Structural effects on the enhancement of first-cycle Coulombic efficiency of mangrove-derived hard carbon as an anode material in sodium ion batteries

Springer Science and Business Media LLC - Tập 1 - Trang 1-7 - 2019
Koji Nakabayashi1,2, Chung Dabin1, Yujin Han1, Jemyung Oh3, Jin Miyawaki1,2, Seong-Ho Yoon1,2
1Department of Applied Science for Electronics and Materials, Kyushu University, Kasuga, Japan
2Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Japan
3Department of Materials Science & Engineering, Adama Science & Technoloy Unieversity, Adama, Ethiopia

Tóm tắt

The effects of material structure on the electrochemical performance of mangrove-derived hard carbon anodes in sodium ion batteries were closely examined. The size and distribution of micropores were controlled by adjusting the preheating step that chars green wood. The electrochemical properties of mangrove-derived hard carbon were significantly improved by optimizing the preheating conditions. Optimal performance, in terms of discharge capacity and first-cycle Coulombic efficiency, was observed following 7 days of preheating at 500 °C. We also examined the influence of ultra-micropore structure on the electrochemical properties of mangrove-derived anodes in SIBs.

Tài liệu tham khảo

Yabuuchi N, Kubota K, Dahbi M, Komaba S (2014) Research development on sodium-ion batteries. Chem Rev 114:11636–11682 Stevens DA, Dahn JR (2001) The mechanisms of lithium and sodium insertion in carbon materials. J Electrochem Soc 148:A803–A811 Fey GTK, Chen KL, Chang YC (2002) Effects of surface modification on the electrochemical performance of pyrolyzed sugar carbons as anode materials for lithium-ion batteries. Mater Chem Phys 76:1–6 Fey GTK, Kao YC (2002) Synthesis and characterization of pyrolyzed sugar carbons under nitrogen or argon atmospheres as anode materials for lithium-ion batteries. Mater Chem Phys 73:37–46 Peled E, Eshkenazi V, Rosenberg Y (1998) Study of lithium insertion in hard carbon made from cotton wool. J Power Sources 76:153–158 Zhang Y, Zhang F, Li GD, Chen JS (2007) Microporous carbon derived from pinecone hull as anode material for lithium secondary batteries. Mater Lett 61:5209–5212 Fey GTK, Lee DC, Lin YY, Kumar TP (2003) High-capacity disordered carbons derived from peanut shells as lithium-intercalating anode materials. Synth Met 139:71–80 Fey GTK, Chen CL (2001) High-capacity carbons for lithium-ion batteries prepared from rice husk. J Power Sources 97:47–51 Giri C, Ochieng E, Tieszen LL, Zhu Z, Singh A, Loveland T, Masek J, Duke N (2011) Status and distribution of mangrove forests of the world using earth observation satellite data. Glob Ecol Biogeogr 20:154–159 Liu T, Luo R, Qiao W, Yoon S-H, Mochida I (2010) Microstructure of carbon derived from mangrove charcoal and its application in Li-ion batteries. Electrochim Acta 55:1696–1700 Han Y-J, Chung D-B, Nakabayashi K, Chung J-D, Miyawaki J, Yoon S-H (2016) Effect of heat pre-treatment conditions on the electrochemical properties of mangrove wood-derived hard carbon as an effective anode material for lithium-ion batteries. Electrochim Acta 213:432–438 Moreau RA, Hicks KB, Powell MJ (1999) Effect of heat pretreatment on the yield and composition of oil extracted from corn fiber. J Agric Food Chem 47:2869–2871 Park CW, Yoon SH, Lee SI, Oh SM (2000) Li+ storage sites in non-graphitizable carbons prepared from methylnaphthalene-derived isotropic pitches. Carbon 38:995–1001