Synthesis of Diverse LiNixMnyCozO2 Cathode Materials from Lithium Ion Battery Recovery Stream

Qina Sa1, Eric Gratz1, Joseph Heelan1, Sijia Ma1, Diran Apelian1, Yan Wang1
1Department of Mechanical Engineering, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA, 01609, USA

Tóm tắt

Từ khóa


Tài liệu tham khảo

Electric car use by country. http://en.wikipedia.org/wiki/Electric_car_use_by_country . Accessed 18 May 2015

Kang DHP, Chen M, Ogunseitan OA (2013) Potential environmental and human health impacts of rechargeable lithium batteries in electronic waste. Environ Sci Technol 47:5495–5503

Lain MJ (2001) Recycling of lithium ion cells and batteries. J Power Sources 97–98:736–738

Xu J, Thomas HR, Francis RW, Lum KR, Wang J, Liang B (2008) A review of processes and technologies for the recycling of lithium-ion secondary batteries. J Power Sources 177:512–527

Paulino JF, Busnardo NG, Afonso JC (2008) Recovery of valuable elements from spent Li-batteries. J Hazard Mater 150:843–849

Zhang P, Yokoyama T, Itabashi O, Suzuki TM, Inoue K (1998) Hydrometallurgical process for recovery of metal values from spent lithium-ion secondary batteries. Hydrometallurgy 47:259–271

Contestabile M, Panero S, Scrosati B (2001) A laboratory-scale lithium-ion battery recycling process. J Power Sources 92:65–69

Shin SM, Kim NH, Sohn JS, Young DH, Kim YH (2005) Development of a metal recovery process from Li-ion battery wastes. Hydrometallurgy 79:172–181

Dorella G, Mansur MB (2007) A study of the separation of cobalt from spent Li-ion battery residues. J Power Sources 170:210–215

Zou H, Gratz E, Apelian D, Wang Y (2013) A novel method to recycle mixed cathode materials for lithium ion batteries. Green Chem 15:1183–1191

Gratz E, Sa Q, Apelian D, Wang Y (2014) A closed loop process for recycling spent lithium ion batteries. J Power Sources 262:255–262

Sa Q, Gratz E, He M, Lu W, Apelian D, Wang Y (2015) Synthesis of high performance LiNi1/3Mn1/3Co1/3O2 from lithium ion battery recovery stream. J Power Sources 282:140–145

Bommerl A, Dahn JR (2009) Synthesis of spherical and dense particles of the pure hydroxide phase Ni1/3Mn1/3Co1/3(OH)2. J Electrochem Soc 156(5):A362–A365

Lee MH, Kang YJ, Myung ST, Sun YK (2004) Synthetic optimization of Li[Ni1/3Co1/3Mn1/3]O2 via co-precipitation. Electrochim Acta 50:939–948

Liu Z, Yu A, Lee JY (1999) Synthesis and characterization of LiNi1−x−yCoxMnyO2 as the cathode materials of secondary lithium batteries. J Power Sources 81–82:416–419

Bommel A, Dahn J (2009) Analysis of the growth mechanism of coprecipitated spherical and dense nickel, manganese and cobalt-containing hydroxides in the presence of aqueous ammonia, contained. Chem Mater 21:1500–1503

Huang Y, Gao D, Lei G, Li Z, Su Y (2007) Synthesis and characterization of Li(Ni1/3Co1/3Mn1/3)0.96Si0.04O1.96F0.04 as a cathode material for lithium-ion battery. Mater Chem Phys 106:354–359

Zhao X, Zhou F, Dahn JR (2008) Phases formed in Al-doped Ni1/3Mn1/3Co1/3(OH)2 prepared by coprecipitation: formation of layered double hydroxide. J Electrochem Soc 155(9):A642–A647

Noh M, Cho J (2013) Optimized synthetic conditions of LiNi0.5Co0.2Mn0.3O2 cathode materials for high rate lithium batteries via co-precipitation method. J Electrochem Soc 160(1):A105–A111

Choi J, Manthiram A (2005) Role of chemical and structural stabilities on the electrochemical properties of layered LiNi1/3Mn1/3Co1/3O2 cathodes. J Electrochem Soc 152(9):A1714–A1718

Liang LW, Du K, Peng ZD, Cao YB, Hu GR (2014) Synthesis and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 as a concentration-gradient cathode material for lithium batteries. Chin Chem Lett 25(6):883–886