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Rủi ro phát thải hydro sulfide trong pin lithium–sulfur dưới điều kiện xảy ra sự cố
Tóm tắt
Pin lithium–sulfur, là một trong những công nghệ hứa hẹn nhất cho các ứng dụng lưu trữ năng lượng, đang thu hút sự quan tâm ngày càng tăng. Một thách thức quan trọng cho việc thương mại hóa pin lithium–sulfur là sự ổn định kém của lithium sulfide trước độ ẩm, điều này có thể dẫn đến việc phát thải khí hydrogen sulfide độc hại. Tuy nhiên, nguy cơ phát thải hydrogen sulfide từ pin lithium–sulfur dưới các điều kiện giới hạn vẫn chưa rõ ràng. Trong bài báo này, chúng tôi điều tra cơ chế phát thải hydrogen sulfide trong pin lithium–sulfur, và đánh giá ảnh hưởng của việc xả pin đến sự sinh ra của hydrogen sulfide. Việc sản xuất sulfion và hydrogen sulfide được nghiên cứu một cách định tính/định lượng. Theo các kết quả trên, hành vi hình thành hydrogen sulfide trong các pin được làm rõ dựa trên mô phỏng nhiệt động học. Hơn nữa, ảnh hưởng của việc xả pin lithium–sulfur đến sự phát thải hydrogen sulfide được tính toán định tính. Những kết quả này cho thấy rằng hydrogen sulfide thực sự được sản xuất từ các sản phẩm xả của pin lithium–sulfur dưới điều kiện axit, các phát hiện này cũng có thể cung cấp một số hướng dẫn hoặc gợi ý cho các ứng dụng thực tế của pin lithium–sulfur.
Từ khóa
#pin lithium–sulfur #phát thải hydrogen sulfide #sự ổn định của lithium sulfide #ứng dụng lưu trữ năng lượng #nhiệt động họcTài liệu tham khảo
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