Removal of dissolved oxygen from water using a Pd-resin based catalytic reactor

Wenxin Shi1, Chongwei Cui1, Liye Zhao2, Shuili Yu1, Xia Yun1
1State Key Laboratory of Urban Water Resources and Environment, School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin, China
2Heilongjiang Urban Planning and Surveying Design and Research Institute, Harbin, China

Tóm tắt

The removal of dissolved oxygen (DO) from water was studied experimentally in a Pd-resin base catalyst reactor using purified hydrogen gas as a reducing agent. The effects of various operating conditions, such as hydrogen and water flow rates, height of the catalytic resin bed, temperature, pH value and run time, on the removal of DO, had been studied extensively. The results shows that DO could be removed by the reactor from ppm to ppb levels at ambient temperature. Increases of temperature, H2 gas rate and the height of the catalytic resin were helpful to improve the DO removal rate. The change of pH value from 4 to 12 resulted in no effect on DO removal. Reaction time was the key factor to control the DO removal efficiency. Only when the reaction time was longer than 2.3 minutes under the experimental conditions, could a very low DO level be achieved.

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Tài liệu tham khảo

Sinha V, Li K. Alternative methods for dissolved oxygen removal from water: a comparative study. Desalination, 2000, 127: 155–164

Chua I, Tai M S L, Li K. Ultrapure water quality and production for industrial uses. Journal of The Institution of Engineers, Singapore, 1993, 33: 57–64

Tan X Y, Li K. Investigation of novel membrane reactors for removal of dissolved oxygen from water. Chemical Engineering Science, 2000, 55: 1213–1224

Li K, Tan X Y. Development of membrane-UV reactor for dissolved oxygen removal from water. Chemical Engineering Science, 2001, 56: 5073–5083

Kasama Y, Yagi Y, Imaoka T. Advanced DI water system with low dissolved oxygen for ULSI processing. Proceedings of Institute of Environmental Science, 1990, 344–349

Imaoka T, Yagi Y, Kasama Y, Sugiyama I, Isagawa T, Ohmi T. Advanced ultrapure water systems for ULSI processing. In: M. K. Balazs, ed. Proceedings of the 10th annual semiconductor pure water conference, Santa Clara, CA, February 26–28, 1991, 128–146

Sato H, Hashimoto N, Shinoda T, Takino K. Dissolved oxygen removal in ultrapure water for semiconductor processes. In: M. K. Balazs, ed. Proceedings of the 10th annual semiconductor pure water conference, Santa Clara, CA, February 26–28, 1991, 147–164

Li K, Chua I, Ng W J, Teo W K. Removal of dissolved oxygen in ultrapure water using a membrane reactor. Chemical Engineering Science, 1995, 50: 3547–3556

Bayer A G. Catalytic removal of dissolved oxygen from water. Organic Chemical Division, Forschung/Anwendungstechnik Lewatit, Ionenaustauscher/Katalysatoren, Geb. B106, Leverkusen. 1990, 1–6

Ozdemir S S, Buonomenna M G, Drioli E. Catalytic polymeric membranes: preparation and application. Applied Catalysis A: General, 2006, 307: 167–183

van der Vaart R, Lebedeva V I, Petrova I V, Plyasova LM, Rudina N A, Kochubey D I, Tereshchenko G F, Volkov V V, van Erkel J. Preparation and characterisation of palladium-loaded polypropylene porous hollow fibre membranes for hydrogenation of dissolved oxygen in water. Journal of Membrane Science. 2007, 299: 38–44

Saito T. Process for removing dissolved oxygen from water and system therefore. European Patent Application, 1991, EP0427191A1

Saito T, Hiroshi N, Mituru I, Ken N, Tujimura M. Simultaneous removal of DO and TOC in ultrapure water by using UV rays. Desalination, 1994, 98: 249–255

Lee H-S, Chung H, Cho Y-H, Ahn D-H, Kim E-K. Dissolved oxygen removal in a column packed with catalyst. Journal of the Korean Nuclear Society,1996, 28(5): 482–487

Teo W K, Ng W J, Li K, Chua I. Membrane reactor for the removal of dissolved oxygen from water. UK patent, GB2283015, 1998