Simultaneous determination of ascorbic acid, dopamine and uric acid using a glassy carbon electrode modified with the nickel(II)-bis(1,10-phenanthroline) complex and single-walled carbon nanotubes

Microchimica Acta - Tập 183 - Trang 1401-1408 - 2016
Songling Yan1, Xi Li1, Yan Xiong1, Mengmeng Wang1, Linlin Yang1, Xin Liu1, Xiaoyu Li1, Lina Abdullah M Alshahrani1, Peng Liu1, Chaocan Zhang2
1Department of Chemistry, School of Science, Wuhan University of Technology, Wuhan, People’s Republic of China
2School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, People’s Republic of China

Tóm tắt

The authors report that a glassy carbon electrode modified with the [Ni(phen)2]2+ complex and single-walled carbon nanotubes represents a useful sensor for simultaneous determination of ascorbic acid (AA), dopamine (DA) and uric acid (UA). The material was characterized by scanning electron microscopy, and the electrode by cyclic voltammetry and electrochemical impedance spectroscopy. The experiments showed that this electrode responds to AA, DA and UA, best at working potentials of 0.130 V, 0.334 V, 0.486 V (vs. SCE), over the wide linear ranges from 30 to 1546 μM (for AA), 1 to 780 μM (for DA), and 1 to 1407 μM (for UA). The respective detection limits are 12 μM, 1 μM and 0.76 μM at an S/N ratio of 3. The modified electrode was successfully applied to the determination of AA, DA and UA in real samples.

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