Removal of Heavy Metal Ion Using Polymer-Functionalized Activated Carbon: Aspects of Environmental Economic and Chemistry Education

Journal of Analytical Methods in Chemistry - Tập 2020 - Trang 1-13 - 2020
Hoang Thu Ha1, Nguyen Thi Huong2, Le Linh Dan3, Nguyen Duy Tung4, Vinh bao Trung5, Tran Dinh Minh6
1Faculty of Pedagogy, VNU University of Education, Vietnam National University, Cau Giay, Hanoi 100000, Vietnam
2Faculty of Educational Management, VNU University of Education, Vietnam National University, Cau Giay, Hanoi 100000, Vietnam
3Hanoi-Amsterdam High School for the Gifted, Hanoi, Vietnam
4Department of Physics, High School for Gifted Students, Hanoi University of Science, Vietnam National University, Hanoi, Vietnam
5High School of Education Sciences (HES), VNU University of Education, Vietnam National University, Cau Giay, Hanoi 100000, Vietnam
6Faculty of Educational Technology, VNU University of Education, Vietnam National University, Cau Giay, Hanoi 100000, Vietnam

Tóm tắt

Numerous countries have shown signs of environmental pollution to prioritize economic growth and benefits, leading to seriously contaminated waters. This work indicated the method to synthesize a green material, which could remove contaminants to protect the natural environment. The porosity and functionality effects of amine-functionalized activated carbon (AFAC) enhanced the removal of toxic heavy metals (THMs) in aqueous solution. The raw activated carbon (RAC) was thermally modified with ultrahigh pure nitrogen (UHPN) at 500°C and 1000°C and then amine-functionalized with coupling agent of aminopropyltriethoxysilane (APS). They were denoted as AFAC-5 and AFAC-10, respectively. The data showed an enhanced metal adsorption capacity of the AFACs, because the modification produced more desired porosity and increased amine functional groups. AFAC-10, modified at a higher temperature, showed much higher THM adsorption capacity than AFAC-5, modified at a lower temperature, and RAC. The adsorption capacity decreased in the following order: Ni > Cd > Zn, which was in good agreement with the increasing electronegativity and ionic potential and the decreasing atomic radius. The maximum THM adsorption capacity of AFAC-10 for Ni, Cd, and Zn was 242.5, 226.9, and 204.3 mg/g, respectively.

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Tài liệu tham khảo

10.1155/2018/2830286

10.1155/2018/8436948

10.1155/2019/5037532

10.1155/2014/460942

10.3390/ma12091407

10.1007/s11356-018-2297-3

10.1007/s11164-018-3506-x

10.1016/j.jenvman.2017.12.085

10.1007/s10163-016-0570-4

10.1016/j.jhazmat.2007.09.101

10.1021/es901659n

10.1016/j.rser.2003.12.001

10.2343/geochemj.1.0065

10.1021/j150579a011

10.1039/ft9918702995

10.1002/jctb.280620103

10.1006/eesa.2000.1947

1971

1997

10.1016/s0304-3894(00)00234-x

10.1016/j.jmrt.2014.03.002

10.1371/journal.pone.0065634

2006, American-eurasian Journal of Agricultural & Environmental Sciences, 1, 179

10.1016/j.jenvman.2009.06.001

10.1002/jctb.1585

2019