Phát hiện nhạy của Natri Dichloroisocyanurate và Axit Rosmarinic bằng các Nanocluster Đồng được phủ Polyvinylpyrrolidone

Journal of Fluorescence - Trang 1-12 - 2023
Jianhua Kuang1, Qingqing Hu1, Yao Feng1, Jingxue Yuan1, Zhengjun Cheng1,2
1Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, China West Normal University, Nanchong, China
2Institute of Applied Chemistry, China West Normal University, Nanchong, China

Tóm tắt

Trong bài viết này, các nanocluster đồng phát quang xanh hòa tan trong nước (CuNCs) được chuẩn bị bằng polyvinylpyrrolidone (PVP) và axit ascorbic với vai trò là tác nhân tạo khuôn và giảm, tương ứng. Điều kiện tổng hợp của PVP-CuNCs đã được nghiên cứu và phân tích nhằm tối ưu hóa. Hiệu suất lượng tử của PVP-CuNCs được tính toán là 14,97%. Nó thể hiện độ đặc hiệu tốt và khả năng phát hiện cực kỳ nhạy cho natri dichloroisocyanurate (DCCNa)/acid rosmarinic (RA), với khoảng đáp ứng tuyến tính từ 0,030–2,400/0,030–0,900 μM và giá trị LOD tương ứng là 10,766/8,985 nM. Hơn nữa, các cơ chế phản ứng phát quang của hệ PVP-CuNCs-DCCNa và PVP-CuNCs-DCCNa-RA đã được thảo luận, và đầu dò cảm biến có thể được sử dụng hiệu quả cho các thử nghiệm DCCNa và RA trong các mẫu thực, với các kết quả đạt yêu cầu.

Từ khóa

#Natri Dichloroisocyanurate #Axit Rosmarinic #Nanocluster Đồng #Polyvinylpyrrolidone #Phát hiện nhạy.

Tài liệu tham khảo

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