Solvothermal Fabrication of Hollow Nanobarrel‐Like ZnCo2O4 Towards Enhancing the Electrochemical Performance of Rechargeable Lithium‐Ion Batteries

ChemElectroChem - Tập 4 Số 9 - Trang 2218-2224 - 2017
Zhen Wang1, Qiang Ru1, Xiaoqiu Chen1, Qing Guo1, Bei Wang1, Xianhua Hou1, Shejun Hu1
1Guang dong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, Guangdong Engineering Technology Research Center of Efficient Green Energy and Environmental Protection Materials, School of Physics and Telecommunication Engineering, South China Normal University, Guangzhou, 510006 China

Tóm tắt

AbstractHollow nanobarrel‐like ZnCo2O4 has been designed and synthesized by means of a simple solvothermal method and subsequent calcination. The obtained samples were systematically characterized by powder X‐ray diffraction (XRD), field emission scanning electron microscopy (FESEM), high‐resolution transmission electron microscopy (HRTEM), N2 adsorption–desorption experiments and X‐ray photoelectron spectroscopy (XPS). This hollow structure could not only relieve the volume expansion effect, but also facilitate the diffusion of lithium ions. We obtained a reversible lithium storage capacity of 1350 mAh g−1 even after 300 cycles at a current density of 500 mA g−1 with a voltage window of 0.01–3.0 V. As‐prepared samples demonstrate the high reversible capacity and excellent cycle life. The good cycling capability and high rate performance suggest that the material will be an attractive anode material for lithium‐ion batteries.

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Tài liệu tham khảo

10.1038/35104644

10.1002/celc.201402397

10.1021/acsami.5b11510

10.1021/acsami.5b10342

10.1016/j.nanoen.2011.11.001

10.1021/nn303002u

10.1016/j.jpowsour.2016.04.107

10.1021/nn506252u

10.1002/celc.201700378

10.1016/j.jallcom.2016.02.038

10.1039/c2jm00094f

Chen J., 2016, Phys. Chem. Chem. Phys., 18, 28

10.1016/j.electacta.2016.05.072

Mondal A., 2014, ACS Appl. Mater. Inter., 6, 17

10.1039/C5NR04791A

10.1002/adfm.201303442

10.1021/nl300794f

10.1016/j.matlet.2015.10.126

10.1039/c2nr33576j

10.1016/j.cej.2016.09.056

10.1039/c3ta13787b

10.1016/j.elecom.2007.11.009

10.1039/b921001f

10.1016/j.elecom.2012.07.003

10.1002/celc.201500046

10.1039/C4TA02378A

10.1039/c0jm00101e

10.1016/j.jallcom.2015.09.105

10.1039/C5RA21992B

10.1021/ja902757a

10.1016/j.electacta.2010.03.015

10.1039/c3ta00085k

10.1016/j.carbon.2015.07.024

10.1039/C5TA00830A

10.1016/j.snb.2010.09.001

10.1021/cm703464p

10.1149/1.2400609

10.1016/j.jpowsour.2007.01.072

10.1016/j.electacta.2016.03.047

10.1021/ic102129w

10.1002/adfm.200600997

10.1016/j.nanoen.2014.09.027

Xie Q., 2013, ACS Appl. Mater. Inter., 5, 12

10.1002/ppsc.201300338

10.1039/c0jm04465b

10.1007/s10854-017-6641-z

10.1039/C1JM15054E

10.1016/j.jpowsour.2015.07.047

10.1016/j.jallcom.2013.09.182

10.1016/j.jpowsour.2015.06.048

10.1039/C4RA15553J

10.1007/s12274-015-0976-7

10.1016/j.jpowsour.2014.10.175

10.1039/C4TA06309K

10.1039/C5RA27708F

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ChemElectroChem

Tập 4 Số 9

2218-2224

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