Statistical foundation of nonequilibrium contact quantities bridging phenomenological and statistical nonequilibrium-thermodynamics
Tóm tắt
Intensive variables of discrete nonequilibrium systems are defined by inequalities which are derivable quantumstatistically for contacts between discrete equilibrium and nonequilibrium systems. These contacts are described by a generalized grand-canonical nonequilibrium density operator of maximal entropy by which heat-, mass-, and power-exchange through the contact can be evaluated. A straightforward calculation yields inequalities whose interpretation enables definitions of intensive nonequilibrium quantities for discrete systems.
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