Recognition of dicarboxylic acids by a bis pyrimidine amine linked xylene spacer: a unique gauche dimeric complex of host and adipic acid detected by X-ray
Tóm tắt
A pyrimidine based receptor (pyrimidine amine linked xylene spacer) has been synthesized for recognition of dicarboxylic acids. Binding studies have been performed by UV–vis method by varying the chain length of dicarboxylic acids. The downfield chemical shift of amine protons of receptor in presence of adipic acid or glutaric acid and the 1:1 dimeric crystal structure of the receptor and adipic acid reveal the strong binding interaction.
Tài liệu tham khảo
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