Synthesis of Ag–Fe3O4 nanoparticles supported on polydopamine-functionalized porous cellulose acetate microspheres: catalytic and antibacterial applications

Springer Science and Business Media LLC - Tập 25 - Trang 4771-4782 - 2018
Shuai Peng1,2, Fei Gao3, Dong Zeng1, Chuang Peng1, Yingming Chen4, Ming Li1
1School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, China
2Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing and Finishing, Wuhan Textile University, Wuhan, China
3Department of Orthopedic Surgery, Union Hospital, Tongji Medical College, Huazhong University of Science and Technology, Wuhan, China
4College of Resource and Environmental Science, South-Central University for Nationalities, Wuhan, China

Tóm tắt

Polydopamine (PDA)—decorated porous cellulose acetate microspheres (PCA/PDA) were synthesized and employed as support for Ag–Fe3O4 NPs (SFNPs) by an in situ one pot method without additional reductants. Different PCA/SFNPs have been studied using various characterization techniques. The as-prepared PCA/PDA/SFNPs exhibited excellent catalytic property for the reduction of 4-nitrophenol within 10 min and strong bactericidal activity against E. coli. Interestingly, the corresponding rate constant increased with the increase of SFNPs amount in PCA/PDA and PCA/PDA/SFNPs showed significantly higher catalytic activity as compared to those exhibited by SFNPs deposited on deacetylated porous cellulose acetate/SFNPs microspheres (DPCA/SFNPs). The enhanced catalytic performance may be attributed to the improved adsorbability and dispersity of SFNPs via the introduction of abundant amine and catechol groups of PDA onto the PCA nanoporous structure. This work has demonstrated the PCA/PDA/SFNPs may hold application potentials in various fields.

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