Sol-gel synthesis of ionic liquid/zeolite nano-particles as green, reusable adsorbents for removal of nitrate from aqueous solution
Tóm tắt
In this study, a low cost IL/Zeolite nanocomposite was prepared using zeolite and an environmentally friendly ionic liquid by sol-gel procedure. The IL/Zeolite nanocomposite was used as an efficient adsorbent to remove nitrate ions from water. The nanocomposite features were investigated in terms of size, structure, morphology and composition using Field Emission Scanning Electron Micrographs (FESEM), Energy Dispersive X-ray spectroscopy (XRD), and Fourier Transform Infrared (FT-IR) spectra. Moreover, the effects of solution pH, contact time, initial concentration of nitrate, and adsorbent dosage on nitrate adsorption were investigated. The optimum removal efficiency (91.29%) of IL/Zeolite occurred at an initial pH of 5 and room temperature (~25 °C) with an initial nitrate concentration of 30 mg L−1, the contact time of 30 min and IL/Zeolite adsorbent dosage of 0.04 g/20 m L−1. Based on the highest correlation coefficient (R2), the adsorption kinetics followed the pseudo-second-order equation and the isotherm followed the Freundlich equation. In addition, the adsorption process is exothermic and spontaneous. The recovery of the nanocomposite was successful in 5 times, so it can be concluded that IL/Zeolite can be used as a potential and active bio-adsorbent to remove nitrate ions from aqueous solutions.
Tài liệu tham khảo
Liu CW, Sung Y, Chen BC, Lai HY (2014) Effects of nitrogen fertilizers on the growth and nitrate content of lettuce (Lactuca sativa L.). Int J Environ Res Public Health 11:4427–4440. https://doi.org/10.3390/ijerph110404427
El Hanache L, Lebeau B, Nouali H, Toufaily J, Hamieh T, Daou TJ (2019) Performance of surfactant-modified* BEA-type zeolite nanosponges for the removal of nitrate in contaminated water: Effect of the external surface. J Hazard Mater 364:206–217. https://doi.org/10.1016/j.jhazmat.2018.10.015
Garcia-Segura S, Lanzarini-Lopes M, Hristovski K, Westerhoff P (2018) Electrocatalytic reduction of nitrate: Fundamentals to full-scale water treatment applications. Appl Catal B: Environ 236:546–568. https://doi.org/10.1016/j.apcatb.2018.05.041
Tyagi S, Rawtani D, Khatri N, Tharmavaram M (2018) Strategies for nitrate removal from aqueous environment using nanotechnology: A review. J Water Proc Eng 21:84–95. https://doi.org/10.1016/j.jwpe.2017.12.005
Epsztein R, Nir O, Lahav O, Green M (2015) Selective nitrate removal from groundwater using a hybrid nanofiltration–reverse osmosis filtration scheme. Chem Eng J 279:372–378. https://doi.org/10.1016/j.cej.2015.05.010
Dewage NB, Liyanage AS, Pittman Jr CU, Mohan D, Mlsna T (2018) Fast nitrate and fluoride adsorption and magnetic separation from water on α-Fe2O3 and Fe3O4 dispersed on Douglas fir biochar. Bioresour Technol 263:258–265. https://doi.org/10.1016/j.biortech.2018.05.001
Wu K, Li Y, Liu T, Huang Q, Yang S, Wang W, Jin P (2019) The simultaneous adsorption of nitrate and phosphate by an organic-modified aluminum-manganese bimetal oxide: Adsorption properties and mechanisms. Appl Surf Sci 478:539–551. https://doi.org/10.1016/j.apsusc.2019.01.194
El Midaoui A, Elhannouni F, Taky M, Chay L, Sahli MAM, Echihabi L, Hafsi M (2002) Optimization of nitrate removal operation from ground water by electrodialysis. Sep Purif Technol 29:235–244. https://doi.org/10.1016/S1383-5866(02)00092-8
Martínez J, Ortiz A, Ortiz I (2017) State-of-the-art and perspectives of the catalytic and electrocatalytic reduction of aqueous nitrates. Appl Catal B: Environ 207:42–59. https://doi.org/10.1016/j.apcatb.2017.02.016
Belkada FD, Kitous O, Drouiche N, Aoudj S, Bouchelaghem O, Abdi N, Mameri N (2018) Electrodialysis for fluoride and nitrate removal from synthesized photovoltaic industry wastewater. Sep Purif Technol 204:108–115. https://doi.org/10.1016/j.seppur.2018.04.068
Zou L, Zhang S, Liu J, Cao Y, Qian G, Li YY, Xu ZP (2019) Nitrate removal from groundwater using negatively charged nanofiltration membrane. Environ Sci Pollut Res 26:34197–34204. https://doi.org/10.1007/s11356-018-3829-6
Rahimi E, Sajednia G, Baghdadi M, Karbassi A (2018) Catalytic chemical reduction of nitrate from simulated groundwater using hydrogen radical produced on the surface of palladium catalyst supported on the magnetic alumina nanoparticles. J Environ Chem Eng 6:5249–5258. https://doi.org/10.1016/j.jece.2018.08.026
Deng S, Li D, Yang X, Xing W, Li J, Zhang Q (2016) Biological denitrification process based on the Fe (0)–carbon micro-electrolysis for simultaneous ammonia and nitrate removal from low organic carbon water under a microaerobic condition. Bioresour Technol 219:677–686. https://doi.org/10.1016/j.biortech.2016.08.014
Ma X, Li M, Feng C, He Z (2020) Electrochemical nitrate removal with simultaneous magnesium recovery from a mimicked RO brine assisted by in situ chloride ions. J Hazard Mater 388:122085. https://doi.org/10.1016/j.jhazmat.2020.122085
Zhang Z, Han Y, Xu C, Ma W, Han H, Zheng M, Ma W (2018) Microbial nitrate removal in biologically enhanced treated coal gasification wastewater of low COD to nitrate ratio by coupling biological denitrification with iron and carbon micro-electrolysis. Bioresour Technol 262:65–73. https://doi.org/10.1016/j.biortech.2018.04.059
Rashed MN (2013) Adsorption technique for the removal of organic pollutants from water and wastewater. Org Pollut-Monit, risk Treat 7:167–194. https://doi.org/10.5772/54048
Bhatnagar A, Sillanpaa M (2011) A review of emerging adsorbents for nitrate removal from water. Chem Eng J 168:493–504. https://doi.org/10.1016/j.cej.2011.01.103
Abukhadra MR, Mohamed AS (2019) Adsorption removal of safranin dye contaminants from water using various types of natural zeolite. Silicon 11:1635–1647. https://doi.org/10.1007/s12633-018-9980-3
Harja M (2019) Clay-and zeolite-based biogeosorbents: modelling and properties. Epitoanyag: JSBCM. https://doi.org/10.14382/epitoanyag-jsbcm.2019.23.
He Y, Lin H, Dong Y, Li B, Wang L, Chu S, Liu J (2018) Zeolite supported Fe/Ni bimetallic nanoparticles for simultaneous removal of nitrate and phosphate: synergistic effect and mechanism. Chem Eng J 347:669–681. https://doi.org/10.1016/j.cej.2018.04.088
Aghaii MD, Pakizeh M, Ahmadpour A (2013) Synthesis and characterization of modified UZM-5 as adsorbent for nitrate removal from aqueous solution. Sep Purif Technol 113:24–32. https://doi.org/10.1016/j.seppur.2013.04.013
Anirudhan TS, Ramachandran M (2007) Surfactant-modified bentonite as adsorbent for the removal of humic acid from wastewaters. Appl Clay Sci 35:276–281. https://doi.org/10.1016/j.clay.2006.09.009
Zhan Y, Lin J, Zhu Z (2011) Removal of nitrate from aqueous solution using cetylpyridinium bromide (CPB) modified zeolite as adsorbent. J Hazard Mater 186:1972–1978. https://doi.org/10.1016/j.jhazmat.2010.12.090
Chutia P, Kato S, Kojima T, Satokawa S (2009) Adsorption of As (V) on surfactant-modified natural zeolites. J Hazard Mater 162:204–211. https://doi.org/10.1016/j.jhazmat.2008.05.024
Yusof AM, Malek NANN (2009) Removal of Cr (VI) and As (V) from aqueous solutions by HDTMA-modified zeolite Y. J Hazard Mater 162:1019–1024. https://doi.org/10.1016/j.jhazmat.2008.05.134
De Gennaro B, Aprea P, Liguori B, Galzerano B, Peluso A, Caputo D (2020) Zeolite-rich composite materials for environmental remediation: arsenic removal from water. Appl Sci 10:6939. https://doi.org/10.3390/app10196939
Ghasemi M, Koupai JA, Heidarpour M (2017) The effect of modified zeolite, activated carbon and peat with cationic surfactant and sodium hydroxide on removing anions from irrigation saline waters. Desalination Water Treat 92:196–204. Search in Google Scholar
Li C, Yao J, Zhang TC, Xing W, Liang Y, Xiang M (2017) Simultaneous removal of nitrogen and phosphorus by cetylpyridinium bromide modified zeolite. Water Sci Technol 76:2895–2906. https://doi.org/10.2166/wst.2017.459
Choi WS, Kyung-Jun H, Choi C, Hong S, Yoon SD, Balathanigaimani MS, Shim WG (2019) Adsorption of nitrate and phosphate on basalt based nanostructured zeolite 13X. J Nanosci Nanotechnol 19:2329–2333. https://doi.org/10.1166/jnn.2019.16009
Shojaipour M, Ghaemy M, Amininasab SM (2020) Removal of NO3− ions from water using bioadsorbent based on gum tragacanth carbohydrate biopolymer. Carbohydr Polym 227:115367. https://doi.org/10.1016/j.carbpol.2019.115367
Krol M, Rozek P, Chlebda D, Mozgawa W (2019) ATR/FT-IR studies of zeolite formation during alkali-activation of metakaolin. Solid State Sci 94:114–119. https://doi.org/10.1016/j.solidstatesciences.2019.06.004
Bagherinia MA, Sheydaei M, Giahi M (2017) Graphene oxide as a compatibilizer for polyvinyl chloride/rice straw composites. J Polym Eng 37:661–670. Search in Google Scholar
Alowasheeir A, Tominaka S, Ide Y, Yamauchi Y, Matsushita Y (2018) Two-dimensional cyano-bridged coordination polymer of Mn (H2O)2 [Ni (CN)4]: Structural analysis and proton conductivity measurements upon dehydration and rehydration. CrystEngComm 20:6713–6720. https://doi.org/10.1039/c8ce01400k
Yazdi F, Anbia M, Salehi S (2019) Characterization of functionalized chitosan-clinoptilolite nanocomposites for nitrate removal from aqueous media. Int J Biol Macromol 130:545–555. https://doi.org/10.1016/j.ijbiomac.2019.02.127
Kireç O, Alacabey İ, Erol K, Alkan H (2021) Removal of 17β-estradiol from aqueous systems with hydrophobic microspheres. J Polym Eng 41:226–234. https://doi.org/10.1515/polyeng-2020-0150
Cheng Q, Li H, Xu Y, Chen S, Liao Y, Deng F, Li J (2017) Study on the adsorption of nitrogen and phosphorus from biogas slurry by NaCl-modified zeolite. PloS one 12:e0176109. https://doi.org/10.1371/journal.pone.0176109
Hassan AF, Alafid F, Hrdina R (2020) Preparation of melamine formaldehyde/nanozeolite Y composite based on nanosilica extracted from rice husks by sol–gel method: adsorption of lead (II) ion. J Sol-Gel Sci Technol 95(1):211–222. https://doi.org/10.1007/s10971-020-05295-y
Osińska M (2017) Removal of lead (II), copper (II), cobalt (II) and nickel (II) ions from aqueous solutions using carbon gels. J Sol-Gel Sci Technol 81(3):678–692. https://doi.org/10.1007/s10971-016-4256-0
Teimouri A, Nasab SG, Vahdatpoor N, Habibollahi S, Salavati H, Chermahini AN (2016) Chitosan/Zeolite Y/Nano ZrO2 nanocomposite as an adsorbent for the removal of nitrate from the aqueous solution. Int J Biol Macromol 93:254–266. https://doi.org/10.1016/j.ijbiomac.2016.05.089
Arora M, Eddy NK, Mumford KA, Baba Y, Perera JM, Stevens GW (2010) Surface modification of natural zeolite by chitosan and its use for nitrate removal in cold regions. Cold Reg Sci Technol 62:92–97. https://doi.org/10.1016/j.coldregions.2010.03.002
Meftah T, Zerafat MM (2016) Nitrate removal from drinking water using organo-silane modified natural nano-Zeolite. J Nanosci Nanotechnol 12:223–232. https://iranjournals.nlai.ir/handle/123456789/80182
Mohsenibandpei A, Alinejad A, Bahrami H, Ghaderpoori M (2016) Water solution polishing of nitrate using potassium permanganate modified zeolite: parametric experiments, kinetics and equilibrium analysis. Glob Nest J 18:546–558.
Hao S, Zhang H (2017) High catalytic performance of nitrate reduction by synergistic effect of zero-valent iron (Fe0) and bimetallic composite carrier catalyst. J Clean Prod 167:192–200. https://doi.org/10.1016/j.jclepro.2017.07.255
Zeng Y, Woo H, Lee G, Park J (2010) Adsorption of Cr (VI) on hexadecylpyridinium bromide (HDPB) modified natural zeolites. Microporous Mesoporous Mater 130:83–91. https://doi.org/10.1016/j.micromeso.2009.10.016
Al-Kadhi NadaS (2019) The kinetic and thermodynamic study of the adsorption Lissamine Green B dye by micro-particle of wild plants from aqueous solutions. Egypt J Aquat Res 45:231–238. https://doi.org/10.1016/j.ejar.2019.05.004
Esmaeili Bidhendi M, Asadi Z, Bozorgian A, Shahhoseini A, Gabris MA, Shahabuddin S, Saidur R (2020) New magnetic CO3O4/Fe3O4 doped polyaniline nanocomposite for the effective and rapid removal of nitrate ions from ground water samples. Environ Prog Sustain Energy 39:13306. https://doi.org/10.1002/ep.13306