyapatite: XRD, FTIR, TEM, XPS and Mössbauer studies, Appl. Surf. Sci., 389, 721, 10.1016/j.apsusc.2016.07.157 Shendruk, 2007, The effect of surface spin disorder on the magnetism of γ-Fe2O3 nanoparticle dispersions, Nanotechnology, 18, 10.1088/0957-4484/18/45/455704 Khurshid, 2015, Spin-glass-like freezing of inner and outer surface layers in hollow γ-Fe2O3 nanoparticles, Sci. Rep., 5, 15054, 10.1038/srep15054 Toulemon, 2016, Enhanced collective magnetic properties induced by the controlled assembly of Iron oxide nanoparticles in chains, Adv. Funct. Mater., 26, 2454, 10.1002/adfm.201505086 Wang, 2009, Magnetic-field-induced formation of one-dimensional magnetite nanochains, Langmuir, 25, 7135, 10.1021/la900234n Sparks, 2013, Explicit shape descriptors: novel morphologic features for histopathology classification, Med. Image Anal., 17, 997, 10.1016/j.media.2013.06.002 Aktaş, 2013, A family of shape ellipticity measures for galaxy classification, SIAM J. Imag. Sci., 6, 765, 10.1137/120866026 Belongie, 2002, Shape matching and object recognition using shape contexts, IEEE Trans. Pattern Anal. Mach. Intell., 24, 509, 10.1109/34.993558 Žunić, 2014, Shape ellipticity from Hu moment invariants, Appl. Math. Comput., 226, 406, 10.1016/j.amc.2013.10.062 Rhouma, 2017, Moment invariants for multi-component shapes with applications to leaf classification, Comput. Electron. Agric., 142, 326, 10.1016/j.compag.2017.08.029 Najafian, 2017, Fourier-based quantification of renal glomeruli size using Hough transform and shape descriptors, Comput. Methods Prog. Biomed., 151, 179, 10.1016/j.cmpb.2017.08.011 Wiwart, 2012, Identification of hybrids of spelt and wheat and their parental forms using shape and color descriptors, Comput. Electron. Agric., 83, 68, 10.1016/j.compag.2012.01.015 Rosin, 2006, A symmetric convexity measure, Comput. Vis. Image Underst., 103, 101, 10.1016/j.cviu.2006.04.002 Rahtu, 2006, A new convexity measure based on a probabilistic interpretation of images, IEEE Trans. Pattern Anal. Mach. Intell., 28, 1501, 10.1109/TPAMI.2006.175 Klette, 2012, ADR shape descriptor – distance between shape centroids versus shape diameter, Comput. Vis. Image Underst., 116, 690, 10.1016/j.cviu.2012.02.001 Yoon, 2017, Systematic study of interdependent relationship on gold nanorod synthesis assisted by electron microscopy image analysis, Nanoscale, 9, 7114, 10.1039/C7NR01462G Zunic, 2004, A new convexity measure for polygons, IEEE Trans. Pattern Anal. Mach. Intell., 26, 923, 10.1109/TPAMI.2004.19 Zunic, 2002, A convexity measurement for polygons, IEEE Trans. Pattern Anal. Mach. Intell., 26, 173 Rosin, 2007, Probabilistic convexity measure, IET Image Process., 1, 182, 10.1049/iet-ipr:20060185 Žunić, 2007, Convexity measure for shapes with partially extracted boundaries, Electron. Lett., 43, 380, 10.1049/el:20070280 Li, 2018, 3-D magnetic graphene oxide-magnetite poly (vinyl alcohol) nanocomposite substrates for immobilizing enzyme, Polymer, 149, 13, 10.1016/j.polymer.2018.06.046 Gu, 2018, Large negative giant magnetoresistance at room temperature and electrical transport in cobalt ferrite-polyaniline nanocomposites, Polymer, 143, 324, 10.1016/j.polymer.2018.04.008 Gong, 2018, Ultrasonic pretreated sludge derived stable magnetic active carbon for Cr (VI) removal from wastewater, ACS Sustain. Chem. Eng., 6, 7283, 10.1021/acssuschemeng.7b04421 Huang, 2017, Magnetic nanocarbon adsorbents with enhanced hexavalent chromium removal: morphology dependence of fibrillar vs particulate structures, Ind. Eng. Chem. Res., 56, 10689, 10.1021/acs.iecr.7b02835 Wu, 2018, Enhanced electromagnetic wave absorption of three-dimensional porous Fe3O4/C composite flowers, ACS Sustain. Chem. Eng., 6, 12471, 10.1021/acssuschemeng.8b03097 Guo, 2018, Bio-gel derived nickel/carbon nanocomposites with enhanced microwave absorption, J. Mater. Chem. C, 6, 8812, 10.1039/C8TC02127A Huang, 2018, Hexavalent chromium removal over magnetic carbon nanoadsorbent: synergistic effect of fluorine and nitrogen co-doping, J. Mater. Chem. A, 6, 13062, 10.1039/C8TA02861C Luo, 2017, Discrete iron (III) oxide nanoislands for efficient and photostable perovskite solar cells, Adv. Funct. Mater., 27, 1702090, 10.1002/adfm.201702090 Zhou, 2017, PAA/alumina composites prepared with different molecular weight polymers and utilized as support for nickel-based catalyst, Adv. Polym. Technol., 37, 2325, 10.1002/adv.21908 Du, 2018, Nickel powders modified nanocoating strengthened Iron plates by surface mechanical attrition alloy and heat treatment, Sci. Adv. Mater., 10, 1063, 10.1166/sam.2018.3324 He, 2018, Reinforced carbon fiber laminates with oriented carbon nanotube epoxy nanocomposites: magnetic field assisted alignment and cryogenic temperature mechanical properties, J. Colloid Interface Sci., 517, 40, 10.1016/j.jcis.2018.01.087 Lou, 2017, Crystal structure modification enhanced FeNb11O29 anodes for lithium-ion batteries, ChemElectroChem, 4, 3171, 10.1002/celc.201700816 Luo, 2017, Discrete iron (III) oxide nanoislands for efficient and photostable perovskite solar cells, Adv. Funct. Mater., 27, 1702090, 10.1002/adfm.201702090 Liu, 2017, A graphene quantum dot decorated SrRuO3 mesoporous film as an efficient counter electrode for high-performance dye-sensitized solar cells, J. Mater. Chem. A, 5, 17848, 10.1039/C7TA05123A Xie, 2018, Silica microsphere templated self-assembly of a three-dimensional carbon network with stable radio-frequency negative permittivity and low dielectric loss, J. Mater. Chem. C, 6, 5239, 10.1039/C7TC05911F Deng, 2018, Potassium hydroxide activated and nitrogen doped graphene with enhanced supercapacitive behavior, Sci. Adv. Mater., 10, 937, 10.1166/sam.2018.3279 Yang, 2019, Long-term antibacterial stable reduced graphene oxide nanocomposites loaded with cuprous oxide nanoparticles, J. Colloid Interface Sci., 533, 13, 10.1016/j.jcis.2018.08.053 Wu, 2018, Enhanced electromagnetic wave absorption of three-dimensional porous Fe3O4/C composite flowers, ACS Sustain. Chem. Eng., 6, 12471, 10.1021/acssuschemeng.8b03097 Zheng, 2018, Sodium dodecyl benzene sulfonate-catalyzed reaction for aromatic aldehydes with 1-phenyl-3-methyl-5-pyrazolone in aqueous media, Green Chem. Lett. Rev., 11, 217, 10.1080/17518253.2018.1465600 Zheng, 2017, Esterification synthesis of ethyl oleate catalyzed by Brønsted acid–surfactant-combined ionic liquid, Green Chem. Lett. Rev., 10, 202, 10.1080/17518253.2017.1342001 Lin, 2018, Nano-TiNb2O7/carbon nanotubes composite anode for enhanced lithium-ion storage, Electrochim. Acta, 260, 65, 10.1016/j.electacta.2017.11.051 Zhang, 2018, Highly efficient Fe-NC nanoparticles modified porous graphene composites for oxygen reduction reaction, J. Electrochem. Soc., 165, H510, 10.1149/2.0991809jes Sun, 2017, Experimental and simulation-based understanding of morphology controlled barium titanate nanoparticles under co-adsorption of surfactants, CrystEngComm, 19, 3288, 10.1039/C7CE00279C Kavre, 2014, Fabrication of magneto-responsive microgears based on magnetic nanoparticle embedded PDMS, RSC Adv., 4, 38316, 10.1039/C4RA05602G Kralj, 2015, Magnetic assembly of superparamagnetic Iron oxide nanoparticle clusters into nanochains and nanobundles, ACS Nano, 9, 9700, 10.1021/acsnano.5b02328 Kralj, 2014, The chemically directed assembly of nanoparticle clusters from superparamagnetic iron-oxide nanoparticles, RSC Adv., 4, 13167, 10.1039/c4ra00776j Tadic, 2014, Magnetic properties of novel superparamagnetic iron oxide nanoclusters and their peculiarity under annealing treatment, Appl. Surf. Sci., 322, 255, 10.1016/j.apsusc.2014.09.181 Kralj, 2013, Targeting EGFR-overexpressed A431 cells with EGF-labeled silica-coated magnetic nanoparticles, J. Nanopart. Res., 15, 1666, 10.1007/s11051-013-1666-6 Kralj, 2012, Effect of surface charge on the cellular uptake of fluorescent magnetic nanoparticles, J. Nanopart. Res., 14, 1151, 10.1007/s11051-012-1151-7 Kralj, 2011, Controlled surface functionalization of silica-coated magnetic nanoparticles with terminal amino and carboxyl groups, J. Nanopart. Res., 13, 2829, 10.1007/s11051-010-0171-4 Kopanja, 2016, Core–shell superparamagnetic iron oxide nanoparticle (SPION) clusters: TEM micrograph analysis, particle design and shape analysis, Ceram. Int., 42, 10976, 10.1016/j.ceramint.2016.03.235 Salunkhe, 2016, Water dispersible superparamagnetic cobalt iron oxide nanoparticles for magnetic fluid hyperthermia, J. Magn. Magn. Mater., 419, 533, 10.1016/j.jmmm.2016.06.057 Wang, 2018, Synthesis and characterization of polymer-coated manganese ferrite nanoparticles as controlled drug delivery, Appl. Surf. Sci., 428, 258, 10.1016/j.apsusc.2017.09.096 Kumar Das, 2018, Structural and magnetic properties of sol-gel derived CaFe2O4 nanoparticles, J. Magn. Magn. Mater., 451, 526, 10.1016/j.jmmm.2017.11.102 Koshy, 2015, Superparamagnetism in undoped ZnO nanorods, Appl. Surf. Sci., 346, 528, 10.1016/j.apsusc.2015.03.053 Lin, 2017, Study on preferential adsorption of cationic-style heavy metals using amine-functionalized magnetic iron oxide nanoparticles (MIONPs-NH2) as efficient adsorbents, Appl. Surf. Sci., 407, 29, 10.1016/j.apsusc.2017.02.173 Lin, 2017, Study on the influence of thiolation on the adsorption and magnetic recovery of superparamagnetic nanoadsorbents for Cd2+ removal, Appl. Surf. Sci., 425, 141, 10.1016/j.apsusc.2017.06.282 Wang, 2016, Monodisperse polyvinylpyrrolidone-coated CoFe2O4 nanoparticles: synthesis, characterization and cytotoxicity study, Appl. Surf. Sci., 365, 114, 10.1016/j.apsusc.2016.01.031 Sardar, 2017, Multiple functionalities of Ni nanoparticles embedded in carboxymethyl guar gum polymer: catalytic activity and superparamagnetism, Appl. Surf. Sci., 405, 231, 10.1016/j.apsusc.2017.01.229 Tadić, 2007, Synthesis and magnetic properties of concentrated α-Fe2O3 nanoparticles in a silica matrix, J. Alloys Compd., 441, 291, 10.1016/j.jallcom.2006.09.099