Recent progress and remaining challenges in post-combustion CO2 capture using metal-organic frameworks (MOFs)

Hajilary, 2018, Evaluation of socio-economic factors on CO2 missions in Iran: factorial design and multivariable methods, J Clean Prod, 189, 10.1016/j.jclepro.2018.04.067 Zhang, 2013, MOFs for CO2 capture and separation from flue gas mixtures: the effect of multifunctional sites on their adsorption capacity and selectivity, Chem Commun, 49, 653, 10.1039/C2CC35561B Liu, 2012, Progress in adsorption-based CO2 capture by metal–organic frameworks, Chem Soc Rev, 41, 2308, 10.1039/C1CS15221A Li, 2011, Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks, Coord Chem Rev, 255, 1791, 10.1016/j.ccr.2011.02.012 Hester, 2009 Rochelle, 2009, Amine scrubbing for CO2 capture, Science, 325, 1652, 10.1126/science.1176731 Samanta, 2012, Post-combustion CO2 capture using solid sorbents: a review, Ind Eng Chem Res, 51, 1438, 10.1021/ie200686q Yang, 2008, Progress in carbon dioxide separation and capture: a review, J Environ Sci, 20, 14, 10.1016/S1001-0742(08)60002-9 D'Alessandro, 2010, Carbon dioxide capture: prospects for new materials, Angew Chemie Int Ed, 49, 6058, 10.1002/anie.201000431 William, 2007, A review of the stern review on the economics of climate change, J Econ Lit, XLV, 686 Zhang, 2017, Effect of flow and module configuration on SO2 absorption by using membrane contactors, Glob Nest J, 19, 716 Rezakazemi, 2017, Hybrid systems: combining membrane and absorption technologies leads to more efficient acid gases (CO2 and H2 S) removal from natural gas, J CO2 Util, 18, 362, 10.1016/j.jcou.2017.02.006 Shirazian, 2012, Separation of CO 2 by single and mixed aqueous amine solvents in membrane contactors: fluid flow and mass transfer modeling, Eng Comput, 28, 189, 10.1007/s00366-011-0237-7 Fasihi, 2012, Computational fluid dynamics simulation of transport phenomena in ceramic membranes for SO2 separation, Math Comput Model, 56, 278, 10.1016/j.mcm.2012.01.010 2018, CFD modeling of CO2 capture by water-based nanofluids using hollow fiber membrane contactor, Int J Greenh Gas Control Rezakazemi, 2019, CO2 absorption enhancement by water-based nanofluids of CNT and SiO2 using hollow-fiber membrane contactor, Sep Purif Technol, 210, 920, 10.1016/j.seppur.2018.09.005 Razavi, 2016, Simulation of CO2 absorption by solution of ammonium ionic liquid in hollow-fiber contactors, Chem Eng Process Process Intensif, 108, 27, 10.1016/j.cep.2016.07.001 Mesbah, 2018, Accurate prediction of miscibility of CO2 and supercritical CO2 in ionic liquids using machine learning, J CO2 Util, 25, 99, 10.1016/j.jcou.2018.03.004 Dashti, 2018, Estimating CH4 and CO2 solubilities in ionic liquids using computational intelligence approaches, J Mol Liq, 271, 661, 10.1016/j.molliq.2018.08.150 Soroush, 2018, A robust predictive tool for estimating CO2 solubility in potassium based amino acid salt solutions, Chin J Chem Eng, 10.1016/j.cjche.2017.10.002 Soroush, 2019, ANFIS modeling for prediction of CO 2 solubility in potassium and sodium based amino acid Salt solutions, J Environ Chem Eng, 7, 10.1016/j.jece.2019.102925 Walton, 2008, Understanding inflections and steps in carbon dioxide adsorption isotherms in metal-organic frameworks, J Am Chem Soc, 130, 406, 10.1021/ja076595g Mueller, 2006, Metal–organic frameworks—prospective industrial applications, J Mater Chem, 16, 626, 10.1039/B511962F Chae, 2004, A route to high surface area, porosity and inclusion of large molecules in crystals, Nature, 427, 523, 10.1038/nature02311 Kitagawa, 2004, Functional porous coordination polymers, Angew Chemie Int Ed, 43, 2334, 10.1002/anie.200300610 Rowsell, 2004, Hydrogen sorption in functionalized metal−organic frameworks, J Am Chem Soc, 126, 5666, 10.1021/ja049408c Rowsell, 2006, Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal−organic frameworks, J Am Chem Soc, 128, 1304, 10.1021/ja056639q Ma, 2008, Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane uptake, J Am Chem Soc, 130, 1012, 10.1021/ja0771639 Li, 1999, Design and synthesis of an exceptionally stable and highly porous metal-organic framework, Nature, 402, 276, 10.1038/46248 Eddaoudi, 2002, Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage, Science, 295, 469, 10.1126/science.1067208 Howarth, 2016, Chemical, thermal and mechanical stabilities of metal–organic frameworks, Nat Rev Mater, 1, 15018, 10.1038/natrevmats.2015.18 Abrahams, 1994, Assembly of porphyrin building blocks into network structures with large channels, Nature, 369, 727, 10.1038/369727a0 Koppens, 2005, Control and detection of singlet-triplet mixing in a random nuclear field, Science, 309, 1346, 10.1126/science.1113719 Rezakazemi, 2014, State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): an overview on current status and future directions, Prog Polym Sci, 39, 817, 10.1016/j.progpolymsci.2014.01.003 Long, 2009, The pervasive chemistry of metal–organic frameworks, Chem Soc Rev, 38, 1213, 10.1039/b903811f Tranchemontagne, 2009, Secondary building units, nets and bonding in the chemistry of metal–organic frameworks, Chem Soc Rev, 38, 1257, 10.1039/b817735j Yaghi, 2003, Reticular synthesis and the design of new materials, Nature, 423, 705, 10.1038/nature01650 O'Keeffe, 2009, Design of MOFs and intellectual content in reticular chemistry: a personal view, Chem Soc Rev, 38, 1215, 10.1039/b802802h Way, 2011, Sun-driven microbial synthesis of chemicals in space, Int J Astrobiol, 10, 359, 10.1017/S1473550411000218 Allen, 2016, Associations of cognitive function scores with carbon dioxide, ventilation, and volatile organic compound exposures in office workers: a controlled exposure study of green and conventional office environments, Environ Health Perspect, 124, 805, 10.1289/ehp.1510037 Lawson, 2019, Amine-functionalized MIL-101 monoliths for CO2 removal from enclosed environments, Energy Fuels, 33, 2399, 10.1021/acs.energyfuels.8b04508 Darunte, 2016, Direct air capture of CO2 using amine functionalized MIL-101(Cr), ACS Sustain Chem Eng, 4, 5761, 10.1021/acssuschemeng.6b01692 Chaemchuen, 2013, Metal–organic frameworks for upgrading biogas via CO2 adsorption to biogas green energy, Chem Soc Rev, 42, 9304, 10.1039/c3cs60244c Tchalala, 2019, Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air, Nat Commun, 10, 1328, 10.1038/s41467-019-09157-2 Clark, 2019, Highly defective UiO-66 materials for the adsorptive removal of perfluorooctanesulfonate, ACS Sustain Chem Eng, 7, 6619, 10.1021/acssuschemeng.8b05572 Liu, 2012, Recent advances in carbon dioxide capture with metal-organic frameworks, Greenh Gases Sci Technol, 2, 239, 10.1002/ghg.1296 Erucar, 2018, High-throughput molecular simulations of metal organic frameworks for CO2 separation: opportunities and challenges, Front Mater, 5, 4, 10.3389/fmats.2018.00004 Seoane, 2015, Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture?, Chem Soc Rev, 44, 2421, 10.1039/C4CS00437J Belmabkhout, 2016, Low concentration CO2 capture using physical adsorbents: are metal–organic frameworks becoming the new benchmark materials?, Chem Eng J, 296, 386, 10.1016/j.cej.2016.03.124 Yu, 2017, CO2 capture and separations using MOFs: computational and experimental studies, Chem Rev, 117, 9674, 10.1021/acs.chemrev.6b00626 Li, 2018, Recent advances in gas storage and separation using metal–organic frameworks, Mater Today, 21, 108, 10.1016/j.mattod.2017.07.006 Lin, 2017, Metal-organic frameworks for carbon dioxide capture and methane storage, Adv Energy Mater, 7, 10.1002/aenm.201601296 Hu, 2019, CO2 Capture in metal-organic framework adsorbents: an engineering perspective, Adv Sustain Syst, 3 Sumida, 2012, Carbon dioxide capture in metal–organic frameworks, Chem Rev, 112, 724, 10.1021/cr2003272 Trickett, 2017, The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion, Nat Rev Mater, 2, 17045, 10.1038/natrevmats.2017.45 Hu Z., Wang Y., Shah B.B., Zhao D. CO2 Capture in Metal-Organic Framework Adsorbents: An Engineering Perspective. Adv Sustain Syst 2019;3:1800080. doi:10.1002/adsu.201800080. Ding, 2019, Carbon capture and conversion using metal–organic frameworks and MOF-based materials, Chem Soc Rev, 48, 2783, 10.1039/C8CS00829A Wang, 2017, A review of post-combustion CO2 capture technologies from coal-fired power plants, Energy Proc, 114, 650, 10.1016/j.egypro.2017.03.1209 Zhang, 2020 Li, 2017, Recent advances in gas storage and separation using metal – organic frameworks, Mater Today, xx Sohaib, 2020, Modeling pre-combustion CO2 capture with tubular membrane contactor using ionic liquids at elevated temperatures, Sep Purif Technol, 241, 10.1016/j.seppur.2020.116677 Ge, 2020, CO2 capture and separation of metal–organic frameworks, 2050, 5 Rezakazemi, 2011, CFD simulation of natural gas sweetening in a gas–liquid hollow-fiber membrane contactor, Chem Eng J, 168, 1217, 10.1016/j.cej.2011.02.019 Berger, 2011, Comparing physisorption and chemisorption solid sorbents for use separating CO2 from flue gas using temperature swing adsorption, Energy Proc, 4, 562, 10.1016/j.egypro.2011.01.089 Xiang, 2012, Microporous metal-organic framework with potential for carbon dioxide capture at ambient conditions, Nat Commun, 3, 954, 10.1038/ncomms1956 Zhou, 2012, Introduction to metal–organic frameworks, Chem Rev, 112, 673, 10.1021/cr300014x Qiao, 2019, [Zn4O] Cluster-based metal-organic frameworks as catalysts for conversion of CO2, Chinese J Chem, 37, 474, 10.1002/cjoc.201800587 Hou, 2019, A noble-metal-free metal-organic framework (MOF) catalyst for the highly efficient conversion of CO2 with propargylic alcohols, Angew Chem, 131, 587, 10.1002/ange.201811506 Sun, 2019, A stable mesoporous Zr-based metal organic framework for highly efficient CO2 conversion, Inorg Chem, 58, 7480, 10.1021/acs.inorgchem.9b00701 Qian, 2013, Structure stability of metal-organic framework MIL-53 (Al) in aqueous solutions, Int J Hydrog Energy, 38, 16710, 10.1016/j.ijhydene.2013.07.054 Xiang, 2010, Multiscale simulation and modelling of adsorptive processes for energy gas storage and carbon dioxide capture in porous coordination frameworks, Energy Environ Sci, 3, 1469, 10.1039/c0ee00049c Mutyala, 2019, CO2 capture and adsorption kinetic study of amine-modified MIL-101 (Cr), Chem Eng Res Des, 143, 241, 10.1016/j.cherd.2019.01.020 Yang, 2010, Synthesis of metal–organic framework MIL-101 in TMAOH-Cr(NO3)3-H2BDC-H2O and its hydrogen-storage behavior, Microporous Mesoporous Mater, 130, 174, 10.1016/j.micromeso.2009.11.001 Wang, 2019, A new microporous metal-organic framework with a novel trinuclear nickel cluster for selective CO2 adsorption, Inorg Chem Commun, 104, 78, 10.1016/j.inoche.2019.03.029 Yang, 2019, A Ni3O-cluster based porous MOF for catalytic conversion of CO2 to cyclic carbonates, J Solid State Chem, 276, 190, 10.1016/j.jssc.2019.05.010 Liao, 2019, Acidity and Cd 2+ fluorescent sensing and selective CO2 adsorption by a water-stable Eu-MOF, Dalt Trans, 48, 4489, 10.1039/C9DT00539K Wang, 2017, Lanthanide-based metal-organic framework nanosheets with unique fluorescence quenching properties for two-color intracellular adenosine imaging in living cells, NPG Asia Mater, 9, 1, 10.1038/am.2017.7 Kurisingal, 2019, Binary metal-organic frameworks: catalysts for the efficient solvent-free CO2 fixation reaction via cyclic carbonates synthesis, Appl Catal A Gen, 571, 1, 10.1016/j.apcata.2018.11.035 Xiang, 2019, Enhanced cycloaddition of CO2 to epichlorohydrin over zeolitic imidazolate frameworks with mixed linkers under solventless and co-catalyst-free condition, Catal Today, 0 Agarwal, 2019, Flexible Zn-MOF exhibiting selective CO2 adsorption and efficient lewis acidic catalytic activity, Cryst Growth Des, 19, 2010, 10.1021/acs.cgd.8b01462 Liu, 2019, Photosensitizing single-site metal−organic framework enabling visible-light-driven CO2 reduction for syngas production, Appl Catal B Environ, 245, 496, 10.1016/j.apcatb.2019.01.014 Li, 2019, Specific K + binding sites as CO2 traps in a porous MOF for enhanced CO2 selective sorption, Small, 15 Sun, 2019, MOF-801 incorporated PEBA mixed-matrix composite membranes for CO2 capture, Sep Purif Technol, 217, 229, 10.1016/j.seppur.2019.02.036 Yang, 2012, CO2 capture and conversion using Mg-MOF-74 prepared by a sonochemical method, Energy Environ Sci, 5, 6465, 10.1039/C1EE02234B ul, 2015, Structural stability of metal organic frameworks in aqueous media – Controlling factors and methods to improve hydrostability and hydrothermal cyclic stability, Microporous Mesoporous Mater, 201, 61, 10.1016/j.micromeso.2014.09.034 Park, 2006, Exceptional chemical and thermal stability of zeolitic imidazolate frameworks, Proc Natl Acad Sci, 103, 10186, 10.1073/pnas.0602439103 Burtch, 2014, Water stability and adsorption in metal–organic frameworks, Chem Rev, 114, 10575, 10.1021/cr5002589 Coe, 1995, Structural effects on the adsorptive properties of molecular sieves for air separation, 213 Nouar, 2008, Supermolecular building blocks (SBBs) for the design and synthesis of highly porous metal-organic frameworks, J Am Chem Soc, 130, 1833, 10.1021/ja710123s Leus, 2016, Systematic study of the chemical and hydrothermal stability of selected “stable” metal organic frameworks, Microporous Mesoporous Mater, 226, 110, 10.1016/j.micromeso.2015.11.055 Kang, 2011, Chemical and thermal stability of isotypic metal–organic frameworks: effect of metal ions, Chem – A Eur J, 17, 6437, 10.1002/chem.201100316 Kandiah, 2010, Synthesis and stability of tagged UiO-66 Zr-MOFs, Chem Mater, 22, 6632, 10.1021/cm102601v Jhung, 2012, Analogous porous metal–organic frameworks: synthesis, stability and application in adsorption, CrystEngComm, 14, 7099, 10.1039/c2ce25760b Leus, 2016, Systematic study of the chemical and hydrothermal stability of selected “stable” metal organic frameworks, Microporous Mesoporous Mater, 226, 110, 10.1016/j.micromeso.2015.11.055 Devic, 2014, High valence 3p and transition metal based MOFs, Chem Soc Rev, 43, 6097, 10.1039/C4CS00081A Mondloch, 2013, Vapor-phase metalation by atomic layer deposition in a metal–organic framework, J Am Chem Soc, 135, 10294, 10.1021/ja4050828 Canivet, 2014, Water adsorption in MOFs: fundamentals and applications, Chem Soc Rev, 43, 5594, 10.1039/C4CS00078A Gu, 2010, MOF-5 metal−organic framework as sorbent for in-field sampling and preconcentration in combination with thermal desorption GC/MS for determination of atmospheric formaldehyde, Anal Chem, 82, 1365, 10.1021/ac902450f Hu, 2015, Ionized Zr-MOFs for highly efficient post-combustion CO2 capture, Chem Eng Sci, 124, 61, 10.1016/j.ces.2014.09.032 Hester, 2016, On thermal stability and catalytic reactivity of Zr-based metal – organic framework (UiO-67) encapsulated Pt catalysts, J Catal, 340, 85, 10.1016/j.jcat.2016.05.003 Katz, 2015, Exploiting parameter space in MOFs: a 20-fold enhancement of phosphate-ester hydrolysis with UiO-66-NH 2, Chem Sci, 6, 2286, 10.1039/C4SC03613A Tan, 2011, Mechanical properties of hybrid inorganic–organic framework materials: establishing fundamental structure–property relationships, Chem Soc Rev, 40, 1059, 10.1039/c0cs00163e Qian, 2013, Structure stability of metal-organic framework MIL-53 (Al) in aqueous solutions, Int J Hydrog Energy, 38, 16710, 10.1016/j.ijhydene.2013.07.054 Ren, 2014, Modulated synthesis of chromium-based metal-organic framework (MIL-101) with enhanced hydrogen uptake, Int J Hydrog Energy, 39, 12018, 10.1016/j.ijhydene.2014.06.019 Lv D., Chen J., Chen Y., Liu Z., Xu Y., Duan C. et al. Moisture stability of ethane-selective Ni(II), Fe(III), Zr(IV)-based metalorganic frameworks. AIChE J 2019;65. doi:10.1002/aic.16616. Mondloch, 2014, Are Zr 6 -based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse, Chem Commun, 50, 8944, 10.1039/C4CC02401J Henninger, 2012, MOFs for use in adsorption heat pump processes, Eur J Inorg Chem, 2012, 2625, 10.1002/ejic.201101056 Nugent, 2013, Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation, Nature, 495, 80, 10.1038/nature11893 Fracaroli, 2014, Metal–organic frameworks with precisely designed interior for carbon dioxide capture in the presence of water, J Am Chem Soc, 136, 8863, 10.1021/ja503296c Li, 2018, Stable aluminum metal–organic frameworks (Al-MOFs) for balanced CO2 and water selectivity, ACS Appl Mater Interfaces, 10, 3160, 10.1021/acsami.7b17026 Liu, 2011, Stability effects on CO2 adsorption for the DOBDC series of metal–organic frameworks, Langmuir, 27, 11451, 10.1021/la201774x Liu, 2015, Topology-guided design and syntheses of highly stable mesoporous porphyrinic zirconium metal–organic frameworks with high surface area, J Am Chem Soc, 137, 413, 10.1021/ja5111317 Kalidindi, 2015, Chemical and structural stability of zirconium-based metal-organic frameworks with large three-dimensional pores by linker engineering, Angew Chem Int Ed, 54, 221, 10.1002/anie.201406501 Low, 2009, Virtual high throughput screening confirmed experimentally: porous coordination polymer hydration, J Am Chem Soc, 131, 15834, 10.1021/ja9061344 Schoenecker, 2012, Effect of water adsorption on retention of structure and surface area of metal–organic frameworks, Ind Eng Chem Res, 51, 6513, 10.1021/ie202325p Milner, 2017, A diaminopropane-appended metal–organic framework enabling efficient CO2 capture from coal flue gas via a mixed adsorption mechanism, J Am Chem Soc, 139, 13541, 10.1021/jacs.7b07612 Hong, 2009, Porous chromium terephthalate MIL-101 with coordinatively unsaturated sites: surface functionalization, encapsulation, sorption and catalysis, Adv Funct Mater, 19, 1537, 10.1002/adfm.200801130 Wittmann, 2015, Enhancing the water stability of Al-MIL-101-NH 2 via postsynthetic modification, Chem – A Eur J, 21, 314, 10.1002/chem.201404654 Bezverkhyy, 2014, MIL-53(Al) under reflux in water: formation of γ-AlO(OH) shell and H2BDC molecules intercalated into the pores, Microporous Mesoporous Mater, 183, 156, 10.1016/j.micromeso.2013.09.015 DeCoste, 2013, Stability and degradation mechanisms of metal–organic frameworks containing the Zr6O4(OH)4 secondary building unit, J Mater Chem A, 1, 5642, 10.1039/c3ta10662d Yang, 2007, Fluorous metal−organic frameworks for high-density gas adsorption, J Am Chem Soc, 129, 15454, 10.1021/ja0775265 Chen, 2019, Highly efficient synthesis of a moisture-stable nitrogen-abundant metal–organic framework (MOF) for large-scale CO2 capture, Ind Eng Chem Res, 58, 1773, 10.1021/acs.iecr.8b05239 Katsenis, 2015, In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework, Nat Commun, 6, 6662, 10.1038/ncomms7662 Coudert, 2015, Responsive metal–organic frameworks and framework materials: under pressure, taking the heat, in the spotlight, with friends, Chem Mater, 27, 1905, 10.1021/acs.chemmater.5b00046 Wu, 2013, Exceptional mechanical stability of highly porous zirconium metal–organic framework UiO-66 and its important implications, J Phys Chem Lett, 4, 925, 10.1021/jz4002345 Van de Voorde, 2015, Improving the mechanical stability of zirconium-based metal–organic frameworks by incorporation of acidic modulators, J Mater Chem A, 3, 1737, 10.1039/C4TA06396A Bennett, 2015, Mechanical properties of zeolitic metal–organic frameworks: mechanically flexible topologies and stabilization against structural collapse, CrystEngComm, 17, 286, 10.1039/C4CE02145B Samanta, 2006, Theoretical assessment of the elastic constants and hydrogen storage capacity of some metal-organic framework materials, J Chem Phys, 125, 10.1063/1.2337287 Tan, 2012, Exceptionally low shear modulus in a prototypical imidazole-based metal-organic framework, Phys Rev Lett, 108, 10.1103/PhysRevLett.108.095502 Zhou, 2006, Lattice dynamics of metal-organic frameworks: neutron inelastic scattering and first-principles calculations, Phys Rev B, 74, 10.1103/PhysRevB.74.180301 Santos, 2019, Effect of high pressure CO2 sorption on the stability of metalorganic framework MOF-177 at different temperatures, J Solid State Chem, 269, 320, 10.1016/j.jssc.2018.09.046 Adams, 2010, Metal organic framework mixed matrix membranes for gas separations, Microporous Mesoporous Mater, 131, 13, 10.1016/j.micromeso.2009.11.035 Schoedel, 2016, The role of metal–organic frameworks in a carbon-neutral energy cycle, Nat Energy, 1, 16034, 10.1038/nenergy.2016.34 Zornoza, 2013, Metal organic framework based mixed matrix membranes: an increasingly important field of research with a large application potential, Microporous Mesoporous Mater, 166, 67, 10.1016/j.micromeso.2012.03.012 Ben-Mansour, 2018, An efficient temperature swing adsorption (TSA) process for separating CO2 from CO2/N2 mixture using Mg-MOF-74, Energy Convers Manag, 156, 10, 10.1016/j.enconman.2017.11.010 Rajagopalan, 2018, The effect of nitrogen adsorption on vacuum swing adsorption based post-combustion CO2 capture, Int J Greenh Gas Control, 78, 437, 10.1016/j.ijggc.2018.09.002 Maring, 2013, A new simplified pressure/vacuum swing adsorption model for rapid adsorbent screening for CO2 capture applications, Int J Greenh Gas Control, 15, 16, 10.1016/j.ijggc.2013.01.009 Adhikari, 2016, Improving CO2 adsorption capacities and CO2/N2 separation efficiencies of MOF-74 (Ni, Co) by doping palladium-containing activated carbon, Chem Eng J, 284, 1348, 10.1016/j.cej.2015.09.086 Pai, 2019, Separation and purification technology evaluation of diamine-appended metal-organic frameworks for post-combustion CO2 capture by vacuum swing adsorption, Sep Purif Technol, 211, 540, 10.1016/j.seppur.2018.10.015 Dasgupta, 2012, CO2 recovery from mixtures with nitrogen in a vacuum swing adsorber using metal organic framework adsorbent : a comparative study, Int J Greenh Gas Control, 7, 225, 10.1016/j.ijggc.2011.10.007 Aaron, 2005, Separation of CO2 from flue gas: a review, Sep Sci Technol, 40, 321, 10.1081/SS-200042244 Chen, 2019, Microwave-assisted rapid synthesis of well-shaped MOF-74 (Ni) for CO2 efficient capture, Inorg Chem, 58, 2717, 10.1021/acs.inorgchem.8b03271 Banerjee, 2009, Control of pore size and functionality in isoreticular zeolitic imidazolate frameworks and their carbon dioxide selective capture properties, J Am Chem Soc, 131, 3875, 10.1021/ja809459e Niu, 2008, Copper-catalyzed coupling of tertiary aliphatic amines with terminal alkynes to propargylamines via C−H activation, J Org Chem, 73, 3961, 10.1021/jo800279j Bastin, 2008, A microporous metal−organic framework for separation of CO2/N2 and CO2 /CH4 by Fixed-bed adsorption, J Phys Chem C, 112, 1575, 10.1021/jp077618g Chen, 2007, A triply interpenetrated microporous metal−organic framework for selective sorption of gas molecules, Inorg Chem, 46, 8490, 10.1021/ic7014034 Llewellyn, 2008, High uptakes of CO2 and CH4 in mesoporous metal–organic frameworks MIL-100 and MIL-101, Langmuir, 24, 7245, 10.1021/la800227x Dietzel, 2009, Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide, J Mater Chem, 19, 7362, 10.1039/b911242a Qianmei, 2017, Carbon dioxide adsorption over amine-functionalized MOFs assessing the feasibility of using the heat demand-outdoor temperature function for a long-term district heat demand forecast, Energy Proc, 142, 2152 Mutyala, 2019, Chemical engineering research and design CO2 capture and adsorption kinetic study of amine-modified MIL-101 (Cr), Chem Eng Res Des, 143, 241, 10.1016/j.cherd.2019.01.020 Wang R., Mi J., Dong X., Liu X., Lv Y., Du J. et al. Creating a Polar Surface in Carbon Frameworks from Single-Source MetalOrganic Frameworks for Advanced CO2 Uptake and LithiumSulfur Batteries. Chem Mater 2019;31:4258–4266. doi:10.1021/acs.chemmater.9b01264. Demessence, 2009, Strong CO2 binding in a water-stable, triazolate-bridged metal−organic framework functionalized with ethylenediamine, J Am Chem Soc, 131, 8784, 10.1021/ja903411w Couck, 2009, An amine-functionalized MIL-53 metal−organic framework with large separation power for CO2 and CH4, J Am Chem Soc, 131, 6326, 10.1021/ja900555r Zheng, 2011, Enhanced CO2 binding affinity of a high-uptake rht-type metal−organic framework decorated with acylamide groups, J Am Chem Soc, 133, 748, 10.1021/ja110042b Bloch, 2010, Metal insertion in a microporous metal−organic framework lined with 2,2′-bipyridine, J Am Chem Soc, 132, 14382, 10.1021/ja106935d Forgan R.S. The surface chemistry of metalorganic frameworks and their applications. Dalt Trans 2019;48:9037–9042. doi:10.1039/C9DT01710K. Hu, 2018, High CO2 adsorption capacities in UiO type MOFs comprising heterocyclic ligand, Microporous Mesoporous Mater, 256, 25, 10.1016/j.micromeso.2017.07.051 Asgari, 2020, Understanding how ligand functionalization influences CO2 and N2 adsorption in a sodalite metal–organic framework, Chem Mater, 10.1021/acs.chemmater.9b04631 Kazemi, 2018, Carbon dioxide capture in MOFs: the effect of ligand functionalization, Polyhedron, 154, 236, 10.1016/j.poly.2018.07.042 Wang, 2018, Three Cd(II) MOFs with different functional groups: selective CO2 capture and metal ions detection, Inorg Chem, 57, 5232, 10.1021/acs.inorgchem.8b00272 He, 2019, Incorporation of bifunctional aminopyridine into an NbO-type MOF for the markedly enhanced adsorption of CO2 and C2H2 over CH4, Inorg Chem Front, 6, 1177, 10.1039/C9QI00195F Wang, 2018, Three Cd(II) MOFs with different functional groups: selective CO2 capture and metal ions detection, Inorg Chem, 57, 5232, 10.1021/acs.inorgchem.8b00272 Belmabkhout, 2018, Natural gas upgrading using a fluorinated MOF with tuned H2S and CO2 adsorption selectivity, Nat Energy, 3, 1059, 10.1038/s41560-018-0267-0 Belmabkhout, 2011, Simultaneous adsorption of H2S and CO2 on triamine-grafted pore-expanded mesoporous MCM-41 silica, Energy Fuels, 25, 1310, 10.1021/ef1015704 Zhao, 2013, The hydrolysis of carbonyl sulfide at low temperature: a review, Sci World J Kadijani, 2014, Adsorptive desulfurization of liquefied petroleum gas for carbonyl sulfide removal, Open J Chem Eng Sci, 1, 79, 10.15764/OJCES.2014.01006 Tsai, 2001, Removal of H2S from exhaust gas by use of alkaline activated carbon, Adsorption, 7, 357, 10.1023/A:1013142405297 Bhatt, 2016, A fine-tuned fluorinated MOF addresses the needs for trace CO2 removal and air capture using physisorption, J Am Chem Soc, 138, 9301, 10.1021/jacs.6b05345 Shekhah, 2015, A facile solvent-free synthesis route for the assembly of a highly CO2 selective and H2S tolerant NiSIFSIX metal–organic framework, Chem Commun, 51, 13595, 10.1039/C5CC04487A Guillerm, 2018, Postsynthetic selective ligand cleavage by solid–gas phase ozonolysis fuses micropores into mesopores in metal–organic frameworks, J Am Chem Soc, 140, 15022, 10.1021/jacs.8b09682 Criegee, 1975, Mechanism of ozonolysis, Angew Chem Int Ed Engl, 14, 745, 10.1002/anie.197507451 Marshall, 2016, Postsynthetic modification of zirconium metal-organic frameworks, Eur J Inorg Chem, 2016, 4310, 10.1002/ejic.201600394 Rezakazemi, 2012, Sorption properties of hydrogen-selective PDMS/zeolite 4A mixed matrix membrane, Int J Hydrog Energy, 37, 17275, 10.1016/j.ijhydene.2012.08.109 Rostamizadeh, 2013, Gas permeation through H2-selective mixed matrix membranes: experimental and neural network modeling, Int J Hydrog Energy, 38, 1128, 10.1016/j.ijhydene.2012.10.069 Rezakazemi, 2012, Hydrogen separation and purification using crosslinkable PDMS/zeolite A nanoparticles mixed matrix membranes, Int J Hydrog Energy, 37, 14576, 10.1016/j.ijhydene.2012.06.104 Rezakazemi, 2013, Gas sorption in H2 -selective mixed matrix membranes: experimental and neural network modeling, Int J Hydrog Energy, 38, 14035, 10.1016/j.ijhydene.2013.08.062 Rezakazemi, 2017, H2 -selective mixed matrix membranes modeling using ANFIS, PSO-ANFIS, GA-ANFIS, Int J Hydrog Energy, 42, 15211, 10.1016/j.ijhydene.2017.04.044 Dashti, 2018, Accurate prediction of solubility of gases within H2 -selective nanocomposite membranes using committee machine intelligent system, Int J Hydrog Energy, 43, 6614, 10.1016/j.ijhydene.2018.02.046 2018, Polyurethane-SAPO-34 mixed matrix membrane for CO2/CH4 and CO2/N2 separation, Chin J Chem Eng Riasat Harami, 2019, Mass transfer through PDMS/zeolite 4A MMMs for hydrogen separation: molecular dynamics and grand canonical Monte Carlo simulations, Int Commun Heat Mass Transf, 108, 10.1016/j.icheatmasstransfer.2019.05.005 Zhang, 2018, Modeling of a CO2-piperazine-membrane absorption system, Chem Eng Res Des, 131, 375, 10.1016/j.cherd.2017.11.024 Asadollahzadeh, 2018, Simulation of nonporous polymeric membranes using CFD for bioethanol purification, Macromol Theory Simul, 27, 10.1002/mats.201700084 Mirqasemi, 2020, Zeolitic imidazolate framework membranes for gas and water purification, Environ Chem Lett, 18, 1, 10.1007/s10311-019-00933-6 Rezakazemi, 2018, Thermally stable polymers for advanced high-performance gas separation membranes, Prog Energy Combust Sci, 66, 1, 10.1016/j.pecs.2017.11.002 Rezakazemi, 2015, Synergistic interactions between POSS and fumed silica and their effect on the properties of crosslinked PDMS nanocomposite membranes, RSC Adv, 5, 82460, 10.1039/C5RA13609A Rezakazemi, 2016, Synthesis and gas transport properties of crosslinked poly(dimethylsiloxane) nanocomposite membranes using octatrimethylsiloxy POSS nanoparticles, J Nat Gas Sci Eng, 30, 10, 10.1016/j.jngse.2016.01.033 Riasat Harami, 2019, Sorption in mixed matrix membranes: experimental and molecular dynamic simulation and grand canonical monte carlo method, J Mol Liq, 282, 566, 10.1016/j.molliq.2019.03.047 Ahmad, 2018, Recent advances in poly (Amide-B-Ethylene) based membranes for carbon dioxide (CO2) Capture : a review recent advances in poly (Amide-B-Ethylene) based membranes for carbon, Polym Plast Technol Eng, 00, 1 Fan L., Kang Z., Shen Y., Wang S., Zhao H., Sun H. et al. Mixed Matrix Membranes Based on MetalOrganic Frameworks with Tunable Pore Size for CO2 Separation. Cryst Growth Des 2018;18:4365–4371. doi:10.1021/acs.cgd.8b00307. Liu, 2018, Enhanced CO2/CH4 separation performance of a mixed matrix membrane based on tailored MOF-polymer formulations, Adv Sci, 5, 2, 10.1002/advs.201800982 Sabetghadam A., Liu X., Benzaqui M., Gkaniatsou E., Orsi A., Lozinska M.M. et al. Influence of Filler Pore Structure and Polymer on the Performance of MOF-Based Mixed-Matrix Membranes for CO2 Capture. Chem - A Eur J 2018;24:7949–7956. doi:10.1002/chem.201800253. Shen, 2016, UiO-66-polyether block amide mixed matrix membranes for CO2 separation, J Memb Sci, 513, 155, 10.1016/j.memsci.2016.04.045 Aykac Ozen, 2019, Gas separation characteristic of mixed matrix membrane prepared by MOF-5 including different metals, Sep Purif Technol, 211, 514, 10.1016/j.seppur.2018.09.052 Cheng, 2019, Mixed matrix membranes containing MOF@COF hybrid fillers for efficient CO2/CH4 separation, J Memb Sci, 573, 97, 10.1016/j.memsci.2018.11.060 Sabetghadam, 2019, Thin mixed matrix and dual layer membranes containing metal-organic framework nanosheets and Polyactive™ for CO2 capture, J Memb Sci, 570–571, 226, 10.1016/j.memsci.2018.10.047 Prasetya, 2018, A new and highly robust light-responsive Azo-UiO-66 for highly selective and low energy post-combustion CO2 capture and its application in a mixed matrix membrane for CO2/N2 separation, J Mater Chem A, 6, 16390, 10.1039/C8TA03553A Thür, 2019, Bipyridine-based UiO-67 as novel filler in mixed-matrix membranes for CO2-selective gas separation, J Memb Sci, 576, 78, 10.1016/j.memsci.2019.01.016 Li, 2019, Facile synthesis of amine-functionalized MOFs incorporated polyimide MMMs with enhanced CO2 permselectivity, ChemistrySelect, 4, 2368, 10.1002/slct.201803944 Zhang, 2019, In situ generation of an N-heterocyclic carbene functionalized metal–organic framework by postsynthetic ligand exchange: efficient and selective hydrosilylation of CO2, Angew Chem, 131, 2870, 10.1002/ange.201813064 Guo, 2019, A novel 2D Cu(II)-MOF as a heterogeneous catalyst for the cycloaddition reaction of epoxides and CO2 into cyclic carbonates, J Mol Struct, 1184, 557, 10.1016/j.molstruc.2019.02.076 Crake, 2019, The effect of materials architecture in TiO2/MOF composites on CO2 photoreduction and charge transfer, Small, 15 Wu, 2019, Ruthenium complexes immobilized on an azolium based metal organic framework for highly efficient conversion of CO2 into formic acid, ChemCatChem, 11, 1256, 10.1002/cctc.201801701 Wang, 2019, In-situ incorporation of Copper(II) porphyrin functionalized zirconium MOF and TiO2 for efficient photocatalytic CO2 reduction, Sci Bull, 64, 926, 10.1016/j.scib.2019.05.012 Kim, 2019, Metal–organic framework-mediated strategy for enhanced methane production on copper nanoparticles in electrochemical CO2 reduction, Electrochim Acta, 306, 28, 10.1016/j.electacta.2019.03.101 Han, 2019, Noble metal (Pt, Au@Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO2 conversion catalysts, J Catal, 370, 70, 10.1016/j.jcat.2018.12.005 Yan, 2019, Synthesis of porous ZnMn2O4 flower-like microspheres by using MOF as precursors and its application on photoreduction of CO2 into CO, Appl Surf Sci, 465, 383, 10.1016/j.apsusc.2018.09.211 Liu, 2019, Anchoring Co II ions into a thiol-laced metal–organic framework for efficient visible-light-driven conversion of CO2 into CO, ChemSusChem, 12, 2166, 10.1002/cssc.201900338 Wang, 2019, Monometallic catalytic models hosted in stable metal–organic frameworks for tunable CO2 photoreduction, ACS Catal, 9, 1726, 10.1021/acscatal.8b04887 Li, 2019, Adenine components in biomimetic metal–organic frameworks for efficient CO2 photoconversion, Angew Chem, 131, 5280, 10.1002/ange.201814729 Hou, 2019, A noble-metal-free metal-organic framework (MOF) catalyst for the highly efficient conversion of CO2 with propargylic alcohols, Angew Chem Int Ed, 58, 577, 10.1002/anie.201811506 Mengting, 2019, Applicability of BaTiO3/graphene oxide (GO) composite for enhanced photodegradation of methylene blue (MB) in synthetic wastewater under UV–vis irradiation, Environ Pollut, 255, 10.1016/j.envpol.2019.113182 Alkhatib, 2020, Metal-organic frameworks for photocatalytic CO2 reduction under visible radiation: a review of strategies and applications, Catal Today, 340, 209, 10.1016/j.cattod.2018.09.032 Alvaro, 2007, Semiconductor behavior of a metal-organic framework (MOF), Chem – A Eur J, 13, 5106, 10.1002/chem.200601003 Zhang, 2014, Metal–organic frameworks for artificial photosynthesis and photocatalysis, Chem Soc Rev, 43, 5982, 10.1039/C4CS00103F Zhou, 2020, A leaf-branch TiO2/carbon@MOF composite for selective CO2 photoreduction, Appl Catal B Environ, 264, 10.1016/j.apcatb.2019.118519 Hu, 2020, In situ fabrication of amorphous TiO2/NH2-MIL-125(Ti) for enhanced photocatalytic CO2 into CH4 with H2O under visible-light irradiation, J Colloid Interface Sci, 560, 857, 10.1016/j.jcis.2019.11.003 Chen, 2019, A simple strategy for engineering heterostructures of Au nanoparticle-loaded metal–organic framework nanosheets to achieve plasmon-enhanced photocatalytic CO2 conversion under visible light, J Mater Chem A, 7, 11355, 10.1039/C9TA01840A Li, 2019, Adenine components in biomimetic metal-organic frameworks for efficient CO2 photoconversion, Angew Chem Int Ed, 58, 5226, 10.1002/anie.201814729 Chen, 2020, Integration of enzymes and photosensitizers in a hierarchical mesoporous metal–organic framework for light-driven CO2 reduction, J Am Chem Soc, 142, 1768, 10.1021/jacs.9b12828 Mu, 2020, Electrostatic charge transfer for boosting the photocatalytic CO2 reduction on metal centers of 2D MOF/rGO heterostructure, Appl Catal B Environ, 262, 10.1016/j.apcatb.2019.118144 Gao, 2018, Heterogeneous single-atom catalyst for visible-light-driven high-turnover CO2 reduction: the role of electron transfer, Adv Mater, 30, 10.1002/adma.201704624 Wu, 2019, Encapsulating perovskite quantum dots in iron-based metal-organic frameworks (MOFs) for Efficient photocatalytic CO2 reduction, Angew Chem Int Ed, 58, 9491, 10.1002/anie.201904537 Ding, 2019, Impregnation of semiconductor CdS NPs in MOFs cavities via double solvent method for effective photocatalytic CO2 conversion, J Catal, 375, 21, 10.1016/j.jcat.2019.05.015 Wei, 2019, Different functional group modified zirconium frameworks for the photocatalytic reduction of carbon dioxide, Dalt Trans, 48, 8221, 10.1039/C9DT01767D Dao, 2019, Solvent-free photoreduction of CO2 to CO catalyzed by Fe-MOFs with superior selectivity, Inorg Chem, 58, 8517, 10.1021/acs.inorgchem.9b00824 Sun, 2020, Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts, Energy Environ Sci, 10.1039/C9EE03660A Lee, 2020, Aluminum metal–organic framework triggers carbon dioxide reduction activity, ACS Appl Energy Mater Dou, 2019, Boosting electrochemical CO2 reduction on metal-organic frameworks via ligand doping, Angew Chemie Int Ed, 58, 4041, 10.1002/anie.201814711 Yang, 2020, Covalently anchoring cobalt phthalocyanine on zeolitic imidazolate frameworks for efficient carbon dioxide electroreduction, CrystEngComm, 10.1039/C9CE01517E Tan, 2019, Restructuring of Cu2O to Cu2O@Cu-metal–organic frameworks for selective electrochemical reduction of CO2, ACS Appl Mater Interfaces, 11, 9904, 10.1021/acsami.8b19111 Albo, 2019, Cu/Bi metal-organic framework-based systems for an enhanced electrochemical transformation of CO2 to alcohols, J CO2 Util, 33, 157, 10.1016/j.jcou.2019.05.025 Xin, 2020, Metallocene implanted metalloporphyrin organic framework for highly selective CO2 electroreduction, Nano Energy, 67, 10.1016/j.nanoen.2019.104233 Rezakazemi, 2018, Computational simulation of mass transfer in molecular separation using microporous polymeric membranes, Chem Eng Technol, 41, 1975, 10.1002/ceat.201800082 Lesch D.A. Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks. United States: N. p., 2010. Web. doi:10.2172/1003992. DeSantis, 2017, Techno-economic analysis of metal–organic frameworks for hydrogen and natural gas storage, Energy Fuels, 31, 2024, 10.1021/acs.energyfuels.6b02510 Mason, 2011, Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption, Energy Environ Sci, 4, 3030, 10.1039/c1ee01720a McDonald, 2015, Cooperative insertion of CO2 in diamine-appended metal-organic frameworks, Nature, 519, 303, 10.1038/nature14327 Weiland, 1997, Heat capacity of aqueous monoethanolamine, diethanolamine, N-Methyldiethanolamine, and N-methyldiethanolamine-based blends with carbon dioxide, J Chem Eng Data, 42, 1004, 10.1021/je960314v Queen, 2014, Comprehensive study of carbon dioxide adsorption in the metal–organic frameworks M2 (dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn), Chem Sci, 5, 4569, 10.1039/C4SC02064B Jiao, 2015, Tuning the kinetic water stability and adsorption interactions of Mg-MOF-74 by partial substitution with Co or Ni, Ind Eng Chem Res, 54, 12408, 10.1021/acs.iecr.5b03843 McDonald, 2012, Capture of carbon dioxide from air and flue gas in the alkylamine-appended metal–organic framework mmen-Mg 2 (dobpdc), J Am Chem Soc, 134, 7056, 10.1021/ja300034j Su, 2017, Postsynthetic functionalization of Mg-MOF-74 with tetraethylenepentamine: structural characterization and enhanced CO2 adsorption, ACS Appl Mater Interfaces, 9, 11299, 10.1021/acsami.7b02471 Danaci, 2020, Exploring the limits of adsorption-based CO2 capture using MOFs with PVSA – from molecular design to process economics, Mol Syst Des Eng, 5, 212, 10.1039/C9ME00102F Zhang, 2018, The fixation of carbon dioxide with epoxides catalyzed by cation-exchanged metal-organic framework, Microporous Mesoporous Mater, 258, 55, 10.1016/j.micromeso.2017.08.013 Calleja, 2010, Hydrogen adsorption over Zeolite-like MOF materials modified by ion exchange, Int J Hydrog Energy, 35, 9916, 10.1016/j.ijhydene.2010.02.114