Tổng quan về các phản ứng hỗ trợ bởi plasma và ứng dụng tiềm năng trong việc sửa đổi khung hữu cơ kim loại

Springer Science and Business Media LLC - Tập 13 - Trang 444-457 - 2019
Tingting Zhao1, Niamat Ullah1, Yajun Hui1, Zhenhua Li1
1Key Lab for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin, China

Tóm tắt

Katalysis plasma đang thu hút sự chú ý ngày càng tăng trên toàn thế giới. Plasma là một loại khí bán ion hóa bao gồm electron, ion, phân tử, gốc và photon. Việc tích hợp quá trình katalysis và plasma có thể nâng cao hoạt tính và độ ổn định của xúc tác. Một số phản ứng thermodynamically không thuận lợi có thể dễ dàng xảy ra với sự hỗ trợ của plasma. So với katalysis nhiệt truyền thống, các bộ phản ứng plasma có thể tiết kiệm năng lượng vì chúng có thể hoạt động ở nhiệt độ thấp hơn rất nhiều hoặc thậm chí ở nhiệt độ phòng. Thêm vào đó, nhiệt độ khối lượng thấp của plasma lạnh khiến nó trở thành một lựa chọn tốt cho việc xử lý các vật liệu nhạy cảm với nhiệt độ. Trong bài đánh giá này, chúng tôi tóm tắt các phản ứng hỗ trợ bởi plasma liên quan đến quá trình cải cách khô của methane, phản ứng methan hóa CO2, phản ứng liên kết methane và giảm thiểu hợp chất hữu cơ bay hơi. Các ứng dụng của plasma trong việc sửa đổi khung hữu cơ kim loại được thảo luận.

Từ khóa

#plasma catalysis #methane reforming #CO2 methanation #metal-organic frameworks #energy efficiency

Tài liệu tham khảo

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