Supramolecular assembly of leaf-like fluorescent tetraphenylethylene through polymer-directed inter-locking

Lehn, 1988, Supramolecular chemistry -scope and perspectives molecules, supermolecules, and molecular devices, Angew. Chem. Int. Ed., 27, 89, 10.1002/anie.198800891 Aida, 2012, Functional supramolecular polymers, Science, 335, 813, 10.1126/science.1205962 Stupp, 2014, Supramolecular chemistry and self-assembly in organic materials design, Chem. Mater., 26, 507, 10.1021/cm403028b Zhang, 2009, Vesicular perylene dye nanocapsules as supramolecular fluorescent pH sensor systems, Nat. Chem., 1, 623, 10.1038/nchem.368 Zhang, 2014, Tetraphenylethylene-based expanded oxacalixarene: synthesis, structure, and its supramolecular grid assemblies directed by guests in the solid state, J. Org. Chem., 79, 2729, 10.1021/jo402884a Gao, 2017, Fluorescent sensors based on aggregation-induced emission: recent advances and perspectives, ACS Sens., 2, 1382, 10.1021/acssensors.7b00551 Song, 2014, Microtubes and hollow microspheres formed by winding of nanoribbons from self-assembly of tetraphenylethylene amide macrocycles, Chem. Commun., 50, 15212, 10.1039/C4CC05390G Li, 2013, Control of aggregation-induced emission by DNA hybridization, Chem. Commun., 49, 5835, 10.1039/c3cc42706d Zhao, 2014, Anion-coordination-induced turn-on fluorescence of an oligourea-functionalized tetraphenylethene in a wide concentration range, Angew. Chem. Int. Ed., 53, 6632, 10.1002/anie.201402169 Yao, 2014, Catalyst-free thiol-yne click polymerization: a powerful and facile tool for preparation of functional poly(vinylene sulfide)s, Macromolecules, 47, 1325, 10.1021/ma402559a Qu, 2017, Molecular face-rotating cube with emergent chiral and fluorescence properties, J. Am. Chem. Soc., 139, 18142, 10.1021/jacs.7b07657 Dalapati, 2016, Highly emissive covalent organic frameworks, J. Am. Chem. Soc., 138, 5797, 10.1021/jacs.6b02700 Zhang, 2015, A porous tricyclooxacalixarene cage based on tetraphenylethylene, Angew. Chem. Int. Ed., 54, 9244, 10.1002/anie.201502912 Tanaka, 1987, Mechanical instability of gels at the phase transition, Nature, 325, 796, 10.1038/325796a0 Khang, 2009, Mechanical buckling: mechanics, metrology, and stretchable electronics, Adv. Funct. Mater., 19, 1526, 10.1002/adfm.200801065 Bowden, 1998, Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer, Nature, 393, 146, 10.1038/30193 Tong, 2007, Aggregation-induced emission: effects of molecular structure, solid-state conformation, and morphological packing arrangement on light-emitting behaviors of diphenyldibenzofulvene derivatives, J. Phys. Chem. C, 111, 2287, 10.1021/jp0630828 Zhang, 2017, Why do simple molecules with “isolated” phenyl rings emit visible light?, J. Am. Chem. Soc., 139, 16264, 10.1021/jacs.7b08592 He, 2018, Journey of aggregation-induced emission research, ACS Omega, 3, 3267, 10.1021/acsomega.8b00062 Sturala, 2017, Excited-state aromatic interactions in the aggregation-induced emission of molecular rotors, J. Am. Chem. Soc., 139, 17882, 10.1021/jacs.7b08570 Zhu, 2015, Insight into the strong aggregation-induced emission of low-conjugated racemic C6-unsubstituted tetrahydropyrimidines through crystal-structure–property relationship of polymorphs, Chem. Sci., 6, 4690, 10.1039/C5SC01226K Yin, 2010, Solution-processable flower-shaped hierarchical structures: self-assembly, formation, and state transition of biomimetic superhydrophobic surfaces, Chem. Eur. J, 16, 7309, 10.1002/chem.201000332 Shimizu, 2005, Supramolecular nanotube architectures based on amphiphilic molecules, Chem. Rev., 105, 1401, 10.1021/cr030072j Frankel, 1994, Supramolecular assemblies of diacetylenic aldonamides, J. Am. Chem. Soc., 116, 10057, 10.1021/ja00101a026 Frisch, 2009