Surface-analytical Studies on Environmental and Geochemical Surface Processes

Analytical Sciences - Tập 19 - Trang 487-497 - 2003
Haruhiko Seyama1, Mitsuyuki Soma2
1Environmental Chemistry Division, National Institute for Environmental Studies, Tsukuba, Ibaraki, Japan
2Institute for Environmental Sciences, University of Shizuoka, Shizuoka, Japan

Tóm tắt

The surface chemical compositions of solid samples from environmental and geological sources can differ from the bulk or average compositions, because of changes caused by adsorption, dissolution, oxidation, etc. Accordingly, analytical information on surface layers is important for a better understanding of the environmental chemistry involving solid surfaces. The rapid development of surface-analytical techniques has enabled us to probe the surface chemistry of environmental and geological solid samples of complex composition. This article demonstrates some examples of important items of information that can be obtained by applying surface-analytical techniques, such as X-ray photoelectron spectroscopy and secondary ion mass spectrometry, to environmental and geological samples. The surface analysis of fly ashes, soils, sediments and weathered silicate minerals is reviewed.

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