Rheological and electrical properties of polystyrene/multi-walled carbon nanotube nanocomposites prepared by latex technology

Springer Science and Business Media LLC - Tập 24 - Trang 97-103 - 2012
Myung Hwan Kang1, Seong Jae Lee1
1Department of Polymer Engineering, The University of Suwon, Gyeonggi, Korea

Tóm tắt

The nanocomposites of monodisperse polystyrene (PS) particles and multi-walled carbon nanotubes (MWNTs) were prepared by latex technology to provide good dispersion of nanotubes in polymer matrix. Two kinds of monodisperse PS particles were synthesized either by emulsion polymerization or by dispersion polymerization. The MWNTs were dispersed in deionized water and mixed with the PS particles, and then PS/MWNT nanocomposites were prepared by freeze-drying and subsequent compression molding. Rheological and electrical properties of these nanocomposites were investigated. Pronounced effect of MWNT incorporation was observed, resulting in larger modulus at lower frequencies when compared to neat PS. The nanocomposite prepared under ultrasonication showed the optimum results providing good dispersion of MWNTs and high electrical conductivity. The effect of PS particle size on electrical conductivity was found to be dependent on the MWNT content incorporated.

Tài liệu tham khảo

Al-Saleh, M. and U. Sundararaj, 2009, A review of vapor grown carbon nanofiber/polymer conductive composites, Carbon 47, 2–22. Arshady, R., 1992, Suspension, emulsion, and dispersion polymerization: A methodological survey, Colloid Polym. Sci. 270, 717–732. Chen, J., M. A. Hamon, H. Hu, Y. Chen, A. M. Rao, P. C. Eklund, and R. C. Haddon, 1998, Solution properties of singlewalled carbon nanotubes, Science 282, 95–98. Du, F., R. C. Scogna, W. Zhou, S. Brand, J. E. Fischer, and K. I. Winey, 2004, Macromolecules, 37, 9048–9055. Grossiord, N., J. Loos, and C. E. Koning, 2005, Strategies for dispersing carbon nanotubes in highly viscous polymers, J. Mater. Chem. 15, 2349–2352. Grossiord, N., J. Loos, O. Regev, and C. E. Koning, 2006, Toolbox for dispersing carbon nanotubes into polymers to get conductive nanocomposites, Chem. Mater. 18, 1089–1099. Grossiord, N., M. E. L. Wouters, H. E. Miltner, K. Lu, J. Loos, B. V. Mele, and C. E. Koning, 2010, Isotactic polypropylene/carbon nanotube composites prepared by latex technology: electrical conductivity study, Eur. Polymer J. 46, 1833–1843. Grunlan, J. C., A. R. Mehrabi, M. V. Bannon, and J. L. Bahr, 2004, Water-based single-walled-nanotube-filled polymer composite with an exceptionally low percolation threshold, Adv. Mater. 16, 150–153 Jin, H. J., H. J. Choi, S. H. Yoon, S. J. Myung, and S. E. Shim, 2005, Carbon nanotube-adsorbed polystyrene and poly(methyl methacrylate) microspheres, Chem. Mater. 17, 4034–4037. Kim, S. T., H. J. Choi, and S. M. Hong, 2007, Bulk polymerized polystyrene in the presence of multi-walled carbon nanotubes, Colloid Polym. Sci. 285, 593–598. Moniruzzaman, M. and K. I. Winey, 2006, Polymer nanocomposites containing carbon nanotubes, Macromolecules 39, 5194–5205. Odian, G., 1991, Principles of Polymerization, 3rd ed., John Wiley & Sons, New York. Ou, J. L., J. K. Yang, and H. Chen, 2001, Styrene/potassium persulfate/water systems: effects of hydrophilic comonomers and solvent additives on the nucleation mechanism and the particle size, Eur. Polym. J. 37, 789–799. Potschke, P., T. D. Fornes, and D. R. Paul, 2002, Rheological behavior of multiwalled carbon nanotube/polycarbonate composites, Polymer 43, 3247–3255. Rastogi, R., R. Kaushal, S. K. Tripathi, A. L. Sharma, I. Kaur, and L. M. Bharadwaj, 2008, Comparative study of carbon nanotube dispersion using surfactants, J. Colloid Interface Sci. 328, 421–428. Regev, O., P. N. B. ElKati, J. Loos, and C. E. Koning, 2004, Preparation of conductive nanotube-polymer composites using latex technology, Adv. Mater. 16, 248–251. Safadi, B., R. Andrews, and E. A. Grulke, 2002, Multi-walled carbon nanotube polymer composites: synthesis and characterization of thin films, J. Appl. Polym. Sci. 84, 2660–2669. Sulong, A. B., C. H. Azhari, R. Zulkifli, M. R. Othman, and J. Park, 2009, A comparison of defects produced on oxidation of carbon nanotubes by acid and UV ozone treatment, Eur. J. Scientific Res. 33, 295–304. Treacy, M. M. J., T. W. Ebbesen and J. M. Gibson, 1996, Exceptionally high Young’s modulus observed for individual carbon nanotubes, Nature 381, 678–680. Woo, D. K. and S. J. Lee, 2010, Effect of treatment method on rheological properties of latex-blended polystyrene/multiwalled carbon nanotube nanocomposites, Korea-Australia Rheol. J. 22, 219–227. Wu, T. M., E. C. Chen, 2008, Preparation and characterization of conductive carbon nanotube-polystyrene nanocomposites using latex technology, Comp. Sci. Tech. 68, 2254–2259. Yu, J., K. Lu, E. Sourty, N. Grossiord, C. E. Koning, and J. Loos, 2007, Characterization of conductive multiwall carbon nanotube/polystyrene composites prepared by latex technology, Carbon 45, 2897–2903.