Sulfur isotope microanalysis of sphalerite by SIMS: constraints on the genesis of Mississippi valley-type mineralization, from the Mascot-Jefferson City district, East Tennessee

Anderson, 1973, The hydrothermal transport and deposition of galena and sphalerite near 100 degrees C, Econ. Geol., 68, 480, 10.2113/gsecongeo.68.4.480 Anderson, 1975, Precipitation of Mississippi Valley-type ores, Econ. Geol., 70, 937, 10.2113/gsecongeo.70.5.937 Anderson, 1983, Some geochemical aspects of sulfide precipitation in carbonate rocks, 61 Anderson, 1991, Organic maturation and ore precipitation in Southeast Missouri, Econ. Geol., 86, 909, 10.2113/gsecongeo.86.5.909 Anderson, 1982, Ore deposit models; 6 Mississippi Valley-type lead–zinc deposits, Geosci. Can., 9, 108 Appold, 1995, Sulfur isotope and fluid inclusion constraints on the genesis of Mississippi valley-type mineralization in the central Appalachians, Econ. Geol., 90, 909, 10.2113/gsecongeo.90.4.902 Barnes, 1983, Ore-depositing reactions in Mississippi valley-type deposits, 77 Barton, 1967, Possible role of organic matter in the precipitation of the Mississippi valley ores, 371 Beales, 1975, Precipitation mechanisms for Mississippi Valley-type ore deposits, Econ. Geol., 7, 943, 10.2113/gsecongeo.70.5.943 Caless, J.R., 1983. Geochemistry and paragenesis of sphalerite mineralization in the East Tennessee zinc district. PhD dissertation, Virginia Polytechnic Institute, Blacksburg. Cathless, 1983, Thermal constraints on the formation of Mississippi valley-type lead–zinc deposits and their implications for episodic basin dewatering and deposit genesis, Econ. Geol., 78, 983, 10.2113/gsecongeo.78.5.983 Churnet, 1983, Sphalerite mineralization and its relationship to carbonate facies boundaries, Copper Ridge District, East Tennessee, 360 Claypool, 1980, The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation, Chem. Geol., 28, 19 Craig, 1983, Growth characteristics of sphalerites in Appalachian zinc deposits, 317 Crawford, J., Fulweiler, R.E., Miller, H.W., 1969. Mine geology of the New Jersey Zinc Company's Jefferson City mine: papers on the stratigraphy and mine geology of the Kingsport and Mascot Formations (Lower Ordovician) of East Tennessee. Tennessee Division of Geology Report of Investigations, Tennessee Division of Geology, Nashville, Tennessee, vol. 23, pp. 64–75. Crocetti, 1989, Sulfur-lead isotope systematics and the composition of fluid inclusions in galena from the Viburnum Trend, Missouri, Econ. Geol., 84, 2196, 10.2113/gsecongeo.84.8.2196 Crowe, 1996, Characterization and use of isotopically homogeneous standards for in situ laser microprobe analysis of 34S/32S ratios, Am. Mineral., 81, 187, 10.2138/am-1996-1-223 Cumming, 1969, Isotopic composition of lead from the Pine Point deposit, Econ. Geol., 64, 731, 10.2113/gsecongeo.64.7.731 Deloule, 1986, Lead and sulfur isotope microstratigraphy in galena crystals from Mississippi Valley-type deposits, Econ. Geol., 81, 1307, 10.2113/gsecongeo.81.6.1307 Ebers, 1979, Cathodoluminescent microstratigraphy in gangue dolomite, the Mascot-Jefferson City district, Tennessee, Econ. Geol., 74, 908, 10.2113/gsecongeo.74.4.908 Foley, N.K., 1980. Mineralogy and geochemistry of the Austinville-Ivanhoe district, Wythe County, Virginia. MS Thesis, Virginia Polytechnic Institute and University, Blacksburg. Foley, 1981, Isotopic composition of lead in the Austinville-Ivanhoe Pb–Zn district, Virginia, Econ. Geol., 76, 2012, 10.2113/gsecongeo.76.7.2012 Garven, 1985, The role of regional fluid flow in the genesis of the Pine Point deposit, Western Canada sedimentary basin, Econ. Geol., 80, 307, 10.2113/gsecongeo.80.2.307 Garven, 1984, Theoretical analysis of the role of groundwater flow in the genesis of stratabound or deposits: 1. Mathematical and numerical model, Am. J. Sci., 284, 1085, 10.2475/ajs.284.10.1085 Giordano, 1985, A preliminary evaluation of organic ligands and metal-organic complexing in Mississippi valley-type ore solutions, Econ. Geol., 80, 96, 10.2113/gsecongeo.80.1.96 Giordano, 1979, Ore solution chemistry VI; PbS solubility in bisulfide solutions to 300 degrees C, Econ. Geol., 74, 1637, 10.2113/gsecongeo.74.7.1637 Gize, 1987, The organic geochemistry of two Mississippi valley-type lead–zinc deposits, Econ. Geol., 82, 457, 10.2113/gsecongeo.82.2.457 Harris, 1971, A lower paleozoic paleoaquifer—the Kingsport Formation and mascot dolomite of Tennessee and southwest Virginia, Econ. Geol., 66, 735, 10.2113/gsecongeo.66.5.735 Haynes, 1987, Chemical evolution of brines during Mississippi valley-type mineralization; evidence from East Tennessee and Pine Point, Econ. Geol., 82, 53, 10.2113/gsecongeo.82.1.53 Haynes, 1989, Simultaneous transport of metal and reduced sulfur, Mascot-Jefferson City zinc district, East Tennessee, evidence from fluid inclusions, Am. J. Sci., 289, 994, 10.2475/ajs.289.8.994 Helgeson, 1969, Thermodynamics of hydrothermal systems at elevated temperatures and pressures, Am. J. Sci., 267, 729, 10.2475/ajs.267.7.729 Hill, W.T., 1971. The geology, applied geochemistry, and drilling results in the Puncheon Camp creek area, Grainger County, Tennessee. PhD dissertation, University of Tennessee, Knoxville. Hoagland, 1965, Genesis of the Ordovician zinc deposits in East Tennessee, Econ. Geol., 60, 693, 10.2113/gsecongeo.60.4.693 Jackson, 1967, An aspect of sedimentary basin evolution: the concentration of Mississippi Valley-type ores during late stages of diagenesis, Can. Petrol. Geol. Bull., 15, 483 Jones, H.D., 1993. Geochemical and sulfur isotopic investigations into the origins of Mississippi Valley-type mineralization in the southern Appalachians and nearby areas. Unpublished PhD dissertation, University of Michigan, Ann Arbor. Jones, 1992, Fluid inclusion gas chemistry in East Tennessee Mississippi Valley-type districts' evidence or immiscibility and implications for depositional mechanisms, Geochim. Cosmochim. Acta, 56, 137, 10.1016/0016-7037(92)90122-Y Kesler, 1988, Strontium isotopic geochemistry of Mississippi valley-type deposits, East Tennessee; implications for age and source of mineralizing brines, Geol. Soc. Amer. Bull., 100, 1300, 10.1130/0016-7606(1988)100<1300:SIGOMV>2.3.CO;2 Kesler, 1994, Role of crude oil in the genesis of Mississippi Valley-type deposits; evidence from the Cincinnati arch, Geology, 22, 609, 10.1130/0091-7613(1994)022<0609:ROCOIT>2.3.CO;2 Kessen, 1981, Gangue mineral (super 87) Sr/(super 86) Sr ratios and the origin of Mississippi valley-type mineralization, Econ. Geol., 76, 913, 10.2113/gsecongeo.76.4.913 Kettler, R.M., 1990. Organic matter in hydrothermal systems: implications for fluid chemistry and source. PhD dissertation, University of Michigan, Ann Arbor, pp. 169–212. Kharaka, 1986, Role of organic species dissolved in formation waters from sedimentary basins in mineral diagenesis, 38, 111 Kiyosu, 1990, The role of organic acid in the abiogenic reduction of sulfate and the sulfur isotope effect, Geochem. J., 24, 21, 10.2343/geochemj.24.21 Layne, 1991, Microscale lead and sulfur isotope zonation in hydrothermal sulfides by ion microprobe; new findings from the Mississippi valley-type Pb–Zn deposits of the Viburnum Trend, S.E. Missouri, Geol. Soc. Amer. Abs., 23, 101 Leshin, 1998, Oxygen isotopic constraints on the genesis of carbonates from Martian meteorite ALH84001, Geochim. Cosmochim. Acta, 62, 3, 10.1016/S0016-7037(97)00331-1 Leventhal, 1990, Organic matter and thermochemical sulfate reduction in the Viburnum Trend, Southeast Missouri, Econ. Geol., 85, 622, 10.2113/gsecongeo.85.3.622 Lyon, 1994, High spatial resolutions measurements of delta (super 18) O in authigenic quartz overgrowths, Mineral. Mag., 58A, 545, 10.1180/minmag.1994.58A.2.21 Machel, 1989, Relationships between sulphate reduction and oxidation of organic compounds to carbonate diagenesis, hydrocarbon accumulations, salt domes, and metal sulphide deposits, 4, 137 Machel, 1995, Products and distinguishing criteria of bacterial and thermochemical sulfate reduction, Appl. Geochem., 10, 373, 10.1016/0883-2927(95)00008-8 McCormick, 1971, Environment of the zinc deposits of Mascot-Jefferson City district, Tennessee, Econ. Geol., 66, 757, 10.2113/gsecongeo.66.5.757 McKibben, 1995, Microscopic sulfur isotope variations in ore minerals from the Viburnum Trend, Southeast Missouri: a SHRIMP study, Econ. Geol., 90, 228, 10.2113/gsecongeo.90.2.228 Misra, 2001, 604 Nakai, 1990, Rb–Sr dating of sphalerites from Mississippi valley type (MVT) deposits, vol. 27, 69 Nakai, 1993, Rb–Sr dating of sphalerites from Mississippi Valley-type (MVT) ore deposits, Geochim. Cosmochim. Acta, 57, 417, 10.1016/0016-7037(93)90440-8 Ohmoto, 1972, Systematics of sulfur and carbon isotopes in hydrothermal ore deposits, Econ. Geol., 67, 551, 10.2113/gsecongeo.67.5.551 Ohmoto, 1986, Stable isotope geochemistry of ore deposits, vol. 16, 491 Ohmoto, 1997, Sulfur and carbon isotopes, 517 Ohmoto, 1979, Isotopes of sulfur and carbon, 509 Olson, 1984, Genesis of paleokarst and strata-bound zinc–lead sulfide deposits in a Proterozoic dolostone, northern Baffin Island, Canada, Econ. Geol., 79, 1056, 10.2113/gsecongeo.79.5.1056 Riciputi, 1996, A comparison of extreme energy filtering and high mass resolution techniques for the measurement of 34S/32S ratio by ion microprobe, Rapid Commun. Mass Spectrom., 10, 282, 10.1002/(SICI)1097-0231(199602)10:3<282::AID-RCM464>3.0.CO;2-6 Roedder, 1971, Fluid-inclusion evidence on the environment of formation of mineral deposits of the southern Appalachian valley, Econ. Geol., 66, 777, 10.2113/gsecongeo.66.5.777 Roedder, 1968, Sphalerite color banding: lack of correlation with iron content, Pine Point, Northwest territories, Canada, Am. Mineral., 53, 1523 Sakai, 1968, Isotopic properties of sulfur compounds in hydrothermal processes, Geochem. J., 2, 29, 10.2343/geochemj.2.29 Sangster, 1983, Mississippi valley-type deposits; a geological melange, 7 Sasaki, 1969, Sulfur isotopes and the Pine Point lead–zinc mineralization, Econ. Geol., 64, 718, 10.2113/gsecongeo.64.7.718 Shanmugam, 1982, Analogous tectonic evolution of the Ordovician foredeeps. Southern and central Appalachians, Geology, 10, 562, 10.1130/0091-7613(1982)10<562:ATEOTO>2.0.CO;2 Shimizu, 1982, Applications of the ion microprobe to geochemistry and cosmochemistry, Annu. Rev. Earth Planet. Sci., 10, 483, 10.1146/annurev.ea.10.050182.002411 Strauss, 1997, The isotopic composition of sedimentary sulfur through time, Palaeogeogr. Palaeoclimatol. Paleoecol., 132, 97, 10.1016/S0031-0182(97)00067-9 Sverjensky, 1981, The origin of a Mississippi valley-type deposit in the Viburnum Trend, Southeast Missouri, Econ. Geol., 76, 1848, 10.2113/gsecongeo.76.7.1848 Sverjensky, 1984, Oil field brines as ore-forming solutions, Econ. Geol., 79, 23, 10.2113/gsecongeo.79.1.23 Taylor, 1983, Fluid inclusion evidence for fluid mixing, Mascot-Jefferson City Zinc district, Tennessee, Econ. Geol., 78, 1425, 10.2113/gsecongeo.78.7.1425 Thode, Monster, 1973. Sulfur isotope geochemistry of petroleum, evaporites, and ancient seas. Marine Evaporites; origin, diagenesis and geochemistry. Dowden, Hutchinson and Ross, pp. 363–373. Valley, J.W., Graham, C.M., 1991. Ion microprobe analyses of oxygen isotopes in magnetite and ilmenite. Eos Trans. Amer. Geophys. Un. 72, 17, 292. Valley, 1997, Ion microprobe analysis of oxygen and carbon isotope ratios in the ALH84001, Lunar Planet. Sci. Conf. Abs., 1475 Walker, 1990, Early diagenetic history controls burial alteration; comparison of Cambrian and Ordovician carbonates in the S. Appalachians, U.S.A., vol. 13, 582 Williams, 1979, Sedimentology, stable-isotope geochemistry and paleo-environment of dolostones capping late Precambrian glacial sequences in Australia, J. Geol. Soc. Aust., 26, 377, 10.1080/00167617908729104 Yu, M.L., Lang, N., 1986. Mechanisms of atomic ion emission during sputtering. Nuclear Instruments and Methods in Physics Research, 14, 403, 413. Zimmerman, 1981, Fluid inclusion evidence for solution mixing, Sweetwater (Mississippi Valley-type) district, Tennessee, Econ. Geol., 76, 134, 10.2113/gsecongeo.76.1.134