Synthesis and characterization of novel triazeno‐group containing photopolymers

Macromolecular Chemistry and Physics - Tập 196 Số 3 - Trang 739-749 - 1995
Oskar Nuyken1, Jürgen Stebani1, Thomas Lippert2, Alexander Wokaun2, Andrej Staško3
1Lehrstuhl für Makromolekulare Stoffe, Technische Universität München, D-85747 Garching, Germany
2Lehrstuhl für Physikalische Chemie II, Universität Bayreuth, D-95440 Bayreuth, Germany
3Physical Chemistry, Slovak Technical University, 81237 Bratislava, Slovakia

Tóm tắt

AbstractThe synthesis of novel triazeno‐group containing photopolymers is described including their characterization by spectroscopic methods, differential scanning calorimetry, and thermogravimetric analysis. Triazene polymers synthesized by a polycondensation reaction between a bisdizaonium salt and a bifunctional secondary amine are well soluble in usual organic solvents. Transparent, light yellow films of these photopolymers may be produced by simple spin‐coating and solution‐casting techniques. The effect of polymer structural elements on the photolytic decomposition is studied. Depending on the structure of the polymer, thermolysis proceeds either via a one‐step or two‐step mechanism.

Từ khóa


Tài liệu tham khảo

Rabek J. F., 1987, Mechanisms of Photophysical Processes and Photochemical Reactions in Polymers

10.1021/cr00096a003

10.1155/1989/18750

Jain K., 1990, Excimer Laser Lithography

10.1364/JOSAB.3.000785

10.1021/ma00168a044

10.1016/0169-4332(90)90156-T

J.Ihlemann M.Bolle K.Luther J.Troe in:Physical Concepts of Materials for Novel Optoelectronic Device Applications I SPIE‐Proc. vol. 1361 Bellingham1990

10.1002/apmc.1993.052130113

10.1002/apmc.1993.052060110

10.1002/marc.1993.030140607

10.1021/j100149a033

10.1021/j100122a013

10.1080/14786442608564083

10.1016/1010-6030(93)03718-V

Thông tin
Thông tin xuất bản

Macromolecular Chemistry and Physics

Tập 196 Số 3

739-749

Thông tin tác giả