Simple synthesis of luminescent CdSe quantum dots from ascorbic acid and selenium dioxide

Luminescence - Tập 30 Số 8 - Trang 1375-1379 - 2015
Yilin Wang1, Meihua Yu2, Kun Yang1, Jianping Lu1, Linqing Chen1
1Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning 530004, China
2Ministry-Province Jointly-Constructed Cultivation Base for the State Key Laboratory of Processing Non-Ferrous Metal and Featured Materials, Guangxi Zhuang Autonomous Region; Guangxi University; Nanning 530004 China

Tóm tắt

Abstract

A simple, low‐cost and convenient method was developed for the synthesis of highly luminescent CdSe quantum dots (QDs) in an aqueous medium. Compared with previous methods, this synthesis was carried out in one pot using ascorbic acid (C6H8O6) to replace NaBH4 or N2H4 · H2O as a reductant, and selenium dioxide to replace selenium or its other hazardous, expensive and unstable compounds as a precursor. The mechanism of CdSe QDs formation was elucidated. The influence of various experimental variables, including refluxing time, Cd/MSA and Cd/Se molar ratios, on the luminescent properties of the QDs were systematically investigated. X‐Ray powder diffraction and transmission electron microscopy characterization indicated that the QDs had a pure cubic zinc‐blended structure with a spherical shape. Copyright © 2015 John Wiley & Sons, Ltd.

Từ khóa


Tài liệu tham khảo

10.1021/jp409937z

10.1021/am404876p

10.1021/nl103814g

10.1021/nl3041417

10.1021/ac4004437

10.1021/cm2033417

10.1016/j.cej.2013.06.116

10.1049/mnl.2012.0439

10.1016/j.mseb.2007.01.018

10.1016/j.electacta.2012.07.015

10.1016/j.jallcom.2013.01.054

10.1016/j.jlumin.2010.12.029

10.1016/j.matlet.2013.07.028

10.1021/cm000843p

10.1021/ja00072a025

10.1039/b104231a

10.1016/j.cclet.2009.03.036

10.1016/j.apsusc.2008.09.009

10.1016/j.matlet.2007.11.027

10.1016/j.matchemphys.2013.09.003

10.1016/j.snb.2013.08.093

10.1021/la901798y

10.1016/j.cej.2014.01.064

Thông tin
Thông tin xuất bản

Luminescence

Tập 30 Số 8

1375-1379

Thông tin tác giả