Sulfur-doped carbon quantum dots and derived 3D carbon nanoflowers are effective visible to near infrared fluorescent probes for hydrogen peroxide

Microchimica Acta - Tập 184 - Trang 2055-2062 - 2017
Huicong Yang1, Feiming Li2, Chuze Zou3, Qitong Huang2,4, Dejian Chen2,5
1Department of Clinical Laboratory, Zhangzhou Affiliated Hospital of Fujian Medical University, Zhangzhou, China
2College of Chemistry and Environment, Minnan Normal University, Zhangzhou, People’s Republic of China
3Department of Bioscience and Bioengineering, Hebei University of Science and Technology, Shijiazhuang, China
4Department of Food and Biological Engineering, Zhangzhou, China
5State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China

Tóm tắt

Near-infrared photoluminescence is intrinsic only to a minority of carbonaceous nanomaterials. Longwave fluorescence is, however, well suited for bio-sensing and bio-imaging owing to the low autofluorescence and low absorbance by biomatter. The authors describe here sulfur doped carbon quantum dots (S-CQDs) and their derivatives (referred to as 3D carbon nanoflowers; S-CNFs). Their average diameters are 2 and 28.5 nm, respectively. They display two emission peaks, one being purple and peaking at 407 nm, the other in the near-infrared and peaking at 780 nm. Quantum yields are 4% for S-CQDs and 6.4% for S-CNFs. The nanoparticles are shown to be viable fluorescent probes for hydrogen peroxide which acts as a quencher. The 3D structure of the S-CNFs and near-infrared detection result in a better linear relationship and lower detection limits. The detection limits for H2O2 are 1.1 μM for S-CQDs, and 0.6 μM for S-CNFs. The results presented here contribute to an improved understanding on how the nanostructure and selection of wavelengths affect the sensitivity and detection limits of such probes.

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