Synthesis and Characterization of Fe3O4 Nanoparticles Using Prunus serrulata Leaf Extract
Tóm tắt
The interest in the green synthesis of nanoparticles has significantly increased in the last decade as an alternative approach to chemical nanoparticle synthesis. Green synthesis is a technique that produces highly valuable matter by minimizing hazardous chemicals and using environmentally friendly, low-cost, and energy-saving materials, such as plant-based, industrial wastes, and recycled substances. This study aimed to control and understand the synthesis of iron oxide nanoparticles (Fe3O4 NPs) using Prunus serrulata leaf extract as both reducing and capping agents. The mixing ratio between the Fe+3 solution and Prunus serrulata leaf extract, the concentration of Fe+3 solution, pH, and the temperature of the reaction were all varied to monitor particle size and morphology. The synthesized Fe3O4 NPs were characterized by several instrumental analyses including Fourier transform infrared attached with attenuated total reflectance (FT-IR), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Optimum conditions for the synthesized Fe3O4 NPs were determined as 3:1 (Fe+3 solution:Prunus serrulata leaf extract) mixing ratio, 10 mM Fe+3 precursor, pH 6, and 25 °C reaction temperature. Therefore, the synthesized Fe3O4 NPs under optimum conditions were spherical with an average particle size of ~40 nm.
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