Structural and electrochemical characterization of Zn–TiO2 and Zn–WO3 nanocomposite coatings electrodeposited on St 37 steel

Journal of Applied Electrochemistry - Tập 45 - Trang 991-1003 - 2015
Ümran Erten1, H. İbrahim Ünal1, Sibel Zor2, Ş. Hakan Atapek1
1Department of Metallurgical and Materials Engineering, Faculty of Engineering, Kocaeli University, Kocaeli, Turkey
2Department of Chemistry, Faculty of Arts and Sciences, Kocaeli University, Kocaeli, Turkey

Tóm tắt

In this study, TiO2 and WO3 nano-sized particles were chosen as metal oxides to generate anticorrosive Zn composite coatings. The effects of type and amount of oxide particles on the microstructure and corrosion behavior of composite coatings on St 37 steel were investigated. In the first stage of study, electrochemical measurements were carried out in 3.5 % NaCl solution to determine the corrosion behavior of uncoated, Zn-coated, Zn–TiO2, and Zn–WO3 nanocomposite-coated steel samples. In the second stage, the time-dependent surface degradations of all samples immersed into NaCl solution were characterized using scanning electron microscope to observe the protective effect of nanoparticles. It was found that WO3 oxide-dispersed composite coating exhibited superior corrosion resistance.

Tài liệu tham khảo

Callister WD, Rethwisch DG (2001) Fundamentals of materials science and engineering: an integrated approach. Wiley, New York Handbook ASM (2004) Metallography and microstructures. ASM International, Almere Talbot D, Talbot J (1998) Corrosion science and technology. CRS Press, Boca Raton Revie RW (2011) Uhlig’s corrosion handbook. Wiley, Hoboken Handbook ASM (1994) Surface engineering. ASM International, Almere Handbook ASM (2003) Corrosion: fundamentals, testing, and protection. ASM International, Almere Ashby MF, Jones DRH (1996) Engineering materials. Butterworth Heinemann, Oxford Handbook ASM (2001) Composites. ASM International, Almere Vaezi MR, Sadrnezhaad SK, Nikzad L (2008) Electrodeposition of Ni-SiC nanocomposite coatings and evaluation of wear and corrosion resistance and electroplating characteristics. Colloids Surf A 315:176–182. doi:10.1016/j.colsurfa.2007.07.027 Sancakoglu O, Culha O, Toparli M, Agaday B, Çelik E (2011) Co-deposited Zn-submicron sized Al2O3 composite coatings: production, characterization and micromechanical properties. Mater Des 32:4054–4061. doi:10.1016/j.matdes.2011.03.027 Chen W, Wang L, Gao W (2012) Synthesis of Zn-Bi nanocomposite coatings by an ionic co-discharge process. Chem Eng J 192:242–245. doi:10.1016/j.cej.2012.04.001 Llewellyn DT, Hudd RC (1998) Steels metallurgy and applications. Butterworth Heinemann, Oxford Saji VS, Thomas J (2007) Nanomaterials for corrosion control. Curr Sci 92:51–55 Shi L, Sun C, Gao P, Zhou F, Liu W (2006) Mechanical properties and wear and corrosion resistance of electrodeposited Ni-Co/SiC nanocomposite coating. Appl Surf Sci 252:3591–3599. doi:10.1016/j.apsusc.2005.05.035 Ranganatha S, Venkatesha TV, Vathsala K (2010) Development of electroless Ni-Zn-P/nano-TiO2 composite coatings and their properties. Appl Surf Sci 256:7377–7383. doi:10.1016/j.apsusc.2010.05.076 Pouladi S, Shariat MH, Bahrololoom ME (2012) Electrodeposition and characterization of Ni-Zn-P and Ni-Zn-P/nano SiC coatings. Surf Coat Technol 213:33–40. doi:10.1016/j.surfcoat.2012.10.011 Shibli SMA, Chacko F (2011) Development of nano TiO2-incorporated phosphate coatings on hot dip zinc surface for good paintability and corrosion resistance. Appl Surf Sci 257:3111–3117. doi:10.1016/j.apsusc.2010.10.125 Ranganatha S, Venkatesha TV, Vathsala K, Kumar MKP (2012) Electrochemical studies on Zn/nano CeO2 electrodeposited composite coatings. Surf Coat Technol 208:64–72. doi:10.1016/j.surfcoat.2012.08.004 Shibli SMA, Chacko F (2008) Development of nano CeO2-incorporated high performance hot-dip zinc coating. Surf Coat Technol 202:4971–4975. doi:10.1016/j.surfcoat.2008.04.090 Praveen BM, Venkatesha TV, Naik YA, Prashantha K (2007) Corrosion studies of carbon nanotubes-Zn composite coating. Surf Coat Technol 20:5836–5842. doi:10.1016/j.surfcoat.2006.10.034 Praveen BM, Venkatesha TV (2008) Electrodeposition and properties of Zn-nanosized TiO2 composite coatings. Appl Surf Sci 254:2418–2424. doi:10.1016/j.apsusc.2007.09.047 Vathsala K, Venkatesha TV (2011) Zn-ZrO2 nanocomposite coatings: electrodeposition and evaluation of corrosion resistance. Appl Surf Sci 257:8929–8936. doi:10.1016/j.apsusc.2011.05.067 Xia X, Zhitomirsky I, McDermid JR (2009) Electrodeposition of zinc and composite zinc-yttria stabilized zirconia coatings. J Mater Process Technol 209:2632–2640. doi:10.1016/j.jmatprotec.2008.06.031 Vlasa A, Varavara S, Pop A, Bulea C, Muresan LM (2010) Electrodeposited Zn-TiO2 nanocomposite coatings and their corrosion behavior. J Appl Electrochem 40:1519–1527. doi:10.1007/s10800-010-0130-x Kumar MKP, Venkatesha TV, Pavithra MK, Shetty AN (2012) A study on corrosion behavior of electrodeposited Zn-Rutile TiO2 composite coatings. Synth React Inorg M 42:1426–1434. doi:10.1080/15533174.2012.682684 Yang X, Li Q, Zhang S, Liu F, Wang S (2010) Microstructure characteristic and excellent corrosion protection of sealed Zn-TiO2 composite coatings for sintered NdFeB magnet. J Alloys Compd 495:189–195. doi:10.1016/j.jallcom.2010.01.117 Praveen BM, Venkatesha TV, Naik YA (2007) Corrosion behavior of Zn-TiO2 composite coating. Synth React Inorg M 37:461–465. doi:10.1080/15533170701471216 Gomes A, Almeida I, Frade T, Tavares AC (2010) Zn-TiO2 and ZnNi-TiO2 nanocomposite coatings: corrosion behaviour. Mater Sci Forum 636–637:1079–1083. doi:10.4028/www.scientific.net/MSF.636-637.1079 Baeck SH, Jaramillo T, Stucky GD, McFarland EW (2002) Controlled electrodeposition of nanoparticulate tungsten oxide. Nano Lett 2:831–834. doi:10.1021/nl025587p Granqvist CG (2000) Electrochromic tungsten oxide films: review of progress 1993–1998. Sol Energy Mat Sol 60:201–262. doi:10.1016/S0927-0248(99)00088-4 Kumar CMP, Venkatesha TV, Chandrappa KG (2012) Effect of surfactants on co-deposition of B4C nanoparticles in Zn matrix by electrodeposition and its corrosion behavior. Surf Coat Technol 206:2249–2257. doi:10.1016/j.surfcoat.2011.09.075 Lee HK, Lee HY, Jeon JM (2007) Codeposition of micro- and nano-sized SiC particles in the nickel matrix composite coatings obtained by electroplating. Surf Coat Technol 201:4711–4717. doi:10.1016/j.surfcoat.2006.10.004 Gomes A, da Silva Pereira MI (2006) Pulsed electrodeposition of Zn in the presence of surfactants. Electrochim Acta 51:1342–1350. doi:10.1016/j.electacta.2005.06.023 Erler F, Jakob C, Romanus H, Spiess L, Wielage B, Lampke T, Steinhauser S (2003) Interface behaviour in nickel composite coatings with nano-particles of oxidic ceramic. Electrochim Acta 48:3063–3070. doi:10.1016/S0013-4686(03)00380-3 Handbook ASM (1993) Properties and selection: iron steels and high performance alloys. ASM International, Almere Huyett GL (2004) Engineering handbook. Industrial Press Inc., New York Nayana KO, Venkatesha TV (2011) Synergistic effects of additives on morphology, texture and discharge mechanism of zinc during electrodeposition. J Electroanal Chem 663:98–107. doi:10.1016/j.jelechem.2011.10.001 Park H, Szpunar JA (1998) The role of texture and morphology in optimizing the corrosion resistance of zinc-based electrogalvanized coatings. Corros Sci 40:525–545. doi:10.1016/S0010-938X(97)00148-0 Raeissi K, Saatchi A, Golozar MA (2003) Effect of nucleation mode on morphology and texture of electrodeposited zinc. J Appl Electrochem 33:635–642. doi:10.1023/A:1024914503902 Behzadnasab M, Mirabedini SM, Kabiri K, Jamali S (2011) Corrosion performance of epoxy coatings containing silane treated ZrO2 nanoparticles on mild steel in 3.5% NaCl solution. Corros Sci 53:89–98. doi:10.1016/j.corsci.2010.09.026 de la Fuente D, Castaňo JG, Morcillo M (2007) Long-term atmospheric corrosion of zinc. Corros Sci 49:1420–1436. doi:10.1016/j.corsci.2006.08.003 Xia F, Liu C, Ma C, Chu D, Miao L (2012) Preparation and corrosion behavior of electrodeposited Ni–TiN composite coatings. Int J Refract Met H 35:295–299. doi:10.1016/j.ijrmhm.2012.07.002 Zhou X, Shen Y (2013) Beneficial effects of CeO2 addition on microstructure and corrosion behavior of electrodeposited Ni nanocrystalline coatings. Surf Coat Technol 235:433–446. doi:10.1016/j.surfcoat.2013.07.070 Tamura H (2008) The role of rusts in corrosion and corrosion protection of iron and steel. Corros Sci 50:1872–1883. doi:10.1016/j.corsci.2008.03.008 Zhang XG (1996) Corrosion and electrochemistry of zinc. Springer, New York Aal AA, Barakat MA, Mohamed RM (2008) Electrophoreted Zn-TiO2-ZnO nanocomposite coating films for photocatalytic degradation of 2-chlorophenol. Appl Surf Sci 254:4577–4583. doi:10.1016/j.apsusc.2008.01.049 Baghery P, Farzam M, Mouavi AB, Hosseini M (2010) Ni-TiO2 nanocomposite coating with high resistance to corrosion and wear. Surf Coat Technol 204:3804–3810. doi:10.1016/j.surfcoat.2010.04.061 Boshkov N, Tsvetkova N, Petrov P, Koleva D, Avdeev G, Tsvetanov C, Raichevsky G, Raicheff R (2008) Corrosion behavior and protective ability of Zn and Zn-Co electrodeposits with embedded polymeric nanoparticles. Appl Surf Sci 254:5618–5625. doi:10.1016/j.apsusc.2008.03.013 Kumar MK, Venkatesha TV (2013) Fabrication of zinc-nano TiO2 composite films: electrochemical corrosion studies. J Chem Pharm Res 5:253–261. doi: JCPRC5 0975-7384 Ohtsuka T, Matsuda M (2003) In situ Raman spectroscopy for corrosion products of zinc in humidified atmosphere in the presence of sodium chloride precipitate. Corros 59:407–413. doi: CORRA 00109312 Koleva DA, Boshkov N, Bachvarov V, Zhan H, de Wit JHW, Van Breugel K (2010) Application of PEO113-b-PS218 nano-aggregates for improved protective characteristics of composite zinc coatings in chloride-containing environment. Surf Coat Technol 204:3760–3772. doi:10.1016/j.surfcoat.2010.04.043