Simulation of free radical addition reactions modified by the presence of cobalt macrocycles

Macromolecular Theory and Simulations - Tập 4 Số 1 - Trang 195-208 - 1995
Thomas P. Davis1, Dax Kukulj1, Ian Maxwell2
1School of Chemical Engineering and Industrial Chemistry, University of New South Wales, PO Box 1, Kensington, Sydney, NSW 2052, Australia
2Memtec Ltd., I. Memtec Parkway, Sth Windsor, NSW 2756, Australia

Tóm tắt

Abstract

Free radical addition reactions in the presence of cobaloximes and related compounds have been modelled. Several mechanisms are presented and similarities with the “persistent radical effect” noted by Daikh and Finke are discussed. Cobaloximes and salophen

System. name: N‐acetyl‐p‐aminophenyl salicylate.

derivatives are widely used in organic synthesis to build carbon‐carbon bonds, whereas in polymer synthesis they are used as catalytic chain transfer agents in the production of oligomers. This work shows that these reactions are closely related and also demonstrates the influence that an external radical source has on the overall reaction kinetics.

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Macromolecular Theory and Simulations

Tập 4 Số 1

195-208

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