Structural parameters of Cu2+ aqua complexes in aqueous solutions of its salts

Russian Journal of General Chemistry - Tập 79 - Trang 1591-1599 - 2009
P. R. Smirnov1, V. N. Trostin1
1Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

Tóm tắt

Published data of various research techniques and own experimental results obtained by the X-ray structural analysis concerning structural characteristics of copper(II) aqua complexes in aqueous solutions of its salts under standard conditions have been generalized. Structural parameters of the nearest environment of this ion, such as coordination number, interparticle distances, and ionic association types, were considered. The possibility of the Jahn-Teller effect realization in aqueous solutions of Cu2+ salts was examined.

Tài liệu tham khảo

Smirnov, P.R. and Trostin, V.N., Zh. Obshch. Khim., 2006, vol. 76, no. 2, p. 187. Smirnov, P.R. and Trostin, Zh. Obshch. Khim., 2007, vol. 77, no. 5, p. 745. Smirnov, P.R. and Trostin, V.N., Zh. Obshch. Khim., 2007, vol. 77, no. 12, p. 1955. Marcus, Y., Chem. Rev., 1988, vol. 88, no. 8, p. 1475. Ohtaki, H. and Radnai, T., Chem. Rev., 1993, vol. 93, no. 3, p. 1157. de Almeida, K.J., Rinkevicius, Z., Hugosson, H.W., Ferreira, A.C., and Ågren, H., Chem. Phys., 2007, vol. 332,nos. 2–3, p. 176. Marques, M.A., Marques, M.I. de B., Cabaɛo, M.I., Gaspar, A.M., and de Almeida, M.L., J. Mol. Liq., 2004, vol. 110,nos. 1–3, p. 23. Schwenk, C.F. and Rode, B.M., J. Am. Chem. Soc., 2004, vol. 126, no. 40, p. 12786. Jayanetti, S., Mayanovic, R.A., Anderson, A.J., Bassett, W.A., and Chou, I-M., J. Chem. Phys., 2001, vol. 115, no. 2, p. 954. Marini, G.W., Liedl, K.R., and Rode, B.M., J. Phys. Chem., A, 1999, vol. 103, no. 51, p. 11387. Ochiai, E., Bioinorganic Chemistry. An Introduction, Allyn and Bacon, 1977. Rode, B.M. and Suwannachot, Y., Coord. Chem. Reviews, 1999, vols. 190–192, p. 1085. Rode, B.M. and Schwendinger, M.G., Orig. Life, 1990, vol. 20, p. 401. Tauler, R. and Rode, B.M., Inorg. Chim. Acta, 1990, vol. 173, p. 93. Salmon, P.S., Howells, W.S. and Mills, R., J. Phys. C: Solid State Phys., 1987, vol. 20, no. 34, p. 5727. Poupko, R. and Luz, Z., J. Chem. Phys., 1972, vol. 57, no. 8, p. 3311. Shapovalov, I.M. and Radchenko, I.V., Zh. Strukt. Khim., 1971, vol. 12, no. 5, p. 769. Fishkis, M.N. and Zhmak, V.A., Zh. Strukt. Khim., 1974, vol. 15, no.1, p. 3. Ohtaki, H., Yamaguchi, T., and Maeda, M., Bull. Chem. Soc. Japan, 1976, vol. 49, no. 3, p. 701. Musinu, A., Paschina, G., Piccaluga, G., and Magini, M., Inorg. Chem., 1983, vol. 22, no. 8, p. 1184. Bell, J.R., Tyvoll, J.L., and Wertz, D.L., J. Am. Chem. Soc., 1973, vol. 95, no. 5, p. 1456. Skryshevskii, A.F., Strukturnyi analiz zhidkostei i amorfnykh tel (Structural Analysis of Liquids and Amorphous Bodies), Moscow: Vysshaya Shkola, 1980. Magini, M., J. Chem. Phys., 1981, vol. 74, no. 4, p. 2525. Neilson, G.W., J. Phys. C: Solid State Phys., 1982, vol. 15, no. 1, p. 233. Rode, B.M. and Islam, S.M., J. Chem. Soc., Faraday Trans., 1992, vol. 88, no. 3, p. 417. D’Angelo, P., Bottari, E., Festa, M.R., Noltig, H.-F., and Pavel, N.V., J. Chem. Phys., 1997, vol. 107, no. 8, p. 2807. Ansell, S., Tromp, R.H., and Neilson, G.W., J. Phys. Condens. Matter., 1995, vol. 7, no. 8, p. 1513. Texler, N.R., Holdway, S., Neilson, G.W., and Rode, B.M., J. Chem. Soc., Faraday Trans., 1998, vol. 94, no. 1, p. 59. Eisenberger, P. and Kincaid, B.M., Chem. Phys. Lett., 1975, vol. 36, no. 1, p. 134. Fontaine, A., Lagarde, P., Raoux, D., Fontana, M.P., Maisano, G., Migliardo, P., and Wanderlingh, F., Phys. Rev. Lett., 1978, vol. 41, no. 7, p. 504. Ludwig, K., Warburton, W.K., and Fontain, A., J. Chem. Phys., 1987, vol. 87, no. 1, p. 620. Lagarde, P., Fontaine, A., Raoux, D., Sadoc, A., and Migliardo, P., J. Chem. Phys., 1980, vol. 72, no. 5, p. 3061. Ichihashi, M., Wakita, H., Mibuchi, T., and Masuda, I., Bull. Chem. Soc. Japan, 1982, vol. 55, no. 10, p. 3160. Filipponi, A., D’Angelo, P., Pavel, N.V., and Di Cicco, A., Chem. Phys. Lett., 1994, vol. 225, nos. 1–3, p. 150. Ohatki, H. and Maeda, M., Bull. Chem. Soc. Japan, 1974, vol. 47, no. 9, p. 2197. Magini, M., Inorg. Chem., 1982, vol. 21, no. 4, p. 1535. Sham, T.K., Hastings, J.B., and Perlman, M.L., Chem. Phys. Lett., 1981, vol. 83, no. 2, p. 391. Neilson, D.L., Newsome, J.R., and Sandstrom, M., J. Chem. Soc., Faraday Trans., 1981, vol. 77, no. 7, p. 1245. Tajiri, Y. and Wakita, H., Bull. Chem. Soc. Japan., 1986, vol. 59, no. 7, p. 2285. Nomura, N. and Yamaguchi, T., J. Phys. Chem., 1988, vol. 92, no. 21, p. 6157. Salmon, P.S., Neilson, G.W. and Enderby, J.E., J. Phys. C: Solid State Phys., 1988, vol. 21, no. 8, p. 1335. Licheri, G., Musinu, A., Paschina, G., Piccaluga, G., Pinna, G., and Sedda, A.F., J. Chem. Phys., 1984, vol. 80, no. 10, p. 5308. Beagley, B., Eriksson, A., Lindgren, J., Persson, I., Pettersson, L.G.M., Sandsrom, M., Wahlgren, U., and White, E.W., J. Phys. Condens. Matter., 1989, vol. 1, no. 13, p. 2395. Salmon, P.S. and Neilson, G.W., J. Phys. Condens. Matter., 1989, vol. 1, no. 31, p. 5291. Powell, D.H., Helm, L., and Merbach, A.E., J. Chem. Phys., 1991, vol. 95, no. 12, p. 9258. Chaboy, J., Muñoz-Páez, A., Merkling, P.J., and Sánchez Marcos, E., J. Chem. Phys., 2006, vol. 124, no. 6, p. 64509. Andreev, S.N. and Sapozhnikov, O.V., Dokl. Akad. Nauk SSSR, 1964, vol. 156, no. 4, p. 855. Texler, N.R. and Rode, B.M., J. Phys. Chem., 1995, vol. 99, no. 43, p. 15714. Texler, N.R. and Rode, B.M., Chem. Phys., 1997, vol. 222, no. 2, p. 281. Berces, A., Nukada, T., Margl, P., and Ziegler, T., J. Phys. Chem., A, 1999, vol. 103, no. 48, p. 9693. Schwenk, C.F. and Rode, B.M., Chemphyschem., 2003, vol. 4, no. 9, p. 931. Schwenk, C.F. and Rode, B.M., J. Chem. Phys., 2003, vol. 119, no. 18, p. 9523. Schwenk, C.F. and Rode, B.M., Chem. Commun., 2003, vol. 11, p. 1286. Borina, A.F., Koord. Khim., 2007, vol. 33, no. 11, p. 845. Pasquarello, A., Petri, I., Salmon, P.S., Parisel, O., Car, R., Toth, E., Powell, D.H., Fischer, H.E., Helm, L., and Merbach, A., Science, 2001, vol. 291, no. 5505, p. 856. Blumberger, J., Bernasconi, L., Tavernelli, I., Vuilleumier, R., and Sprik, M., J. Am. Chem. Soc., 2004, vol. 126, no. 12, p. 3928 Benfatto, M., D’Angelo, P., Della Longa, S., and Pavel, N.V., Phys. Rev., B, 2002, vol. 65, no. 17, p. 174205. Frank, P., Benfatto, M., Szilagyi, R.K., D’Angelo, P., Della Longa, S., and Hodgson, K.O., Inorg. Chem., 2005, vol. 44, no. 6, p. 1922. Amira, S., Spangberg, D., and Hermansson, K., Phys. Chem. Chem. Phys., 2005, vol. 7, no. 15, p. 2874. Bryantsev, V.S., Diallo, M.S., van Duin, A.C., and Goddard III, W.A., J. Phys. Chem., A, 2008, vol. 112, no. 38, p. 9104. Kritayakornupong, C., J. Comput. Chem., 2007, vol. 29, no. 1, p. 115. Vinogradov, E.V., Smirnov, P.R., and Trostin, V.N., Izv. Ross. Akad. Nauk, Ser. Khim., 2003, no. 6, p. 1186. Sukrat, K. and Parasuk, V., Chem. Phys. Lett., 2007, vol. 447,nos. 1–3, p. 58. Petrun’kin, S.P., Trostin, V.N., and Lyashchenko, A.K., Koord. Khim., 1992, vol. 18, no. 10, p. 1181. Smirnov, P.R. and Trostin, V.N., Struktura kontsentrirovannykh vodnykh rastvorov elektrolitov s kislorodsoderzhashchimi anionami (Structure of Concentrated Aqueous Solutions of Electrolytes with Oxygen-Containing Anions), Izd. IKhNR Ross. Akad. Nauk, 1994.