Structure and Mössbauer Spectrum of a (μ-1,2-Peroxo)bis(μ-carboxylato)diiron(III) Model for the Peroxo Intermediate in the Methane Monooxygenase Hydroxylase Reaction Cycle

Feig A. L., 1994, J. Chem. Rev, 94, 805

Crabtree R. H, 1995, Chem. Rev, 95, 1007

Rosenzweig A., 1995, J. Chem. Biol, 2, 418

Lipscomb J. D, 1994, Annu. Rev. Microbiol, 48, 399, 10.1146/annurev.mi.48.100194.002103

Liu, K. E.; Lippard, S. J. InAdvances in Inorganic Chemistry; Sykes, A. G., Ed.; Academic Press, Inc.  San Diego, CA, 1995; Vol. 42, pp 263−289.

Liu K. E., 1995, J. Am. Chem. Soc, 117, 10185

Liu K. E., 1995, J. Am. Chem. Soc, 117, 4998

While, 1996, Angew. Chem., Int. Ed. Engl, 35, 620, 10.1002/anie.199606201

Ookubo T., 1996, J. Am. Chem. Soc, 118, 702, 10.1021/ja953705n

Kitajima N., 1994, J. Am. Chem. Soc, 116, 9085

Fe, V = 4,223(3) Å3 at −150 °C with Z = 4

The compound 2[Fe2(μ-1,2-O2)(μ-O2CCH2Ph)2{HB(pz‘)3}2]·0.5CH2Cl2·0.5(i-Pr2O)·2.5C5H12crystallized in space groupP21/n,a= 17.222(4) Å,b= 24.206(4) Å,c= 45.449(10) Å, β = 96.198(11)°,V= 18 836(7) Å3at −150 °C withZ= 4. Data were collected on a Siemens SMART diffractometer equipped with a CCD detector and Mo Kα radiation. With the use of 23 205 reflections, the structure was refined to a conventionalRvalue (I> 2σ(I)) of 0.142. This high residual reflects poor crystal quality (>100 crystals were examined and 4 complete data sets were collected), a large unit cell (1801 parameters), high solvent content, and solvent disorder. Details are available as supporting information.

Micklitz W., 1989, J. Am. Chem. Soc, 111, 374, 10.1021/ja00183a061

Menage S., 1990, J. Am. Chem. Soc, 112, 6425, 10.1021/ja00173a055

Brennan B. A., 1991, Inorg. Chem, 30, 1943, 10.1021/ic00008a048