Shape-Controlled Metal Nanocrystals for Heterogeneous Catalysis

Annual Review of Chemical and Biomolecular Engineering - Tập 7 Số 1 - Trang 327-348 - 2016
Aleksey Ruditskiy1, Hsin‐Chieh Peng1, Younan Xia2,1,3
1School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332
2School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332
3the Wallace H. Coulter Department of Biomedical Engineering, Georgia Institute of Technology, and Emory University, Atlanta, Georgia 30332,

Tóm tắt

The ability to control the shape of metal nanocrystals allows us to not only maneuver their physicochemical properties but also optimize their activity in a variety of applications. Heterogeneous catalysis, in particular, would benefit tremendously from the availability of metal nanocrystals with controlled shapes and well-defined facets or surface structures. The immediate benefits may include significant enhancements in catalytic activity and/or selectivity along with reductions in the materials cost. We provide a brief account of recent progress in the development of metal nanocrystals with controlled shapes and thereby enhanced catalytic performance for several reactions, including formic acid oxidation, oxygen reduction, and hydrogenation. In addition to monometallic nanocrystals, we also cover a bimetallic system, in which the two metals are formulated as alloyed, core-shell, or core-frame structures. We hope this article will provide further impetus for the development of next-generation heterogeneous catalysts essential to a broad range of applications.

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Annual Review of Chemical and Biomolecular Engineering

Tập 7 Số 1

327-348

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