Synthesis of palm oil-based fatty methylhydrazide

Research on Chemical Intermediates - Tập 39 - Trang 2133-2139 - 2012
Emad A. Jaffar Al-Mulla1,2, Nor Azowa Bt Ibrahim3, Isam Hussain T. Al-Karkhi4, Kamyar Shameli1,5, Mohammed Zidan1, Mansor Bin Ahmad1, Wan Md. Zin Wan Yunus6
1Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, UPM Serdang, Malaysia
2Department of Chemistry, College of Science, University of Kufa, An-Najaf, Iraq
3Department of Chemistry, Faculty of Science, Universiti Putra Malaysia-UPM, Serdang, Malaysia
4Department of Basic Science, College of Dentistry, University of Baghdad, Al-Jadrya-Baghdad, Iraq
5Materials and Energy Research Center, Karaj, Iran
6Department of Chemistry, Centre for Defence Foundation Studies, National Defence University of Malaysia, Kuala Lumpur, Malaysia

Tóm tắt

Fatty methylydrazides (FMHs) have been successfully synthesized from palm oil. Glycerol was produced as a by-product. The synthesis was carried out by reflux palm oil with methylhydrazine in hexane. FMHs have been characterized using elemental analysis, Fourier transform infrared spectroscopy and 1H nuclear magnetic resonance technique. The results showed that a 6:1 molar ratio of palm oil to methylhydrazine, a round 78 % maximum conversion of palm oil into FMHs and a 10 h reaction time are the optimum reaction conditions.

Tài liệu tham khảo

C.R. Millington, Tetrahedron Lett. 39, 7201 (1998) M. Lumbierres, J.M. Palomo, G. Kragol, S. Roehrs, O. Muller, H. Waldmann, Chem. Eur. J. 11, 7405 (2005) R. Stefan, M. Jochen, K. Joachim, W. Ludger, B. Gerhard, R.H. John, J.O. Tom, W. Daguang, S. Markus, Nucl. Acids Res. 30, 4793 (2002) G.D. Yadav, S.S. Joshi, P.S. Lathi, Enzym. Microb. Technol. 36, 217 (2007) H. Zhang, J. Drewe, B. Tseng, S. Kasibhatla, S.X. Cai, Bioorg Med. Chem. 12, 3649 (2004) A. Uzma, A. Rifat, M. Mohammad, T.M. Zahida, M.K. Khalid, N.K. Shamsun, S. Hina, I.C. Muhammad, Chem. Biodivers. 18, 82 (2008) P. Yanqing, S. Gonghua, Green Chem. 3, 302 (2001) D.Y. Ganapati, S.J. Sachin, S.L. Piyush, Enzym. Microb. Technol. 36, 217 (2004) A.M. Nadia, M.F. Mona, F.A. Refah, Reac. Func. Polym. 63, 185 (2004) S. Mohamad, W.M.Z. Yunus, M. Haron, M.Z. Abdul Rahman, J. Oleo Sci. 57, 263 (2008) E.A.J. Al-Mulla, N.A.B. Ibrahim, K. Shameli, M.B. Ahmad, W.M.W. Yunus, Res. Chem. Intermed. (2012). doi:10.1007/s11164-012-0687-6 E.A.J. Al-Mulla, K.W.S. Al-Janabi, Chin. Chem. Lett. 22, 469 (2011) S. James, O.G.M. Fritz, Anal. Chem. 47, 2043 (1975) E.A.J. Al-Mulla, W.M.Z. Yunus, N.A. Ibrahim, M.Z. Abdul Rahman, J. Oieo Sci. 58, 467 (2009) H.W. Hoidy, M.B. Ahmad, E.A.J. Al-Mulla, W.M.Z. Yonus, N.A. Ibrahim, J. Oieo Sci. 59, 15 (2010) E.A.J. Al-Mulla, W.M.Z. Yunus, N.A. Ibrahim, M.Z. Abdul Rahman, J. Oieo Sci. 2010(59), 59 (2010) H.W. Hoidy, M.B. Ahmad, E.A.J. Al-Mulla, W.M.Z. Yonus, N.A. Ibrahim, J. Oieo Sci. 2010(59), 229 (2010) E.A.J Al-Mulla, W.M.Z. Yunus, N.A. Ibrahim, M.Z. Abdul Rahman, J. Oieo Sci. 59, 157 (2010)
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Research on Chemical Intermediates

Tập 39

2133-2139

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