Syntheses, Structures, and Luminescence Properties of Two Copper(II) Complexes Constructed by Rigid Bis(triazole) and Nitrogen‐containing Carboxylic Acid Ligands

Bulletin of the Korean Chemical Society - Tập 36 Số 7 - Trang 1848-1853 - 2015
Xiaoxiao Wang1, Zuo‐Xi Li2, Baoyi Yu3, Kristof Van Hecke3, Guang‐Hua Cui1
1College of Chemical Engineering Hebei United University Tangshan 063009 P.R. China
2Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science Northwest University Xi'an 710069 P. R. China
3Department of Inorganic and Physical Chemistry Ghent University Ghent B-9000 Belgium

Tóm tắt

Two new copper(II) complexes with the formulas [Cu(btb)(pydc)(H2O)]n (1) and [Cu(btb)0.5(nph)(H2O)]n (2) have been synthesized under hydrothermal conditions by employing a rigid bis(triazole) ligand (btb = 4,4′‐bis(1,2,4‐triazolyl‐1‐yl)‐biphenyl) and two carboxylic acids mixed ligands (H2pydc = pyridine‐2,5‐dicarboxylic acid and H2nph = 3‐nitrophthalic acid). The copper atoms present different environments, with a tetragonal pyramidal geometry in 1 and octahedral configuration in 2. Complex 1 displays a dinuclear cluster, which is further packed into a 2D supramolecular layer by classical OH · · · O hydrogen bonds. Complex 2 possesses a trinodal 3,4,4‐connected 3D framework with a rare sqc69 topology. In addition, thermal stability and luminescence property were investigated.

Từ khóa


Tài liệu tham khảo

10.1039/C4CS00106K

10.1021/cr200205j

10.1021/ic402467g

10.1039/C4RA08138B

10.5012/bkcs.2014.35.2.651

10.1016/j.ica.2012.07.033

10.1016/S0020-1693(02)00837-X

10.1021/ic035370d

10.1021/cg500371n

10.1039/c2ce25677k

10.5012/bkcs.2013.34.10.3133

10.1021/cg200261j

10.1016/j.inoche.2015.01.030

10.1039/C3CE41974F

10.1016/j.ccr.2012.10.002

10.5012/bkcs.2013.34.6.1891

10.1021/cg400579w

10.1002/chem.200400332

Sheldrick G. M., 1996, SADABS

10.1107/S0108767390000277

10.1039/B617136B

10.1016/j.inoche.2013.10.017

10.1021/cg500498k

10.1021/ic902241n

10.1016/j.poly.2014.04.038

10.1039/b811855h

10.1016/j.molstruc.2014.04.037

Nakamoto K., 1986, Infrared Spectra and Raman Spectra of Inorganic and Coordination Compounds

10.1021/cg100688z

10.1039/b916280c

Thông tin
Thông tin xuất bản

Bulletin of the Korean Chemical Society

Tập 36 Số 7

1848-1853

Thông tin tác giả