Selective Oxidation of Primary Alcohols to Carboxylic Acids Using Lacunary Polyoxometalates Catalysts and Hydrogen Peroxide

Catalysis Letters - Tập 153 - Trang 1738-1742 - 2022
Feng-Li Yu1, Min-Xue Liu1, Bing Yuan1, Cong-Xia Xie1, Shi-Tao Yu2
1College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, China
2State Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, China

Tóm tắt

The first organic–inorganic lacunary polyoxometalate catalytic oxidation system with H2O2 as an oxidant for the preparation of aliphatic carboxylic acids from primary alcohols has been developed. This new catalytic system not only exhibits good catalytic activity with high selectivity toward acids, but also satisfactorily resolves the separation of the catalyst for reuse.

Tài liệu tham khảo

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