Synthesis, crystal structure and magnetic properties of one-dimensional cyano-bridged bimetallic complex of [Mn(Me2-bipy)2]3[W(CN)8]2·9H2O
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Crystal data for 1: C88H90Mn3N28O9W2, M=2215.39, monoclinic, space group C2/c, a=22.372(4)Å, b=16.468(3)Å, c=26.648(4)Å, β=90.112(3)°, V=9818(3)Å3, Z=4, Dc=1.500gcm3, F(000)=4436, μ(Mo Kα)=2.777mm−1, R1=0.0532, wR2=0.1119 for 8884 unique reflections and 593 parameters, S=1.027. Crystallographic data were collected using a Bruker SMART CCD diffractometer operating at room temperature. Intensities were collected with graphite monochromatized Mo Kα radiation (λ=0.71073Å), using the phi and omega scan technique. Data reduction was made with the Bruker SAINT package. Absorption correction was performed using the SADABS program. The structure was solved by direct methods and refined on F2 by full-matrix least-squares using SHELXL-2000 with anisotropic displacement parameters for all non-hydrogen atoms. H atoms were introduced in calculations using the riding model. All computations were carried out using the SHELXTL-2000 program package [28].
Bruker, SMART, SAINT, SADABS and SHELXTL, Bruker AXS Inc., Madison, WI, USA, 2000.
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