Synthesis of ethyl (±)-(13,15-dideoxy)-16-methyl-9-oxoprosta-13(E,Z),15(E)-dienoate
Tóm tắt
The condensation of ethyl 7-(2-oxo-5-formulcyclopentyl)heptanoate by Wittig reaction with the ylide prepared from [(2E)-3-methylhept-2-en-1-yl]triphenylphosphonium bromide afforded ethyl (±)-(13,15-dideoxy)-16-methyl-9-oxoprosta-13(E,Z),15(E)-dienoate as a mixture of two isomers, 2:1.
Tài liệu tham khảo
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