Simple electrodeposition of a novel lanthanide-based porous tri-metallic metal–organic framework grown onto Ni-foam support as a novel binder-free electrode for supercapacitors
Tóm tắt
A novel three mixed metal–organic framework (TM-MOF) containing lanthanum, gadolinium and thulium metals is prepared through a simple cathodic electrodeposition strategy onto nickel foam substrate. Various techniques are used to full characterization of the as-prepared TM-MOF product. The microscopic results revealed formation of the TM-MOF nanosheets uniformly grown onto porous Ni-foam. The synergistic effects of the La/Gd/Tm-lanthanide elements within the composition of TM-MOF electrode delivered a high specific capacity of 412 C/g at a current density of 1 A/g, high-rate capability of 52.9% (at 15 A/g), and an outstanding cycling stability of 94.2% after 6000 cycles. Based on the electrochemical findings, the hierarchical sheet-like morphology of the TM-MOF was rich in active redox sites and electrolyte ions diffusion pathways. All of these characters suggested that TM-MOF electrode could be promising candidate for supercapacitors.
Tài liệu tham khảo
Abdel Maksoud MIA, Fahim RA, Shalan AE, Abd Elkodous M, Olojede SO, Osman AI, Farrell C, Al-Muhtaseb AAH, Awed AS, Ashour AH, Rooney DW (2021) Advanced materials and technologies for supercapacitors used in energy conversion and storage: a review. Environ Chem Lett 19(1):375–439
Burke A (2000) Ultracapacitors: why, how, and where is the technology. J Power Sources 91(1):37–50
Li WS, Chang ML, Cheng HC (2020) Facile synthesis of CNTs/Co(OH)2 hybrid nanostructures for high-performance electrochemical supercapacitor. Chem Phys Lett 739:137003
Dubey R, Guruviah V (2019) Review of carbon-based electrode materials for supercapacitor energy storage. Ionics 25(4):1419–1445
Barmi AAM, Aghazadeh M, Moosavian MA, Golikand AN (2020) Binder-free high-performance Fe3O4 fine particles in situ grown onto N-doped porous graphene layers co-embedded into porous substrate as supercapacitor electrode. J Mater Sci: Mater Electron 31(18):15198–15217
Rodenas T, Luz I, Prieto G, Seoane B, Miro H, Corma A, Kapteijn F, Xamena FXL, Gascon J (2015) Metal–organic framework nanosheets in polymer composite materials for gas separation. Nat Mater 14(1):48–55
Zhang X, Wang J, Ji X, Sui Y, Wei F, Qi J, Meng Q, Ren Y, He Y (2020) Nickel/cobalt bimetallic metal-organic frameworks ultrathin nanosheets with enhanced performance for supercapacitors. J Alloys Comp 825:154069
Hussain I, Lamiel C, Qin N, Gu S, Li Y, Wu S, Huang X, Zhang K (2022) Development of vertically aligned trimetallic Mg-Ni-Co oxide grass-like nanostructure for high-performance energy storage applications. J Colloid Interf Sci 582:782–792
Hussain I, Mak T, Zhang K (2021) Boron-doped trimetallic Cu-Ni-Co oxide nanoneedles for supercapacitor application. ACS Appl Nano Mater 4:129–141
Solgi M, Cheraghali R, Aghazadeh M (2021) Self-assembled Co(OH)2/functionalized MWNTs/porous graphene ternary binder-free hybrid for supercapacitors. J Mater Sci: Mater Electron 32(1):151–167
Hussain I, Iqbal S, Hussain T, Chen Y, Ahmad M, Sufyan Jave M, AlFantazi A, Zhang K (2021) An oriented Ni–Co-MOF anchored on solution-free 1D CuO: a p–n heterojunction for supercapacitive energy storage. J Mater Chem A 9:17790–17800
Hussain I, Hussain T, Bilal Ahmed S, Kaewmaraya T, Ahmad M, Chen X, SufyanJaved M, Lamiel C, Zhang K (2021) Binder-free trimetallic phosphate nanosheets as an electrode: Theoretical and experimental investigation. J Power Sources 513:230556
Hussain I, Sahoo S, Mohapatra D, Ahmad M, Iqbal S, SufyanJaved M, Gu S, Qin N, Lamiel C, Zhang K (2022) Recent progress in trimetallic/ternary-metal oxides nanostructures: Misinterpretation/ misconception of electrochemical data and devices. Appl Mater Today 26:101297
Aghazadeh M, Foratirad H (2022) Electrochemical grown Ni, Zn-MOF and its derived hydroxide as battery-type electrodes for supercapacitors. Synth Met 285:117009
Aghazadeh M, Forati-Rad H, Yavari K, Mohammadzadeh K (2021) On-pot fabrication of binder-free composite of iron oxide grown onto porous N-doped graphene layers with outstanding charge storage performance for supercapacitors. J Mater Sci: Mater Electron 32(10):13156–13176
Mehtab T, Yasin G, Arif M, Shakeel M, Korai RM, Nadeem M, Muhammad N, Lu X (2019) Metal-organic frameworks for energy storage devices: batteries and supercapacitors. J Energy Stor 21:632–646
Wang DG, Liang Z, Gao S, Qu C, Zou R (2020) Metal-organic framework-based materials for hybrid supercapacitor application. Coord Chem Rev 404:213093
Liu Y, Li G, Guo Y, Ying Y, Peng X (2017) Flexible and binder-free hierarchical porous carbon film for supercapacitor electrodes derived from MOFs/CNT. ACS Appl Mater Interf 9(16):14043–14050
Du W, Bai YL, Xu J, Zhao H, Zhang L, Li X, Zhang J (2018) Advanced metal-organic frameworks (MOFs) and their derived electrode materials for supercapacitors. J Power Sources 402:281–295
Ramachandran R, Zhao C, Luo D, Wang K, Wang F (2018) Morphology-dependent electrochemical properties of cobalt-based metal organic frameworks for supercapacitor electrode materials. Electrochim Acta 267:170–180
Dezfuli AS, Kohan E, Naderi HR, Salehi E (2019) Study of the supercapacitive activity of a Eu-MOF as an electrode material. New J Chem 43(23):9260–9264
Liu QQ, Zhang SH, Yang J, Yue KF (2019) A water-stable La-MOF with high fluorescence sensing and supercapacitive performances. Analyst 144(15):4534–4544
Yu H, Xia H, Zhang J, He J, Guo S, Xu Q (2018) Fabrication of Fe-doped Co-MOF with mesoporous structure for the optimization of supercapacitor performances. Chin Chem Lett 29(6):834–836
Rahmanifar MS, Hesari H, Noori A, Masoomi MY, Morsali A, Mousavi MF (2018) A dual Ni/Co-MOF-reduced graphene oxide nanocomposite as a high performance supercapacitor electrode material. Electrochim Acta 275:76–86
Jiao Y, Pei J, Chen D, Yan C, Hu Y, Zhang Q, Chen G (2017) Mixed-metallic MOF based electrode materials for high performance hybrid supercapacitors. J Mater Chem A 5(3):1094–1102
Wang E, Jiang S, Bu X (2020) One-pot electrochemical assembling of porous cobalt hydroxide/nitrogen-doped porous graphene onto Ni foam as a binder-free electrode for supercapacitor applications. J Energy Stor 32:101881
Hussain I, Hussain T, Lamiel C, Zhang K (2020) Turning indium oxide into high-performing electrode materials via cation substitution strategy: Preserving single crystalline cubic structure of 2D nanoflakes towards energy storage devices. J Power Sour 480:228873
Hussain I, Hussain T, Yang S, Chen Y, Zhou J, Ma X, Abbas N, Lamiel C, Zhang K (2020) Integration of CuO nanosheets to Zn-Ni-Co oxide nanowire arrays for energy storage applications. Chem Eng J 413:127570
Xue Z, Jiang J, Ma MG, Li MF, Mu T (2017) Gadolinium-based metal–organic framework as an efficient and heterogeneous catalyst to activate epoxides for cycloaddition of CO2 and alcoholysis. ACS Sustain Chem Eng 5(3):2623–2631
Xia H, Zhang J, Yang Z, Guo S, Guo S, Xu Q (2017) 2D MOF nanoflake-assembled spherical microstructures for enhanced supercapacitor and electrocatalysis performances. Nano-micro lett 9(4):1–11
Trivedi MK, Branton A, Trivedi D, Nayak G, Saikia G, Jana S (2018) Physical and structural characterization of biofield treated imidazole derivatives. Nat Prod Chem Res 3(5):1000187
Xu H, Cao CS, Kang XM, Zhao B (2016) Lanthanide-based metal–organic frameworks as luminescent probes. Dalton Trans 45(45):18003–18017
Zhang X, Wan K, Subramanian P, Xu M, Luo J, Fransaer J (2020) Electrochemical deposition of metal–organic framework films and their applications. J Mater Chem A 8:7569–7587
Campagnol N, Van Assche TRC, Li M, Stappers L, Dincă M, Denayer JFM, Binnemans K, De Vos DE, Fransaer J (2016) On the electrochemical deposition of metal–organic frameworks. J Mater Chem A 4:3914–3925
Wang J, Zhong Q, Zeng Y, Cheng D, Xiong Y, Bu Y (2019) Rational construction of triangle-like nickel-cobalt bimetallic metal-organic framework nanosheets arrays as battery-type electrodes for hybrid supercapacitors. J Colloid Interf Sci 555:42–52
Sarkar S, Howli P, Das B, Das NS, Samanta M, Das GC, Chattopadhyay KK (2017) Novel quaternary chalcogenide/reduced graphene oxide-based asymmetric supercapacitor with high energy density. ACS Appl Mater Interf 9(27):22652–22664
Halder L, Das AK, Maitra A, Bera A, Paria S, Karan SK, Si SK, Ojha S, De A, Khatua BB (2020) A polypyrrole-adorned, self-supported, pseudocapacitive zinc vanadium oxide nanoflower and nitrogen-doped reduced graphene oxide-based asymmetric supercapacitor device for power density applications. New J Chem 44(3):1063–1075
Ghosh S, De Adhikari A, Nath J, Nayak GC, Nayek HP (2019) Lanthanide (III) Metal-Organic Frameworks: Syntheses, Structures and Supercapacitor Application. Chem Select 4(36):10624–10631
Jafari H, Mohammadnezhad P, Khalaj Z, Naderi HR, Kohan E, Hosseini MRM, Dezfuli AS (2020) Terbium metal–organic frameworks as capable electrodes for supercapacitors. New J Chem 44(27):11615–11621
He H, Wang G, Shen B, Wang Y, Lu Z, Guo S, Zhang J, Yang L, Jiang Q, Xiao Z (2020) Three isostructural Zn/Ni nitro-containing metal-organic frameworks for supercapacitor. J Solid State Chem 288:121375
Zhang X, Sui Y, Wei F, Qi J, Meng Q, Ren Y, He Y (2019) Self-supported 3D layered zinc/nickel metal-organic-framework with enhanced performance for supercapacitors. J Mater Sci: Mater Electron 30(19):18101–18110