Một số chất hoạt động bề mặt cation Gemini mới tổng hợp làm chất ức chế ăn mòn cho thép carbon trong dung dịch axit hydrochloric

Journal of Bio- and Tribo-Corrosion - Tập 9 - Trang 1-16 - 2023
S. A. Abd El-Maksoud1, F. I. El-Dossoki2, Mona Abd-Elhamed1, Ahmed A. Farag3
1Chemistry Department, Faculty of Science, Port Said University, Port Said, Egypt
2Chemistry Department, Faculty of Science, Port-Said University, Port-Said, Egypt
3Egyptian Petroleum Research Institute (EPRI), Cairo, Egypt

Tóm tắt

Tác động của các chất hoạt động bề mặt gemini mới tổng hợp lên sự ăn mòn của thép carbon trong dung dịch HCl 1-M đã được nghiên cứu. Kết quả cho thấy hiệu quả ức chế của các hợp chất này bị ảnh hưởng bởi sự gia tăng nồng độ và khả năng tạo micelle trong dung dịch nước. Các kỹ thuật bao gồm mất trọng lượng, phân cực động và phổ điện hóa thể hiện (EIS) đã được sử dụng trong nghiên cứu. Kết quả thu được cho thấy rằng những chất hoạt động bề mặt này hoạt động như là những chất ức chế ăn mòn tốt. Với việc tăng nồng độ chất hoạt động bề mặt, hiệu suất ức chế của các hợp chất được nghiên cứu tăng lên. Kết quả cho thấy hiệu suất ức chế của chất ức chế tốt nhất đạt tới 97,9% ở 100 ppm. Thay đổi trong các tham số điện trở (điện trở chuyển tải, Rct, và điện dung lớp đôi, Cdl) chỉ ra rằng có sự hấp phụ chất hoạt động bề mặt trên bề mặt kim loại, dẫn đến sự hình thành một lớp màng bảo vệ, theo kết quả từ EIS. Các phép đo phân cực động cho thấy các chất ức chế thuộc loại hỗn hợp. Hấp phụ vật lý và hóa học được chứng minh bởi các chất hoạt động bề mặt gemini này và được điều khiển bởi isotherm hấp phụ Langmuir. Hình thái bề mặt thép carbon và lớp màng bảo vệ trên bề mặt đã được nghiên cứu bằng cách sử dụng đặc trưng SEM, AFM và XPS. Kết quả từ các phương pháp khác nhau rất đồng nhất.

Từ khóa

#chất hoạt động bề mặt #gemini #ức chế ăn mòn #thép carbon #axit hydrochloric

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