Synthesis and characterization of the narrow polydispersity fullerene-end-capped polystyrene

Changchun Wang1, Junpo He1, Shoukuan Fu1, Kejian Jiang2, Hongzheng Cheng2, Mang Wang2
1Department of Macromolecular Science, Fudan University, Shanghai, People’s Republic of China
2Institute of Polymer Science and Materials, Zhejiang University, Hangzhou, People's Republic of China

Tóm tắt

A living free radical polymerization process was adopted to synthesize a narrow polydispersity fullerene-end-capped polystyrene(NPFECPS). The UV-Vis, DSC, GPC demonstrated that fullerene(C60) was chemically bonded to polystyrene successfully, and C60 was almost monosubstituted. The NPFECPS can be dissolved in a variety of solvents, such as THF, toluene, trichloromethane, and so on. The good photoconductivity is also found for NPFECPS.

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Tài liệu tham khảo

Hirsch A (1993) Adv. Mater. 5: 859

Olah GA, Bucsi J, Lambert C, Amiszfeld R, Trivedi N, Sensharma D K, Prakash GKS (1991) J. Am. Chem. Soc. 113: 9387

Loy DA, Assink RA (1992) J. Am. Chem. Soc. 114: 3977

Patil AO, Schriver GW, Carstensen B, Lundberg RD (1993) Polym. Bull. 30: 187

Samulski ET, DeSimone JM, Hunt MGJ, Mencelogu YZ, Jarhagin RC, York GA, Labert KB, Wang H (1992) Chem. Marter. 14: 9665

Wooley KL, Hawker CJ, Frechet JMJ, Wudl F, Srdanov S, Shi S, Li C, Kao M (1993) J. Am. Chem. Soc. 115: 9836

Hawker CJ, Wooley KL, Frechet JMJ (1994) J. Chem. Soc. Chem. Commun. 925

Hawker J (1994) Macromolecules 27: 4836

Weis C, Friedrich C, Mulhaupt R, Frey H (1995) Macromolecules 28: 403

Wang J, Javahery G, Petrie S, Bohme D (1992) J. Am. Chem. Soc. 114:9665

Wang J, Javahery G, Petrie S, Hopkinson AC, Bohme DK (1994) J. Am. Chem. Soc. 116:227

Zhang ZY (1980) Journal of Lanzhou University(China), Natural Science 2:112

Wang CC, Shu C, Fu SK, Chemical Journal of Chinese Universities