Surface microtopography of metamorphic white micas

Physics and Chemistry of Minerals - Tập 5 - Trang 65-81 - 1979
Shinji Tomura1, Masao Kitamura1, Ichiro Sunagawa1
1Institute of Mineralogy, Petrology and Economic Geology, Tohoku University, Sendai, Japan

Tóm tắt

Gold decoration and platinum-carbon-shadowing techniques of electron microscopy have been applied to study the surface microtopographs of noncleavage (001) faces of porphyroblastic white micas and sericite crystals collected from the chlorite, biotite, and garnet zones in the Shiragayama area in the Sanbagawa metamorphic terrain, Shikoku, Japan. Two different types of surface microtopograph have been observed; parallel step system and saw-tooth step system. The former is interpreted as representing the surface microtopographs formed either by growth or under near equilibrium conditions, the latter either by dissolution or under rigorous kinetic conditions. The former has been observed on porphyroblastic white micas occurring in the middle portion of each metamorphic zone and on all sericite crystals, the latter on most sericites and on porphyroblastic white micas occurring along the boundaries of the neighboring metamorphic zones. It is suggested that the observed variations in the surface microtopographic characteristics are due to Ostwald ripening during a kind of sintering process in which interstitial water plays an essential role, and that the drastic changes along the metamorphic zone boundaries are due to dehydration reactions. Retrogressive metamorphism is considered to have an almost negligible effect, if any, upon the surface microtopographs.

Tài liệu tham khảo

Baronnet, A.: Growth mechanism and polytypism in synthetic hydroxyl-bearing phlogopite. Am. Mineralogist 57, 1272–1293 (1972) Baronnet, A.: Polytypism et polymorphisme dans les micas contribution a l'étude du role de la croissance cristalline. Marseilles: Dr. Es-Sci. Thesis 1976 Baronnet, A.: Some aspects of polytypism in crystals. Prog. Crys. Growth Charact. 1, 151–211 (1978) Bassett, G.: A new technique for decoration of cleavage and slip steps on ionic crystal surface. Phil. Mag. 3, 1042–1043 (1958) Bethge, H.: Oberflächenstrukturen und Kirstallbaufehler im elektronenmikroskopischen Bild, untersucht am NaCl. Phys. Status Solidi 2, 3–27 (1962) Bethge, H.: Electron-microscopic investigations of the molecular processes, during evaporation and growth of crystals. J. Cryst. Growth 1, 623–627 (1967) Bethge, H., Keller, K. W., Zieghr, E.: Molecular process during crystal growth from the vaporphase. J. Cryst. Growth 3,4, 184–187 (1968) Brauer, K.H.: Ätzresultate an Kristallen der Glimmergruppe. Berlin: Akademie-Verlag 1971 Gritsaenko, G., Samotoyin, N.: The decoration method applied to the study of clay minerals. Vol. 3. Jerusalem, Israel: Proc. Internat. Clay Conf. 1966, pp. 391–400 Higashino, T.: Biotite zone of Sanbagawa metamorphic terrain in the Siragayama area, central Shikoku, Japan (in Japanease). J. Geol. Soc. Japan 81, 653–670 (1975) Itaya, T.: Pyrrhotite from the Sanbagawa pelitic schists of the Shiraga-yama area, central Shikoku, Japan. Mineral. J. (Japan) 8, 25–37 (1975) Kawachi, Y.: Large-scale overturned structure in the Sanbagawa metamorphic zone in central Shikoku, Japan. J. Geol. Soc. Japan 74, 607–616 (1968) Keller, K. W.: Surface Microstructures and Processes of Crystal Growth Observed by Electron Microscopy. In: Crystal growth and characterization, Ueda, R., Mullin, J.B. (eds.). Amsterdam: North-Holland 1975, pp. 361–372 Kihara, K., Matsumoto, T., Banno, S.: Existance of 3T muscovite in low grade metamorphic rocks of the Sanbagawa metamorphic belt, Japan. Mineral. Mag. 40, 202–205 (1975) Kurata, H.: Local chemical heterogeneity of chlorites in Sanbagawa pelitic schists from Sazare area, central Shikoku. J. Geol. Soc. Japan 78, 653–657 (1972) Kurata, H., Banno, S.: Low-grade progressive metamorphism of pelitic schists of the Sazare area, Sanbagawa metamorphic terrain in central Shikoku, Japan. J. Petrol. 15, 361–382 (1974) Mimuro, Y.: Muscovites from low-grade Sanbagawa schists in central Shikoku. Kanazawa Univ.: MSc. Thesis 1971 Sato, H.: Microstructure of mica cleavage surfaces (in Japanease). J. Japan Assoc. Mineral. Petrol. Econ. Geol. 64, 192–198 (1970) Shirozu, H., Bailey, S. W.: Chlorite polytypism III, Crystal structure of an ortho-hexagonal iron chlorite. Am. Mineral. 50, 868–885 (1965) Strübel, G.: Hydrothermal Löslichkeit und Auflösungsverhalten von Muskovit. Giessen: Lenz 1974 Sunagawa, I.: Mechanism of natural etching of hematite crystals. Am. Mineral. 47, 1332–1345 (1962) Sunagawa, I.: Natural crystallization. J. Cryst. Growth 42, 214–223 (1977) Sunagawa, I.: Vapour growth and epitaxy of minerals and synthetic crystals. J. Cryst. Growth 45, 3–13 (1978) Sunagawa, I., Koshino, Y.: Growth spirals on kaolin group minerals. Am. Mineral. 60, 401–412 (1975) Sunagawa, I., Koshino, Y., Asakura, M., Yamamoto, T.: Growth mechanism of some clay minerals. Fortschr. Mineral. 52, 217–224 (1975)