Recent developments in the use of metal oxides for photocatalytic degradation of pharmaceutical pollutants in water—a review

Mezzelani, 2018, Pharmaceuticals in the aquatic environments: evidence of emerged threat and future challenges for marine organisms, Mar. Environ. Res., 140, 41, 10.1016/j.marenvres.2018.05.001 Cuervo Lumbaque, 2019, Current trends in the use of zero-valent iron (Fe0) for degradation of pharmaceuticals present in different water matrices, Trends Environ. Anal. Chem., 24, 10.1016/j.teac.2019.e00069 Patel, 2019, Pharmaceuticals of emerging concern in aquatic Systems: chemistry , occurrence , E ff ects , and removal methods, Chem. Rev., 119, 3510, 10.1021/acs.chemrev.8b00299 Mzukisi, 2017, Status of pharmaceuticals in African water bodies: occurrence , removal and analytical methods, J. Environ. Manag., 193, 211 Ondarza, 2019, Pharmaceuticals, illicit drugs and their metabolites in fish from Argentina: implications for protected areas influenced by urbanization, Sci. Total Environ., 649, 1029, 10.1016/j.scitotenv.2018.08.383 Quesada, 2019, Surface water pollution by pharmaceuticals and an alternative of removal by low-cost adsorbents: a review, Chemosphere, 222, 766, 10.1016/j.chemosphere.2019.02.009 Zilker, 2019, A systematic review of the stability of finished pharmaceutical products and drug substances beyond their labeled expiry dates, J. Pharmaceut. Biomed. Anal., 166, 222, 10.1016/j.jpba.2019.01.016 Majumder, 2019, Pharmaceutically active compounds in aqueous environment : a status , toxicity and insights of remediation, Environ. Res., 176, 108542, 10.1016/j.envres.2019.108542 Akerdi, 2019, Application of heterogeneous nano-semiconductors for photocatalytic advanced oxidation of organic compounds: a review, J. Environ. Chem. Eng., 7, 103283 De Souza, 2018, Nanofiltration for the removal of norfloxacin from pharmaceutical effluent, J. Environ. Chem. Eng., 6, 6147 Jaria, 2020, Effect of the surface functionalization of a waste-derived activated carbon on pharmaceuticals ’ adsorption from water, J. Mol. Liq., 299, 112098, 10.1016/j.molliq.2019.112098 Garcia-ivars, 2017, Nano fi ltration as tertiary treatment method for removing trace pharmaceutically active compounds in wastewater from wastewater treatment plants, Water Res., 125, 360, 10.1016/j.watres.2017.08.070 Kamrani, 2018, Chitosan-modified acrylic nanofiltration membrane for efficient removal of pharmaceutical compounds, J. Environ. Chem. Eng., 6, 583 Bartolomeu, 2018, Wastewater chemical contaminants: remediation by advanced oxidation processes, Photochem. Photobiol. Sci., 17, 1573, 10.1039/C8PP00249E Lou, 2017, Study of a photocatalytic process for removal of antibiotics from wastewater in a falling film photoreactor: scavenger study and process intensification feasibility, Chem. Eng. Process. Process Intensif., 122, 213, 10.1016/j.cep.2017.10.010 Serpone, 2017, Light-driven advanced oxidation processes in the disposal of emerging pharmaceutical contaminants in aqueous media: a brief review, Curr. Opin. Green Sustain. Chem., 6, 18, 10.1016/j.cogsc.2017.05.003 Başaran Dindaş, 2020, Treatment of pharmaceutical wastewater by combination of electrocoagulation, electro-fenton and photocatalytic oxidation processes, J. Environ. Chem. Eng., 8, 103777 Gupta, 2017, Synthesis of CdSe quantum dots decorated SnO2 nanotubes as anode for photo-assisted electrochemical degradation of hydrochlorothiazide: kinetic process, J. Colloid Interface Sci., 508, 575, 10.1016/j.jcis.2017.08.083 Hosseini, 2020, Degradation of ciprofloxacin antibiotic using photo-electrocatalyst process of Ni-doped ZnO deposited by RF sputtering on FTO as an anode electrode from aquatic environments: synthesis , kinetics , and ecotoxicity study, Microchem. J., 154, 104663, 10.1016/j.microc.2020.104663 Akbar, 2020, Sono-photocatalytic degradation of tetracycline and pharmaceutical wastewater using WO 3/CNT heterojunction nanocomposite under US and visible light irradiations: a novel hybrid system, J. Hazard Mater., 390, 122050, 10.1016/j.jhazmat.2020.122050 Dong, 2019, Efficient degradation of pharmaceutical micropollutants in water and wastewater by FeIII-NTA-catalyzed neutral photo-Fenton process, Sci. Total Environ., 688, 513, 10.1016/j.scitotenv.2019.06.315 Nawaz, 2020, Photo-Fenton reaction for the degradation of sulfamethoxazole using a multi-walled carbon nanotube-NiFe 2 O 4 composite, Chem. Eng. J., 382, 123053, 10.1016/j.cej.2019.123053 Liu, 2019, Hierarchical biomimetic BiVO4 for the treatment of pharmaceutical wastewater in visible-light photocatalytic ozonation, Chemosphere, 222, 38, 10.1016/j.chemosphere.2019.01.084 Prieto-Rodriguez, 2012, Treatment of emerging contaminants in wastewater treatment plants (WWTP) effluents by solar photocatalysis using low TiO 2 concentrations, J. Hazard Mater., 211–212, 131, 10.1016/j.jhazmat.2011.09.008 Bagheri, 2017, Photocatalytic pathway toward degradation of environmental pharmaceutical pollutants: structure, kinetics and mechanism approach, Catal. Sci. Technol., 7, 4548, 10.1039/C7CY00468K Sarkar, 2014, Involvement of process parameters and various modes of application of TiO2 nanoparticles in heterogeneous photocatalysis of pharmaceutical wastes - a short review, RSC Adv., 4, 57250, 10.1039/C4RA09582K Varma, 2020, Photocatalytic degradation of pharmaceutical and pesticide compounds (PPCs) using doped TiO2 nanomaterials: a review, Water-Energy Nexus, 3, 46, 10.1016/j.wen.2020.03.008 Gusain, 2019, Adsorptive removal and photocatalytic degradation of organic pollutants using metal oxides and their composites: a comprehensive review, Adv. Colloid Interface Sci., 272, 102009, 10.1016/j.cis.2019.102009 Gautam, 2020, Metal oxides and metal organic frameworks for the photocatalytic degradation: a review, J. Environ. Chem. Eng., 8, 103726 Zhang, 2020, Functionalized metal-organic frameworks for photocatalytic degradation of organic pollutants in environment, Chemosphere, 242, 125144, 10.1016/j.chemosphere.2019.125144 Chen, 2020, Photocatalytic degradation of organic pollutants using TiO2-based photocatalysts: a review, J. Clean. Prod., 268, 121725, 10.1016/j.jclepro.2020.121725 Kanakaraju, 2018, Advanced oxidation process-mediated removal of pharmaceuticals from water: a review, J. Environ. Manag., 219, 189 Sirés, 2012, Remediation of water pollution caused by pharmaceutical residues based on electrochemical separation and degradation technologies: a review, Environ. Int., 40, 212, 10.1016/j.envint.2011.07.012 Wang, 2016, A review on Fenton-like processes for organic wastewater treatment, J. Environ. Chem. Eng., 4, 762 Casado, 2019, Towards industrial implementation of Electro-Fenton and derived technologies for wastewater treatment: a review, J. Environ. Chem. Eng., 7, 102823 Peleyeju, 2018, Recent trend in visible-light photoelectrocatalytic systems for degradation of organic contaminants in water/wastewater, Environ. Sci. Water Res. Technol., 4, 1389, 10.1039/C8EW00276B Li, 2020, 260 Kansal, 2014, Photocatalytic degradation of the antibiotic levofloxacin using highly crystalline TiO2 nanoparticles, New J. Chem., 38, 3220, 10.1039/C3NJ01619F Romeiro, 2017, Effect of the calcination temperature on the photocatalytic efficiency of acidic sol-gel synthesized TiO2 nanoparticles in the degradation of alprazolam, Photochem. Photobiol. Sci., 16, 935, 10.1039/C6PP00447D Chen, 2020, Influence of pH and DO on the ofloxacin degradation in water by UVA-LED/TiO2 nanotube arrays photocatalytic fuel cell: mechanism, ROSs contribution and power generation, J. Hazard Mater., 383, 1, 10.1016/j.jhazmat.2019.121220 Fan, 2019, Photocatalytic degradation of naproxen by a H2O2-modified titanate nanomaterial under visible light irradiation, Catal. Sci. Technol., 9, 4614, 10.1039/C9CY00965E Gao, 2014, A p–type Ti(iv)–based metal–organic framework with visible–light photo–response, Chem. Commun., 50, 3786, 10.1039/C3CC49440C Khadgi, 2017, Simultaneous bacterial inactivation and degradation of an emerging pollutant under visible light by ZnFe2O4 co-modified with Ag and rGO, RSC Adv., 7, 27007, 10.1039/C7RA01782K Li, 2019, Tunable titanium metal-organic frameworks with infinite 1D Ti-O rods for efficient visible-light-driven photocatalytic H2 evolution, J. Mater. Chem. A., 7, 11928, 10.1039/C9TA01942A Shirazi, 2020, La2MnTiO6 double perovskite nanostructures as highly efficient visible light photocatalysts, New J. Chem., 44, 231, 10.1039/C9NJ04932K Haque, 2018, Two-dimensional transition metal oxide and chalcogenide-based photocatalysts, Nano-Micro Lett., 10, 1, 10.1007/s40820-017-0176-y Shen, 2018, One-step hydrothermal synthesis of peony-like Ag/Bi2WO6 as efficient visible light-driven photocatalyst toward organic pollutants degradation, J. Mater. Sci., 53, 4848, 10.1007/s10853-017-1885-9 Malekshahi Byranvand, 2013, A review on synthesis of nano-TiO2 via different methods, J. Nanostructures., 3, 1 Wu, 2020, Preparation of Bi-based photocatalysts in the form of powdered particles and thin films: a review, J. Mater. Chem., 15302, 10.1039/D0TA01180K Grabowska, 2018 D. Pathania, R. Katwal, P. Thakur, Ceramic Materials: General Introduction , Properties , and Fabrication Methods, (n.d). S. Adhikari, K. Mishra, D. Sarkar, Ceramic-Based Nanomaterials for Multifunctional Application, (n.d). Zhu, 2017, Construction of WO3-g-C3N4 composites as efficient photocatalysts for pharmaceutical degradation under visible light, Catal. Sci. Technol., 7, 2591, 10.1039/C7CY00529F Fabbri, 2019, Photocatalytic abatement of emerging pollutants in pure water and wastewater effluent by TiO2 and Ce-ZnO: degradation kinetics and assessment of transformation products, Photochem. Photobiol. Sci., 18, 845, 10.1039/C8PP00311D 2019, 1 Stankic, 2016, Pure and multi metal oxide nanoparticles: synthesis, antibacterial and cytotoxic properties, J. Nanobiotechnol., 14, 1 Meng, 2016, The progress of microwave-assisted hydrothermal method in the synthesis of functional nanomaterials, Mater. Today Chem., 1–2, 63, 10.1016/j.mtchem.2016.11.003 Samsudin, 2020, Hybrid 2D/3D g-C3N4/BiVO4 photocatalyst decorated with RGO for boosted photoelectrocatalytic hydrogen production from natural lake water and photocatalytic degradation of antibiotics, J. Mol. Liq., 314, 10.1016/j.molliq.2020.113530 Reddy, 2020, Z-scheme binary 1D ZnWO4 nanorods decorated 2D NiFe2O4 nanoplates as photocatalysts for high efficiency photocatalytic degradation of toxic organic pollutants from wastewater, J. Environ. Manag., 268, 110677 Hayati, 2020, Ultrasound-assisted photocatalytic degradation of sulfadiazine using MgO@CNT heterojunction composite: effective factors, pathway and biodegradability studies, Chem. Eng. J., 381, 122636, 10.1016/j.cej.2019.122636 Jamali, 2020, Effect of synthesis route on the structural and morphological properties of WO3 nanostructures, Mater. Sci. Semicond. Process., 107, 104829, 10.1016/j.mssp.2019.104829 Yilmaz, 2020, TiO2 nanoparticles and C-Nanofibers modified magnetic Fe3O4 nanospheres (TiO2@Fe3O4@C–NF): a multifunctional hybrid material for magnetic solid-phase extraction of ibuprofen and photocatalytic degradation of drug molecules and azo dye, Talanta, 213, 120813, 10.1016/j.talanta.2020.120813 Lwin, 2019, Visible-light photocatalytic degradation pathway of tetracycline hydrochloride with cubic structured ZnO/SnO2 heterojunction nanocatalyst, Chem. Phys. Lett., 736, 136806, 10.1016/j.cplett.2019.136806 Rohani Bastami, 2017, Synthesis of Fe3O4/Bi2WO6 nanohybrid for the photocatalytic degradation of pharmaceutical ibuprofen under solar light, J. Ind. Eng. Chem., 51, 244, 10.1016/j.jiec.2017.03.008 Bilgin Simsek, 2017, Solvothermal synthesized boron doped TiO2 catalysts: photocatalytic degradation of endocrine disrupting compounds and pharmaceuticals under visible light irradiation, Appl. Catal. B Environ., 200, 309, 10.1016/j.apcatb.2016.07.016 Golubović, 2014, Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam, Ceram. Int., 40, 13409, 10.1016/j.ceramint.2014.05.060 Shafei, 2019, Visible light photocatalytic activity of Cu doped TiO2-CNT nanocomposite powder prepared by sol–gel method, Mater. Res. Bull., 110, 198, 10.1016/j.materresbull.2018.10.035 Boxi, 2015, Visible light induced enhanced photocatalytic degradation of organic pollutants in aqueous media using Ag doped hollow TiO2 nanospheres, RSC Adv., 5, 37647, 10.1039/C5RA03421C Wei, 2018, Visible light photocatalytic mineralization of 17α-ethinyl estradiol (EE2) and hydrogen evolution over silver and strontium modified TiO2 nanoparticles: mechanisms and phytotoxicity assessment, RSC Adv., 8, 4329, 10.1039/C7RA12638G Parashar, 2020, Metal oxides nanoparticles via sol–gel method: a review on synthesis, characterization and applications, J. Mater. Sci. Mater. Electron., 31, 3729, 10.1007/s10854-020-02994-8 Itteboina, 2019, Sol-gel synthesis and characterizations of morphology-controlled Co 3 O 4 particles, Mater. Today Proc., 9, 458, 10.1016/j.matpr.2019.02.176 Li, 2020, HZSM-5 zeolite supported boron-doped TiO2 for photocatalytic degradation of ofloxacin, J. Mater. Res. Technol., 9, 2557, 10.1016/j.jmrt.2019.12.086 Rueda-Márquez, 2020, Photocatalytic degradation of pharmaceutically active compounds (PhACs) in urban wastewater treatment plants effluents under controlled and natural solar irradiation using immobilized TiO2, Sol. Energy, 208, 480, 10.1016/j.solener.2020.08.028 Zhao, 2017, Photocatalytic performances of ZnO nanoparticle film and vertically aligned nanorods in chamber-based microfluidic reactors: reaction kinetics and flow effects, Appl. Catal. B Environ., 209, 468, 10.1016/j.apcatb.2017.03.020 Parthibavarman, 2018, Facile and one step synthesis of WO3 nanorods and nanosheets as an efficient photocatalyst and humidity sensing material, Vacuum, 155, 224, 10.1016/j.vacuum.2018.06.021 Kadam, 2017, Sunlight driven high photocatalytic activity of Sn doped N-TiO2 nanoparticles synthesized by a microwave assisted method, Ceram. Int., 43, 5164, 10.1016/j.ceramint.2017.01.039 Kubiak, 2020, Microwave-assisted synthesis of a TiO2-CuO heterojunction with enhanced photocatalytic activity against tetracycline, Appl. Surf. Sci., 520, 146344, 10.1016/j.apsusc.2020.146344 Nikam, 2018, Wet chemical synthesis of metal oxide nanoparticles: a review, CrystEngComm, 20, 5091, 10.1039/C8CE00487K Hangxun, 2013, Sonochemical synthesis of nanomaterials, Chem. Soc. Rev., 42, 2555, 10.1039/C2CS35282F Ramasamy Raja, 2019, Sonochemical synthesis of novel ZnFe 2 O 4/CeO 2 heterojunction with highly enhanced visible light photocatalytic activity, Solid State Ionics, 332, 55, 10.1016/j.ssi.2018.12.016 Mousavi-Kamazani, 2020, Single-step sonochemical synthesis of Cu2O-CeO2 nanocomposites with enhanced photocatalytic oxidative desulfurization, Ultrason. Sonochem., 63, 10.1016/j.ultsonch.2019.104948 Bhattacharyya, 2008, A template-free, sonochemical route to porous ZnO nano-disks, Microporous Mesoporous Mater., 110, 553, 10.1016/j.micromeso.2007.06.053 Han, 2020, Sonochemical synthesis of hierarchical WO3 flower-like spheres for highly efficient triethylamine detection, Sensor. Actuator. B Chem., 306, 127536, 10.1016/j.snb.2019.127536 Teh, 2017, An application of ultrasound technology in synthesis of titania-based photocatalyst for degrading pollutant, Chem. Eng. J., 317, 586, 10.1016/j.cej.2017.01.001 Periyasamy, 2020, Modulating the properties of SnO2 nanocrystals: morphological effects on structural, photoluminescence, photocatalytic, electrochemical and gas sensing properties, J. Mater. Chem. C., 8, 4604, 10.1039/C9TC06469A Subhan, 2015, Structure and photoluminescence studies of CeO2· CuAlO2 mixed metal oxide fabricated by co-precipitation method, Spectrochim. Acta Part A Mol. Biomol. Spectrosc., 135, 466, 10.1016/j.saa.2014.07.030 Sharma, 2016, Synthesis of Co3O4-ZnO mixed metal oxide nanoparticles by homogeneous precipitation method, J. Alloys Compd., 686, 64, 10.1016/j.jallcom.2016.05.298 Mohamed, 2018, Synthesis, characterization and photocatalysis enhancement of Eu2O3-ZnO mixed oxide nanoparticles, J. Phys. Chem. Solid., 116, 375, 10.1016/j.jpcs.2018.02.008 Abu-Dief, 2021, Facile synthesis and characterization of novel Gd2O3–CdO binary mixed oxide nanocomposites of highly photocatalytic activity for wastewater remediation under solar illumination, J. Phys. Chem. Solid., 148, 109666, 10.1016/j.jpcs.2020.109666 Sharma, 2016, Synthesis of nanocrystalline ZnO-NiO mixed metal oxide powder by homogeneous precipitation method, Ceram. Int., 42, 4090, 10.1016/j.ceramint.2015.11.081 Sharma, 2014, Synthesis of nanocrystalline CuO-ZnO mixed metal oxide powder by a homogeneous precipitation method, Ceram. Int., 40, 10919, 10.1016/j.ceramint.2014.03.089 Guo, 2020, Investigation of visible-light-driven photocatalytic tetracycline degradation via carbon dots modified porous ZnSnO3 cubes: mechanism and degradation pathway, Separ. Purif. Technol., 253, 117518, 10.1016/j.seppur.2020.117518 Xia, 2014, Solution synthesis of metal oxides for electrochemical energy storage applications, Nanoscale, 6, 5008, 10.1039/C4NR00024B Zhang, 2020, Stimuli-responsive microemulsions: state-of-the-art and future prospects, Curr. Opin. Colloid Interface Sci., 49, 27, 10.1016/j.cocis.2020.04.008 Akbari, 2020, Microemulsion based synthesis of promoted Fe–Co/MgO nanocatalyst: influence of calcination atmosphere on the physicochemical properties, activity and light olefins selectivity for hydrogenation of carbon monoxide, Mater. Chem. Phys., 249, 123003, 10.1016/j.matchemphys.2020.123003 Hadi, 2015, Effect of metals oxides loading on the modification of microstructure and phase transformation of nanocrystalline CeZrO2 synthesized using water-in-oil-microemulsion, Procedia - Soc. Behav. Sci., 195, 2051, 10.1016/j.sbspro.2015.06.227 Kaur, 2018, DNA interaction, anti-proliferative effect of copper oxide nanocolloids prepared from metallosurfactant based microemulsions acting as precursor, template and reducing agent, Int. J. Pharm., 535, 95, 10.1016/j.ijpharm.2017.10.059 Cao, 2020, Microemulsion synthesis of ms/tz-BiVO4 composites: the effect of pH on crystal structure and photocatalytic performance, Ceram. Int., 46, 20788, 10.1016/j.ceramint.2020.05.048 Chen, 2019, Facile microemulsion synthesis of mesoporous ZnMn2O4 submicrocubes as high-rate and long-life anodes for lithium ion batteries, Ceram. Int., 45, 5594, 10.1016/j.ceramint.2018.12.019 Sanchez-Dominguez, 2015, Synthesis of Zn-doped TiO2 nanoparticles by the novel oil-in-water (O/W) microemulsion method and their use for the photocatalytic degradation of phenol, J. Environ. Chem. Eng., 3, 3037 Bai, 2013, The microemulsion preparation and high catalytic performance of mesoporous NiO nanorods and nanocubes for toluene combustion, Chem. Eng. J., 219, 200, 10.1016/j.cej.2013.01.008 Abazari, 2014, Characterization and optical properties of spherical WO3 nanoparticles synthesized via the reverse microemulsion process and their photocatalytic behavior, Mater. Lett., 133, 208, 10.1016/j.matlet.2014.07.032 Wang, 2017, Expeditious synthesis of SnO2 nanoparticles through controlled hydrolysis and condensation of Tin alkoxide in reverse microemulsion, Ceram. Int., 43, 4702, 10.1016/j.ceramint.2017.01.002 Foroughi, 2016, In situ microemulsion synthesis of hydroxyapatite-MgFe2O4 nanocomposite as a magnetic drug delivery system, Mater. Sci. Eng. C, 68, 774, 10.1016/j.msec.2016.07.028 Fan, 2020, Visible-light-driven photocatalytic degradation of naproxen by Bi-modified titanate nanobulks: synthesis, degradation pathway and mechanism, J. Photochem. Photobiol. Chem., 386, 112108, 10.1016/j.jphotochem.2019.112108 Abbas, 2015, A novel approach for the synthesis of ultrathin silica-coated iron oxide nanocubes decorated with silver nanodots (Fe3O4/SiO2/Ag) and their superior catalytic reduction of 4-nitroaniline, Nanoscale, 7, 12192, 10.1039/C5NR02680F Mulinari, 2013, Microwave-hydrothermal synthesis of single-crystalline Co3O 4 spinel nanocubes, CrystEngComm, 15, 7443, 10.1039/c3ce41215f Das, 2014, Microwave assisted hydrothermal synthesis of well-dispersed and thermally stable Ag@SnO2 core-shell nanocomposites for propane sensing applications, J. Mater. Sci. Mater. Electron., 25, 217, 10.1007/s10854-013-1575-6 Hendekhale, 2020, A novel synthesis of Co2ZrO5 and m-ZrO2 nanoparticles by sono-precipitation and hydrothermal methods and their application in UV/Visible-photocatalytic studies, J. Environ. Chem. Eng., 8, 104065 Wang, 2020, High-performance spherical urchin-like CoAl2O4 pigments prepared via microemulsion-hydrothermal-precipitation method, Adv. Powder Technol., 31, 1290, 10.1016/j.apt.2019.12.041 Park, 2014, A facile exfoliation-crystal growth route to multicomponent Ag 2CO3/Ag-Ti5NbO14 nanohybrids with improved visible light photocatalytic activity, Dalton Trans., 43, 10566, 10.1039/C4DT00018H Pastrana-Martínez, 2018, Photocatalytic activity of functionalized nanodiamond-TiO 2 composites towards water pollutants degradation under UV/Vis irradiation, Appl. Surf. Sci., 458, 839, 10.1016/j.apsusc.2018.07.102 Zhu, 2020, A self-assembled urchin-like TiO 2 @Ag–CuO with enhanced photocatalytic activity toward tetracycline hydrochloride degradation, New J. Chem., 11076, 10.1039/D0NJ02153A Mou, 2019, A one-step deep eutectic solvent assisted synthesis of carbon nitride/metal oxide composites for photocatalytic nitrogen fixation, J. Mater. Chem. A., 7, 5719, 10.1039/C8TA11681D Salimi, 2019, A new nano-photocatalyst based on Pt and Bi co-doped TiO 2 for efficient visible-light photo degradation of amoxicillin, New J. Chem., 43, 1562, 10.1039/C8NJ05020A Fan, 2018, Degradation of acetaminophen in aqueous solution under visible light irradiation by Bi-modified titanate nanomaterials: morphology effect, kinetics and mechanism, Catal. Sci. Technol., 8, 5906, 10.1039/C8CY01614C Chen, 2012, Efficient degradation of an antibiotic norfloxacin in aqueous solution via a simulated solar-light-mediated Bi 2WO 6 process, Ind. Eng. Chem. Res., 51, 4887, 10.1021/ie300146h Song, 2020, Highly flexible, core-shell heterostructured, and visible-light-driven titania-based nanofibrous membranes for antibiotic removal and E. coil inactivation, Chem. Eng. J., 379, 122269, 10.1016/j.cej.2019.122269 Babić, 2017, TiO2 assisted photocatalytic degradation of macrolide antibiotics, Curr. Opin. Green Sustain. Chem., 6, 34, 10.1016/j.cogsc.2017.05.004 Yan, 2020, From isolated Ti-oxo clusters to infinite Ti-oxo chains and sheets: recent advances in photoactive Ti-based MOFs, J. Mater. Chem., 15245, 10.1039/D0TA03749D Haroune, 2014, Photocatalytic degradation of carbamazepine and three derivatives using TiO2 and ZnO: effect of pH, ionic strength, and natural organic matter, Sci. Total Environ., 475, 16, 10.1016/j.scitotenv.2013.12.104 Calza, 2006, Photocatalytic degradation study of diclofenac over aqueous TiO2 suspensions, Appl. Catal. B Environ., 67, 197, 10.1016/j.apcatb.2006.04.021 Arlos, 2017, Influence of methanol when used as a water-miscible carrier of pharmaceuticals in TiO2 photocatalytic degradation experiments, J. Environ. Chem. Eng., 5, 4497 Lambropoulou, 2017, Degradation of venlafaxine using TiO 2/UV process : kinetic studies , RSM optimization , identification of transformation products and toxicity evaluation, J. Hazard Mater., 323, 513, 10.1016/j.jhazmat.2016.04.074 Szabó-Bárdos, 2020, Photolytic and photocatalytic degradation of nitrofurantoin and its photohydrolytic products, J. Photochem. Photobiol. Chem., 386, 112093, 10.1016/j.jphotochem.2019.112093 Teixeira, 2016, Photocatalytic degradation of pharmaceuticals present in conventional treated wastewater by nanoparticle suspensions, J. Environ. Chem. Eng., 4, 287 Riente, 2019, Application of metal oxide semiconductors in light-driven organic transformations, Catal. Sci. Technol., 9, 5186, 10.1039/C9CY01170F Luttrell, 2015, Why is anatase a better photocatalyst than rutile? - model studies on epitaxial TiO2 films, Sci. Rep., 4, 1, 10.1038/srep04043 Zhang, 2014, New understanding of the difference of photocatalytic activity among anatase, rutile and brookite TiO2, Phys. Chem. Chem. Phys., 16, 20382, 10.1039/C4CP02201G Lin, 2017, Comparison study on photocatalytic oxidation of pharmaceuticals by TiO2-Fe and TiO2-reduced graphene oxide nanocomposites immobilized on optical fibers, J. Hazard Mater., 333, 162, 10.1016/j.jhazmat.2017.02.044 Silva, 2016, Ciprofloxacin wastewater treated by UVA photocatalysis: contribution of irradiated TiO2 and ZnO nanoparticles on the final toxicity as assessed by Vibrio fischeri, RSC Adv., 6, 95494, 10.1039/C6RA19202E Jyotsna, 2020, β-AgVO3 nanowires/TiO2 nanoparticles heterojunction assembly with improved visible light driven photocatalytic decomposition of hazardous pollutants and mechanism insight, Separ. Purif. Technol., 251, 117271, 10.1016/j.seppur.2020.117271 Balachandran, 2020, Photocatalytic decomposition of A549-lung cancer cancer cells by TiO2 nanoparticles, Mater, Today Proc, 2 Sayed, 2016, VUV-photocatalytic degradation of bezafibrate by hydrothermally synthesized enhanced {001} facets TiO2/Ti film, J. Phys. Chem., 120, 118, 10.1021/acs.jpca.5b10502 Xu, 2016, Photocatalytic degradation of a low concentration pharmaceutical pollutant by nanoporous TiO2 film with exposed {001} facets, RSC Adv., 6, 95818, 10.1039/C6RA22011H Shahzad, 2018, Heterostructural TiO2/Ti3C2Tx (MXene) for photocatalytic degradation of antiepileptic drug carbamazepine, Chem. Eng. J., 349, 748, 10.1016/j.cej.2018.05.148 Yao, 2020, Simultaneous photocatalytic degradation of ibuprofen and H2 evolution over Au/sheaf-like TiO2 mesocrystals, Chemosphere, 261, 127759, 10.1016/j.chemosphere.2020.127759 Boxi, 2014, Effect of silver doping on TiO2, CdS, and ZnS nanoparticles for the photocatalytic degradation of metronidazole under visible light, RSC Adv., 4, 37752, 10.1039/C4RA06192F Eswar, 2016, Novel synergistic photocatalytic degradation of antibiotics and bacteria using V-N doped TiO2 under visible light: the state of nitrogen in V-doped TiO2, New J. Chem., 40, 3464, 10.1039/C5NJ02861B Aba-guevara, 2017, Comparison of two synthesis methods on the preparation of Fe , N-Co-doped TiO 2 materials for degradation of pharmaceutical compounds under visible light, Ceram. Int., 43, 5068, 10.1016/j.ceramint.2017.01.018 Barrocas, 2019, Ruthenium-modified titanate nanowires for the photocatalytic oxidative removal of organic pollutants from water, ACS Appl. Nano Mater., 2, 1341, 10.1021/acsanm.8b02215 Jahdi, 2020, Smart pathways for the photocatalytic degradation of sulfamethoxazole drug using F-Pd co-doped TiO2 nanocomposites, Appl. Catal. B Environ., 267, 118716, 10.1016/j.apcatb.2020.118716 Kitsiou, 2018, Mineralization of the antineoplastic drug carboplatin by heterogeneous photocatalysis with simultaneous synthesis of platinum-modified TiO2 catalysts, J. Environ. Chem. Eng., 6, 2409 Mishra, 2019, 916 Farhadian, 2019, Chitosan modified N, S-doped TiO 2 and N, S-doped ZnO for visible light photocatalytic degradation of tetracycline, Int. J. Biol. Macromol., 132, 360, 10.1016/j.ijbiomac.2019.03.217 Lei, 2019, An inverse opal TiO 2/g-C 3 N 4 composite with a heterojunction for enhanced visible light-driven photocatalytic activity, Dalton Trans., 48, 3486, 10.1039/C8DT04496A Sacco, 2020, Pt–TiO2–Nb2O5 heterojunction as effective photocatalyst for the degradation of diclofenac and ketoprofen, Mater. Sci. Semicond. Process., 107, 10.1016/j.mssp.2019.104839 Yin, 2020, Construction of carbon bridged TiO2/CdS tandem Z-scheme heterojunctions toward efficient photocatalytic antibiotic degradation and Cr (VI) reduction, J. Alloys Compd., 824, 153915, 10.1016/j.jallcom.2020.153915 Wang, 2020, 0D/2D Co3O4/TiO2 Z-Scheme heterojunction for boosted photocatalytic degradation and mechanism investigation, Appl. Catal. B Environ., 278, 10.1016/j.apcatb.2020.119298 Rashid, 2019, Butterfly cluster like lamellar BiOBr/TiO 2 nanocomposite for enhanced sunlight photocatalytic mineralization of aqueous ciprofloxacin, Sci. Total Environ., 665, 668, 10.1016/j.scitotenv.2019.02.145 Gurung, 2019, Removal of pharmaceutically active compounds (PhACs) from real membrane bioreactor (MBR) effluents by photocatalytic degradation using composite Ag2O/P-25 photocatalyst, Separ. Purif. Technol., 215, 317, 10.1016/j.seppur.2018.12.069 Chen, 2020, TiO2 nanosheet/NiO nanorod hierarchical nanostructures: p–n heterojunctions towards efficient photocatalysis, J. Colloid Interface Sci., 562, 313, 10.1016/j.jcis.2019.12.031 Abdel-Wahab, 2017, Photocatalytic degradation of paracetamol over magnetic flower-like TiO2/Fe2O3 core-shell nanostructures, J. Photochem. Photobiol. Chem., 347, 186, 10.1016/j.jphotochem.2017.07.030 Zaccariello, 2014, TiO2-mesoporous silica nanocomposites: cooperative effect in the photocatalytic degradation of dyes and drugs, RSC Adv., 4, 37826, 10.1039/C4RA06767C Kumar, 2019, Electrochemical detection and photocatalytic performance of MoS2/TiO2 nanocomposite against pharmaceutical contaminant: Paracetamol, Sens. Bio-Sensing Res., 24, 2 Mugunthan, 2018, Visible light assisted photocatalytic degradation of diclofenac using TiO2-WO3 mixed oxide catalysts, Environ. Nanotechnol., Monit. Manag., 10, 322 Chen, 2020, Perovskite LaNiO3/TiO2 step-scheme heterojunction with enhanced photocatalytic activity, Appl. Surf. Sci., 503, 10.1016/j.apsusc.2019.144287 Hu, 2020, Facile synthesis of Z-scheme composite of TiO2 nanorod/g-C3N4 nanosheet efficient for photocatalytic degradation of ciprofloxacin, J. Clean. Prod., 253, 10.1016/j.jclepro.2020.120055 Mu, 2020, Synthesis of novel ternary heterogeneous anatase-TiO 2 ( B ) biphase nanowires/Bi 4 O 5 I 2 composite photocatalysts for the highly e ffi cient degradation of acetaminophen under visible light irradiation, J. Hazard Mater., 382, 121083, 10.1016/j.jhazmat.2019.121083 Odling, 2018, Bismuth titanate modified and immobilized TiO2 photocatalysts for water purification: broad pollutant scope, ease of re-use and mechanistic studies, Environ. Sci. Water Res. Technol., 4, 2170, 10.1039/C8EW00568K Sharma, 2020, LaTiO2N/Bi2S3 Z-scheme nano heterostructures modified by rGO with high interfacial contact for rapid photocatalytic degradation of tetracycline, J. Mol. Liq., 311, 113300, 10.1016/j.molliq.2020.113300 Gao, 2020, 3D heterogeneous CTF@TiO 2/Bi 2 WO 6/Au hybrid supported by hollow carbon tubes and its efficient photocatalytic performance in the UV-vis range, Environ. Sci. Nano., 2061, 10.1039/D0EN00307G Khan, 2019, Unravelling mechanistic reasons for differences in performance of different Ti- and Bi-based magnetic photocatalysts in photocatalytic degradation of PPCPs, Sci. Total Environ., 686, 878, 10.1016/j.scitotenv.2019.05.340 Jo, 2015, Facile synthesis of novel redox-mediator-free direct Z-scheme CaIn2S4 marigold-flower-like/TiO2 photocatalysts with superior photocatalytic efficiency, ACS Appl. Mater. Interfaces, 7, 17138, 10.1021/acsami.5b03935 Sharma, 2020, Effect of Ce on piezo/photocatalytic effects of Ba0.9Ca0.1CexTi1-xO3 ceramics for dye/pharmaceutical waste water treatment, Mater. Res. Bull., 122, 1, 10.1016/j.materresbull.2019.110647 Kushwaha, 2015, Visible light-induced photocatalytic and antibacterial activity of Li-doped Bi0.5Na0.45K0.5TiO3–BaTiO3 ferroelectric ceramics, J. Electron. Mater., 44, 4334, 10.1007/s11664-015-4007-y Thakur, 2015, A study on the structural and photocatalytic degradation of ciprofloxacine using (70B2O3-29Bi2O3-1Dy2O3)-x(BaO-TiO2) glass ceramics, J. Non-Cryst. Solids, 428, 197, 10.1016/j.jnoncrysol.2015.08.009 Diaz-Angulo, 2019, Visible-light activation of TiO2 by dye-sensitization for degradation of pharmaceutical compounds, Photochem. Photobiol. Sci., 18, 897, 10.1039/C8PP00270C Diaz-angulo, 2020, Enhancement of the oxidative removal of diclofenac and of the TiO 2 rate of photon absorption in dye-sensitized solar pilot scale CPC photocatalytic reactors, Chem. Eng. J., 381, 122520, 10.1016/j.cej.2019.122520 Hashim, 2014, Intrinsic kinetic study for photocatalytic degradation of diclofenac under UV and visible light, Ind. Eng. Chem. Res., 53, 18637, 10.1021/ie404355k Basha, 2011, On the adsorption/photodegradation of amoxicillin in aqueous solutions by an integrated photocatalytic adsorbent (IPCA): experimental studies and kinetics analysis, Photochem. Photobiol. Sci., 10, 1014, 10.1039/c0pp00368a Ahmadi, 2017, Enhanced photocatalytic degradation of tetracycline and real pharmaceutical wastewater using MWCNT/TiO2 nano-composite, J. Environ. Manag., 186, 55 Awfa, 2019, Novel magnetic carbon nanotube-TiO 2 composites for solar light photocatalytic degradation of pharmaceuticals in the presence of natural organic matter, J. Water Process Eng., 31, 100836, 10.1016/j.jwpe.2019.100836 Uheida, 2019, Photocatalytic degradation of Ibuprofen, Naproxen, and Cetirizine using PAN-MWCNT nanofibers crosslinked TiO2-NH2 nanoparticles under visible light irradiation, Separ. Purif. Technol., 212, 110, 10.1016/j.seppur.2018.11.030 Sun, 2020, Hydrothermally synthesis of MWCNT/N-TiO2/UiO-66-NH2 ternary composite with enhanced photocatalytic performance for ketoprofen, Inorg. Chem. Commun., 111, 107669, 10.1016/j.inoche.2019.107669 Evgenidou, 2020, New insights into transformation pathways of a mixture of cytostatic drugs using Polyester-TiO2 films: identification of intermediates and toxicity assessment, Sci. Total Environ., 741, 10.1016/j.scitotenv.2020.140394 Sayed, 2018, Solar light responsive poly(vinyl alcohol)-assisted hydrothermal synthesis of immobilized TiO2/Ti film with the addition of peroxymonosulfate for photocatalytic degradation of ciprofloxacin in aqueous media: a mechanistic approach, J. Phys. Chem. C, 122, 406, 10.1021/acs.jpcc.7b09169 Monteagudo, 2020, Effect of reduced graphene oxide load into TiO 2 P25 on the generation of reactive oxygen species in a solar photocatalytic reactor . Application to antipyrine degradation, Chem. Eng. J., 380, 122410, 10.1016/j.cej.2019.122410 Wang, 2019, Enhanced photocatalytic degradation performance of organic contaminants by heterojunction photocatalyst BiVO 4/TiO 2/RGO and its compatibility on four different tetracycline antibiotics, Adv. Powder Technol., 30, 1882, 10.1016/j.apt.2019.06.006 Chávez, 2020, Magnetic graphene TiO2-based photocatalyst for the removal of pollutants of emerging concern in water by simulated sunlight aided photocatalytic ozonation, Appl. Catal. B Environ., 262, 118275, 10.1016/j.apcatb.2019.118275 Wang, 2020, Robust superhydrophobic mesh coated by PANI/TiO2 nanoclusters for oil/water separation with high flux, self-cleaning, photodegradation and anti-corrosion, Separ. Purif. Technol., 235, 116166, 10.1016/j.seppur.2019.116166 Khalil, 2019, Surface modified of polyacrylonitrile nanofibers by TiO2/MWCNT for photodegradation of organic dyes and pharmaceutical drugs under visible light irradiation, Environ. Res., 179, 108788, 10.1016/j.envres.2019.108788 Awfa, 2018, Photodegradation of pharmaceuticals and personal care products in water treatment using carbonaceous-TiO 2 composites : a critical review of recent literature, Water Res., 142, 26, 10.1016/j.watres.2018.05.036 Kusiak-Nejman, 2019, TiO2/graphene-based nanocomposites for water treatment: a brief overview of charge carrier transfer, antimicrobial and photocatalytic performance, Appl. Catal. B Environ., 253, 179, 10.1016/j.apcatb.2019.04.055 Jung, 2015, Removal of endocrine disrupting compounds, pharmaceuticals, and personal care products in water using carbon nanotubes: a review, J. Ind. Eng. Chem., 27, 1, 10.1016/j.jiec.2014.12.035 Matos, 2017, Development of TiO 2 -C photocatalysts for solar treatment of polluted water, Carbon N. Y., 122, 361, 10.1016/j.carbon.2017.06.091 Bergamonti, 2019, 3D printed chitosan scaffolds: a new TiO2 support for the photocatalytic degradation of amoxicillin in water, Water Res., 163, 114841, 10.1016/j.watres.2019.07.008 Shinde, 2018, Decoration of Pt on the metal free RGO-TiO2 composite photocatalyst for the enhanced photocatalytic hydrogen evolution and photocatalytic degradation of pharmaceutical pollutant Β blocker, Int. J. Hydrogen Energy, 43, 4015, 10.1016/j.ijhydene.2017.10.089 Hassani, 2016, Heterogeneous photocatalytic ozonation of ciprofloxacin using synthesized titanium dioxide nanoparticles on a montmorillonite support: parametric studies, mechanistic analysis and intermediates identification, RSC Adv., 6, 87569, 10.1039/C6RA19191F Hassani, 2017, Degradation of mixture of three pharmaceuticals by photocatalytic ozonation in the presence of TiO2/montmorillonite nanocomposite: simultaneous determination and intermediates identification, J. Environ. Chem. Eng., 5, 1964 Pronina, 2015, Titanium dioxide sol–gel-coated expanded clay granules for use in photocatalytic fluidized-bed reactor, Appl. Catal. B Environ., 178, 117, 10.1016/j.apcatb.2014.10.006 Nomura, 2020, Thermodynamics of removing crotamiton and its transformation byproducts from water by a rotating advanced oxidation contactor with zeolite/TiO 2 composite sheets, Chem. Eng. J., 380, 122479, 10.1016/j.cej.2019.122479 Fischer, 2015, Photocatalytic degradation and toxicity evaluation of diclofenac by nanotubular titanium dioxide-PES membrane in a static and continuous setup, RSC Adv., 5, 16340, 10.1039/C4RA16219F Dixit, 2016, Assessment of solar photocatalytic degradation and mineralization of amoxicillin trihydrate (AMT) using slurry and fixed-bed batch reactor: efficacy of parabolic trough collector, RSC Adv., 6, 36109, 10.1039/C6RA03414D Kumar, 2017, N-doped ZnO-MoS2 binary heterojunctions: the dual role of 2D MoS2 in the enhancement of photostability and photocatalytic activity under visible light irradiation for tetracycline degradation, Mater. Chem. Front., 1, 1093, 10.1039/C6QM00274A Elhalil, 2018, Synthesis, characterization and efficient photocatalytic activity of novel Ca/ZnO-Al2O3 nanomaterial, Mater. Today Commun, 16, 194, 10.1016/j.mtcomm.2018.06.005 Elhalil, 2018, Photocatalytic degradation of caffeine as a model pharmaceutical pollutant on Mg doped ZnO-Al2O3 heterostructure, Environ. Nanotechnology, Monit. Manag., 10, 63, 10.1016/j.enmm.2018.02.002 Xue, 2015, Synthesis of Ag/ZnO/C plasmonic photocatalyst with enhanced adsorption capacity and photocatalytic activity to antibiotics, RSC Adv., 5, 18832, 10.1039/C5RA00217F Mohammed, 2020, Green ZnO nanorod material for dye degradation and detoxification of pharmaceutical wastes in water, J. Environ. Chem. Eng., 8, 104295 Ivetić, 2014, Effect of annealing temperature on structural and optical properties of Mg-doped ZnO nanoparticles and their photocatalytic efficiency in alprazolam degradation, Ceram. Int., 40, 1545, 10.1016/j.ceramint.2013.07.041 Abazari, 2018, Amine-functionalized Al-mof#@ yxSm2O3-ZnO: a visible light-driven nanocomposite with excellent photocatalytic activity for the photo-degradation of amoxicillin, Inorg. Chem., 57, 2529, 10.1021/acs.inorgchem.7b02880 Mugunthan, 2019, Photocatalytic activity of ZnO-WO3 for diclofenac degradation under visible light irradiation, J. Photochem. Photobiol. Chem., 383, 111993, 10.1016/j.jphotochem.2019.111993 Cheshme Khavar, 2019, Novel magnetic Fe3O4@rGO@ZnO onion-like microspheres decorated with Ag nanoparticles for the efficient photocatalytic oxidation of metformin: toxicity evaluation and insights into the mechanisms, Catal. Sci. Technol., 9, 5819, 10.1039/C9CY01381D Hernández, 2019, Hollow ZnO microspheres functionalized with electrochemical graphene oxide for the photodegradation of salicylic acid, RSC Adv., 9, 6965, 10.1039/C8RA10113B An, 2015, Photocatalytic degradation of three amantadine antiviral drugs as well as their eco-toxicity evolution, Catal. Today, 258, 602, 10.1016/j.cattod.2015.01.004 Wang, 2015, Photocatalytic degradation of the antiviral drug Tamiflu by UV-A/TiO2: kinetics and mechanisms, Chemosphere, 131, 41, 10.1016/j.chemosphere.2015.02.032 Woche, 2016, Degradation of the antiviral drug zanamivir in wastewater - the potential of a photocatalytic treatment process, Chem. Eng. J., 287, 674, 10.1016/j.cej.2015.11.047 Roselló-Márquez, 2020, Influence of annealing conditions on the photoelectrocatalytic performance of WO3 nanostructures, Separ. Purif. Technol., 238, 116417, 10.1016/j.seppur.2019.116417 Rong, 2021, Synthesis of hierarchical hollow nest-like WO3 micro/nanostructures with enhanced visible light-driven photocatalytic activity, J. Alloys Compd., 850, 156742, 10.1016/j.jallcom.2020.156742 Dadigala, 2019, Construction of in situ self-assembled FeWO4/g-C3N4 nanosheet heterostructured Z-scheme photocatalysts for enhanced photocatalytic degradation of rhodamine B and tetracycline, Nanoscale Adv, 1, 322, 10.1039/C8NA00041G Devi, 2019, Fabrication of nanostructured NiO/WO3 with graphitic carbon nitride for visible light driven photocatalytic hydroxylation of benzene and metronidazole degradation, New J. Chem., 43, 14616, 10.1039/C9NJ02904D Maavia, 2019, Facile synthesis of g-C3N4/CdWO4 with excellent photocatalytic performance for the degradation of Minocycline, Mater. Sci. Energy Technol., 2, 258 Pan, 2020, Anionic polyacrylamide-assisted construction of thin 2D-2D WO3/g-C3N4 Step-scheme heterojunction for enhanced tetracycline degradation under visible light irradiation, J. Hazard Mater., 393, 122366, 10.1016/j.jhazmat.2020.122366 Zhu, 2017, Fabrication and photocatalytic activity enhanced mechanism of direct Z-scheme g-C 3 N 4/Ag 2 WO 4 photocatalyst, Appl. Surf. Sci., 391, 175, 10.1016/j.apsusc.2016.07.104 Cui, 2020, Fabrication of dual Z-scheme MIL-53(Fe)/Α-Bi2O3/g-C3N4 ternary composite with enhanced visible light photocatalytic performance, Separ. Purif. Technol., 232, 10.1016/j.seppur.2019.115959 Santhosh, 2020, Hydrothermal synthesis of WO3 nanoparticles: characterization and sonocatalytic study, Mater, Today Proc, 25, 183 Jeevitha, 2019, Ammonia sensing at ambient temperature using tungsten oxide (WO3) nanoparticles, Mater. Today Proc., 18, 1602, 10.1016/j.matpr.2019.05.254 Fan, 2020, Double photoelectron-transfer mechanism in Ag-AgCl/WO3/g-C3N4 photocatalyst with enhanced visible-light photocatalytic activity for trimethoprim degradation, J. Hazard Mater., 403, 123964, 10.1016/j.jhazmat.2020.123964 Jing, 2021, Engineering of g-C3N4 nanoparticles/WO3 hollow microspheres photocatalyst with Z-scheme heterostructure for boosting tetracycline hydrochloride degradation, Separ. Purif. Technol., 255, 117646, 10.1016/j.seppur.2020.117646 Chen, 2019, Ag nanoparticles decorated WO 3/g-C 3 N 4 2D/2D heterostructure with enhanced photocatalytic activity for organic pollutants degradation, Appl. Surf. Sci., 467–468, 1000 Askari, 2020, Synthesis of CuWO4/Bi2S3 Z-scheme heterojunction with enhanced cephalexin photodegradation, J. Photochem. Photobiol. Chem., 394, 112463, 10.1016/j.jphotochem.2020.112463 Davari, 2017, Degradation of diphenhydramine by the photocatalysts of ZnO/Fe2O3 and TiO2/Fe2O3 based on clinoptilolite: structural and operational comparison, J. Environ. Chem. Eng., 5, 5707 Liu, 2016, Fabrication of a visible-light-driven photocatalyst and degradation of tetracycline based on the photoinduced interfacial charge transfer of SrTiO3/Fe2O3 nanowires, New J. Chem., 40, 5198, 10.1039/C5NJ03167B Lin, 2016, Synthesis of a SrFeO3-x/g-C3N4 heterojunction with improved visible-light photocatalytic activities in chloramphenicol and crystal violet degradation, RSC Adv., 6, 2323, 10.1039/C5RA21339H Liu, 2019, Simultaneous efficient adsorption and accelerated photocatalytic degradation of chlortetracycline hydrochloride over novel Fe-based MOGs under visible light irradiation assisted by hydrogen peroxide, Inorg. Chem. Front., 6, 1388, 10.1039/C9QI00046A Wang, 2020, Rapid toxicity elimination of organic pollutants by the photocatalysis of environment-friendly and magnetically recoverable step-scheme SnFe2O4/ZnFe2O4 nano-heterojunctions, Chem. Eng. J., 379, 122264, 10.1016/j.cej.2019.122264 Li, 2018, Design of visible-light-response core-shell Fe2O3/CuBi2O4 heterojunctions with enhanced photocatalytic activity towards the degradation of tetracycline: Z-scheme photocatalytic mechanism insight, Inorg. Chem. Front., 5, 3148, 10.1039/C8QI00906F Wang, 2019, Construction of novel Z-scheme Ag/ZnFe 2 O 4/Ag/BiTa 1-x V x O 4 system with enhanced electron transfer capacity for visible light photocatalytic degradation of sulfanilamide, J. Hazard Mater., 375, 161, 10.1016/j.jhazmat.2019.04.081 Dong, 2020, Double-shelled ZnSnO3 hollow cubes for efficient photocatalytic degradation of antibiotic wastewater, Chem. Eng. J., 384, 123279, 10.1016/j.cej.2019.123279 Dong, 2015, Recent developments in heterogeneous photocatalytic water treatment using visible light-responsive photocatalysts: a review, RSC Adv., 5, 14610, 10.1039/C4RA13734E Guo, 2016, Homogeneous {001}-BiOBr/Bi heterojunctions: facile controllable synthesis and morphology-dependent photocatalytic activity, ACS Sustain. Chem. Eng., 4, 4003, 10.1021/acssuschemeng.6b00884 Jiang, 2020, One-pot hydrothermal synthesis of Bi2O3-WO3 p-n heterojunction film for photoelectrocatalytic degradation of norfloxacin, Separ. Purif. Technol., 238, 116428, 10.1016/j.seppur.2019.116428 Arya, 2020, Hydrothermal synthesis of rGO-Bi2WO6 heterostructure for the photocatalytic degradation of levofloxacin, Opt. Mater., 107, 110126, 10.1016/j.optmat.2020.110126 Huang, 2019, Synthesis and application of Bi2WO6 for the photocatalytic degradation of two typical fluoroquinolones under visible light irradiation, RSC Adv., 9, 27768, 10.1039/C9RA04445K Pu, 2020, Plasmonic silver/silver oxide nanoparticles anchored bismuth vanadate as a novel visible-light ternary photocatalyst for degrading pharmaceutical micropollutants, J. Environ. Sci. (China), 96, 21, 10.1016/j.jes.2020.03.038 Li, 2016, Photocatalytic degradation and removal mechanism of ibuprofen via monoclinic BiVO4 under simulated solar light, Chemosphere, 150, 139, 10.1016/j.chemosphere.2016.02.045 Ding, 2017, Z-scheme BiO1-xBr/Bi2O2CO3photocatalyst with rich oxygen vacancy as electron mediator for highly efficient degradation of antibiotics, Appl. Catal. B Environ., 205, 281, 10.1016/j.apcatb.2016.12.018 Tang, 2018, Construction of novel Z-scheme Ag/FeTiO3/Ag/BiFeO3 photocatalyst with enhanced visible-light-driven photocatalytic performance for degradation of norfloxacin, Chem. Eng. J., 351, 1056, 10.1016/j.cej.2018.06.171 Jo, 2015, Fabrication of hierarchically structured novel redox-mediator-free ZnIn2S4 marigold flower/Bi2WO6 flower-like direct Z-scheme nanocomposite photocatalysts with superior visible light photocatalytic efficiency, Phys. Chem. Chem. Phys., 18, 1000, 10.1039/C5CP06176H Xu, 2020, Bi spheres SPR-coupled Cu 2 O/Bi 2 MoO 6 with hollow spheres forming Z- scheme Cu 2 O/Bi/Bi 2 MoO 6 heterostructure for simultaneous photocatalytic decontamination of sulfadiazine and Ni ( II ), J. Hazard Mater., 381, 120953, 10.1016/j.jhazmat.2019.120953 Chen, 2017, Two-dimensional heterojunction photocatalysts constructed by graphite-like C3N4and Bi2WO6nanosheets: enhanced photocatalytic activities for water purification, J. Alloys Compd., 694, 193, 10.1016/j.jallcom.2016.09.326 Li, 2019, In situ growth of copper(II) phthalocyanine-sensitized electrospun CeO2/Bi2MoO6 nanofibers: a highly efficient photoelectrocatalyst towards degradation of tetracycline, Inorg. Chem. Front., 6, 3215, 10.1039/C9QI00950G Luo, 2015, Fabrication of a Ag/Bi3TaO7 plasmonic photocatalyst with enhanced photocatalytic activity for degradation of tetracycline, ACS Appl. Mater. Interfaces, 7, 17061, 10.1021/acsami.5b03535 Li, 2020, Two layered Bi-based borate photocatalysts MBi 2 B 2 O 7 ( M = Ca , Sr ) for photocatalytic degradation and oxygen activation, Colloids Surf., A, 584, 123994, 10.1016/j.colsurfa.2019.123994 Shao, 2020, Electronic structure tailoring of BiOBr (0 1 0) nanosheets by cobalt doping for enhanced visible-light photocatalytic activity, Appl. Surf. Sci., 502, 143895, 10.1016/j.apsusc.2019.143895 Zhong, 2020, Enhanced photocatalytic degradation of levofloxacin by Fe-doped BiOCl nanosheets under LED light irradiation, Chem. Eng. J., 383, 10.1016/j.cej.2019.123148 Kumar, 2018, Quaternary magnetic BiOCl/g-C3N4/Cu2O/Fe3O4 nano-junction for visible light and solar powered degradation of sulfamethoxazole from aqueous environment, Chem. Eng. J., 334, 462, 10.1016/j.cej.2017.10.049 Wen, 2017, Fabrication of SnO2 nanopaticles/BiOI n-p heterostructure for wider spectrum visible-light photocatalytic degradation of antibiotic oxytetracycline hydrochloride, ACS Sustain. Chem. Eng., 5, 5134, 10.1021/acssuschemeng.7b00501 Kandi, 2020, CdS QDs modified BiOI/Bi2MoO6 nanocomposite for degradation of quinolone and tetracycline types of antibiotics towards environmental remediation, Separ. Purif. Technol., 253, 117523, 10.1016/j.seppur.2020.117523 Chen, 2020, Efficient catalytic activity of BiOBr@polyaniline-MnO2ternary nanocomposites for sunlight-driven photodegradation of ciprofloxacin, J. Photochem. Photobiol. Chem., 386, 1 Zhang, 2020, Solvothermal synthesis of a peony flower-like dual Z-scheme PANI/BiOBr/ZnFe2O4 photocatalyst with excellent photocatalytic redox activity for organic pollutant under visible-light, Separ. Purif. Technol., 234, 10.1016/j.seppur.2019.116098 Guan, 2020, Fabrication of Co3O4 and Au co-modified BiOBr flower-like microspheres with high photocatalytic efficiency for sulfadiazine degradation, Separ. Purif. Technol., 234, 10.1016/j.seppur.2019.116100 Guo, 2017, Assessing the photocatalytic transformation of norfloxacin by BiOBr/iron oxides hybrid photocatalyst: kinetics, intermediates, and influencing factors, Appl. Catal. B Environ., 205, 68, 10.1016/j.apcatb.2016.12.032 Jia, 2020, The BiOCl/diatomite composites for rapid photocatalytic degradation of ciprofloxacin : efficiency , toxicity evaluation , mechanisms and pathways, Chem. Eng. J., 380, 122422, 10.1016/j.cej.2019.122422 Yan, 2017, Fabrication of nitrogen doped graphene quantum dots-BiOI/MnNb2O6 p-n junction photocatalysts with enhanced visible light efficiency in photocatalytic degradation of antibiotics, Appl. Catal. B Environ., 202, 518, 10.1016/j.apcatb.2016.09.039 Ganose, 2016, Interplay of orbital and relativistic effects in bismuth oxyhalides: BiOF, BiOCl, BiOBr, and BiOI, Chem. Mater., 28, 10.1021/acs.chemmater.6b00349 Yu, 2015 Al Marzouqi, 2019, Controlled microwave-assisted synthesis of the 2D-BiOCl/2D-g - C 3 N 4 heterostructure for the degradation of amine-based pharmaceuticals under solar light illumination, ACS Omega, 4, 4671, 10.1021/acsomega.8b03665 Zhao, 2017, Synthesis of g-C3N4/Bi4O5Br2 via reactable ionic liquid and its cooperation effect for the enhanced photocatalytic behavior towards ciprofloxacin degradation, J. Photochem. Photobiol. Chem., 347, 168, 10.1016/j.jphotochem.2017.07.023 Chen, 2019, Z-scheme inverse opal CN/BiOBr photocatalysts for highly efficient degradation of antibiotics, Phys. Chem. Chem. Phys., 21, 12818, 10.1039/C9CP01495K Shabani, 2018, One-pot combustion fabrication of grain-like mesoporous intra-heterostructure Bi: XOyClz nanophotocatalyst with substantial solar-light-driven degradation of antibiotic ofloxacin: influence of various fuels, Catal. Sci. Technol., 8, 4052, 10.1039/C8CY00547H He, 2018, Review on nanoscale Bi-based photocatalysts, Nanoscale Horizons, 3, 464, 10.1039/C8NH00062J Zhang, 2020, Facile synthesis of Bi5O7Br/BiOBr 2D/3D heterojunction as efficient visible-light-driven photocatalyst for pharmaceutical organic degradation, Separ. Purif. Technol., 231, 115917, 10.1016/j.seppur.2019.115917 Dandapat, 2018, Solar photocatalytic degradation of trace organic pollutants in water by Bi(0)-doped bismuth oxyhalide thin films, ACS Omega, 3, 10858, 10.1021/acsomega.8b00759 Gao, 2020, TBAOH assisted synthesis of ultrathin BiOCl nanosheets with enhanced charge separation efficiency for superior photocatalytic activity in carbamazepine degradation, J. Colloid Interface Sci., 570, 242, 10.1016/j.jcis.2020.02.065 Liang, 2020, The enhanced photocatalytic performance toward carbamazepine by nitrogen-doped carbon dots decorated on BiOBr/CeO2: mechanism insight and degradation pathways, Chem. Eng. J., 391, 123599, 10.1016/j.cej.2019.123599 Ghoreishian, 2019, Ultrasound-assisted heterogeneous degradation of tetracycline over flower-like rGO/CdWO4 hierarchical structures as robust solar-light-responsive photocatalysts: optimization, kinetics, and mechanism, Appl. Surf. Sci., 489, 110, 10.1016/j.apsusc.2019.05.299 Li, 2019, Boosting visible-light photocatalytic degradation of indomethacin by an efficient and photostable Ag3PO4/NG/WO3 composites, Appl. Surf. Sci., 490, 481, 10.1016/j.apsusc.2019.06.072 Chen, 2020, Direct Z-scheme 1D/2D WO2.72/ZnIn2S4 hybrid photocatalysts with highly-efficient visible-light-driven photodegradation towards tetracycline hydrochloride removal, J. Hazard Mater., 384, 121308, 10.1016/j.jhazmat.2019.121308 Zhu, 2018, Enhanced photodegradation of sulfamethoxazole by a novel WO 3 -CNT composite under visible light irradiation, J. Alloys Compd., 754, 153, 10.1016/j.jallcom.2018.04.286 Kumar, 2018, High-performance photocatalytic hydrogen production and degradation of levo fl oxacin by wide spectrum-responsive Ag/Fe 3 O 4 bridged SrTiO 3/g - C 3 N 4 plasmonic Nanojunctions : joint E ff ect of Ag and Fe 3 O 4, ACS Appl. Mater. Interfaces, 10, 40474, 10.1021/acsami.8b12753 Wu, 2019, Visible-light-driven mitigation of antibiotic oxytetracycline and disinfection of Escherichia coli using magnetic recyclable Ag-modified zinc ferrite/diatomite ternary hybrid material, J. Chem. Technol. Biotechnol., 94, 2537, 10.1002/jctb.6048 Xu, 2013, Photocatalytic degradation of carbamazepine by tailored BiPO4: efficiency, intermediates and pathway, Appl. Catal. B Environ., 130–131, 285, 10.1016/j.apcatb.2012.11.013 Wang, 2020, Photocatalytic degradation of paracetamol on Pd–BiVO4 under visible light irradiation, Chemosphere, 239, 124815, 10.1016/j.chemosphere.2019.124815 Dumitru, 2019, BiFeO3-synthesis, characterization and its photocatalytic activity towards doxorubicin degradation from water, Ceram. Int., 45, 2789, 10.1016/j.ceramint.2018.07.298 Chen, 2020, Photocatalytic performance and mechanism of Z-Scheme CuBi2O4/Ag3PO4 in the degradation of diclofenac sodium under visible light irradiation: effects of pH, H2O2, and S2O82−, Sci. Total Environ., 711, 134643, 10.1016/j.scitotenv.2019.134643 Wen, 2017, Study of the photocatalytic degradation pathway of norfloxacin and mineralization activity using a novel ternary Ag/AgCl-CeO2 photocatalyst, J. Catal., 355, 73, 10.1016/j.jcat.2017.08.028 Liu, 2020, Shuttle-like CeO2/g-C3N4 composite combined with persulfate for the enhanced photocatalytic degradation of norfloxacin under visible light, Ecotoxicol, Environ. Saf., 190, 110062, 10.1016/j.ecoenv.2019.110062 Palas, 2019, Bioinspired metal oxide particles as efficient wet air oxidation and photocatalytic oxidation catalysts for the degradation of acetaminophen in aqueous phase, Ecotoxicol. Environ. Saf., 182, 109367, 10.1016/j.ecoenv.2019.109367 Yue, 2020, Enhanced dark adsorption and visible-light-driven photocatalytic properties of narrower-band-gap Cu 2 S decorated Cu 2 O nanocomposites for efficient removal of organic pollutants, J. Hazard Mater., 384, 121302, 10.1016/j.jhazmat.2019.121302 Zuo, 2017, A facile and novel construction of attapulgite/Cu 2 O/Cu/g-C 3 N 4 with enhanced photocatalytic activity for antibiotic degradation, Ceram. Int., 43, 3324, 10.1016/j.ceramint.2016.11.173 Torki, 2017, Photocatalytic activity of NiS, NiO and coupled NiS-NiO for degradation of pharmaceutical pollutant cephalexin under visible light, RSC Adv., 7, 54651, 10.1039/C7RA09461B Duan, 2019, In situ growth of Ag-SnO2 quantum dots on silver phosphate for photocatalytic degradation of carbamazepine: performance, mechanism and intermediates toxicity assessment, J. Colloid Interface Sci., 534, 270, 10.1016/j.jcis.2018.09.039 Suyana, 2017, Co3O4-C3N4 p-n nano-heterojunctions for the simultaneous degradation of a mixture of pollutants under solar irradiation, Environ. Sci. Nano., 4, 212, 10.1039/C6EN00410E Kumar Ray, 2019, Transformation of tetracycline in water during degradation by visible light driven Ag nanoparticles decorated Α-NiMoO4 nanorods: mechanism and pathways, Chem. Eng. J., 373, 259, 10.1016/j.cej.2019.05.041 Liu, 2018, Application of manganese oxides under anoxic conditions to remove diclofenac from water, J. Environ. Chem. Eng., 6, 5061 Cui, 2019, Constructing ZIF-8 derived C-ZnS/ZnMoO4@MoS2 and C-ZnS/MoS2 nanocomposites using a simple one-pot strategy to enhance photocatalytic degradation activity, RSC Adv., 9, 35189, 10.1039/C9RA06591A Zia, 2019, Photocatalytic degradation of anti-inflammatory drug using POPD/Sb2O3 organic-inorganic nanohybrid under solar light, J. Mater. Res. Technol., 8, 4079, 10.1016/j.jmrt.2019.07.017 Abinaya, 2019, In situ synthesis , characterization , and catalytic performance of polypyrrole polymer-incorporated Ag 2 MoO 4 nanocomposite for detection and degradation of environmental pollutants and pharmaceutical drugs, ACS Appl. Mater. Interfaces, 11, 38321, 10.1021/acsami.9b13682 Fakhri, 2016, Synthesis and characterization of ZrO2 and carbon-doped ZrO2 nanoparticles for photocatalytic application, J. Mol. Liq., 216, 342, 10.1016/j.molliq.2016.01.046 Haddadou, 2018, Photoelectrochemical investigations in lead-free Ba (Ti0.950Sc0.025Nb0.025)O3 ferroelectric ceramics. Application to amoxicillin photodegradation, J. Photochem. Photobiol. Chem., 358, 294, 10.1016/j.jphotochem.2018.03.033 Samy, 2020, Effective photocatalytic degradation of sulfamethazine by CNTs/LaVO4 in suspension and dip coating modes, Separ. Purif. Technol., 235, 10.1016/j.seppur.2019.116138 Arunpandian, 2019, Fabrication of novel Nd 2 O 3/ZnO-GO nanocomposite : an efficient photocatalyst for the degradation of organic pollutants, Colloids Surf., A, 567, 213, 10.1016/j.colsurfa.2019.01.058 Aazam, 2016, Enhancement of the photocatalytic activity of europium(III) oxide by the deposition of gold for the removal of atrazine, J. Alloys Compd., 672, 344, 10.1016/j.jallcom.2016.02.181 Li, 2014, Surface interactions with compartmentalized cellular phosphates explain rare earth oxide nanoparticle hazard and provide opportunities for safer design, ACS Nano, 8, 1771, 10.1021/nn406166n Hou, 2020, Rare earth oxides and their supported noble metals in application of environmental catalysis, J. Rare Earths, 38, 819, 10.1016/j.jre.2020.01.011 Malato, 2016, Decontamination and disinfection of water by solar photocatalysis: the pilot plants of the Plataforma Solar de Almeria, Mater. Sci. Semicond. Process., 42, 15, 10.1016/j.mssp.2015.07.017 Sousa, 2012, Suspended TiO 2 -assisted photocatalytic degradation of emerging contaminants in a municipal WWTP effluent using a solar pilot plant with CPCs, Chem. Eng. J., 198–199, 301, 10.1016/j.cej.2012.05.060 Cabrera-Reina, 2019, TiO2 photocatalysis under natural solar radiation for the degradation of the carbapenem antibiotics imipenem and meropenem in aqueous solutions at pilot plant scale, Water Res., 166, 10.1016/j.watres.2019.115037 Talwar, 2020, Plug flow approaching novel reactor employing in-situ dual effect of photocatalysis and photo-Fenton for the degradation of metronidazole, Chem. Eng. J., 382, 10.1016/j.cej.2019.122772 Andronic, 2016, Pilot-plant evaluation of TiO 2 and TiO 2 -based hybrid photocatalysts for solar treatment of polluted water, J. Hazard Mater., 320, 469, 10.1016/j.jhazmat.2016.08.013 Bansal, 2018, In-situ dual e ff ect studies using novel Fe-TiO 2 composite for the pilot-plant degradation of pentoxifylline, Chem. Eng. J., 332, 682, 10.1016/j.cej.2017.09.121 Wang, 2020, UVC-assisted photocatalytic degradation of carbamazepine by Nd-doped Sb2O3/TiO2 photocatalyst, J. Colloid Interface Sci., 562, 461, 10.1016/j.jcis.2019.11.094 Heidari, 2020, Efficient photocatalytic degradation of furosemide by a novel sonoprecipited ZnO over ion exchanged clinoptilolite nanorods, Separ. Purif. Technol., 242, 116800, 10.1016/j.seppur.2020.116800 Jallouli, 2018, Heterogeneous photocatalytic degradation of ibuprofen in ultrapure water, municipal and pharmaceutical industry wastewaters using a TiO2/UV-LED system, Chem. Eng. J., 334, 976, 10.1016/j.cej.2017.10.045 Durán, 2018, Operation costs of the solar photo-catalytic degradation of pharmaceuticals in water: a mini-review, Chemosphere, 211, 482, 10.1016/j.chemosphere.2018.07.170 Quiñones, 2015, Removal of emerging contaminants from municipal WWTP secondary effluents by solar photocatalytic ozonation, A pilot-scale study, 149, 132 Zhang, 2020, Construction of Bi2O3/CuNiFe LDHs composite and its enhanced photocatalytic degradation of lomefloxacin with persulfate under simulated sunlight, J. Hazard Mater., 383, 10.1016/j.jhazmat.2019.121236 Li, 2019, Photocatalytic degradation of amoxicillin via TiO 2 nanoparticle coupling with a novel submerged porous ceramic membrane reactor, J. Clean. Prod., 209, 755, 10.1016/j.jclepro.2018.10.183 Shankar, 2017, Facile approach for large-scale production of metal and metal oxide nanoparticles and preparation of antibacterial cotton pads, Carbohydr. Polym., 163, 137, 10.1016/j.carbpol.2017.01.059 Gao, 2020, Economic evaluation of typical metal production process: a case study of vanadium oxide production in China, J. Clean. Prod., 256, 120217, 10.1016/j.jclepro.2020.120217 Shi, 2020, Tetracycline removal from aqueous solution by visible-light-driven photocatalytic degradation with low cost red mud wastes, Chem. Eng. J., 382, 122876, 10.1016/j.cej.2019.122876 Lu, 2019, A novel TiO2/biochar composite catalysts for photocatalytic degradation of methyl orange, Chemosphere, 222, 391, 10.1016/j.chemosphere.2019.01.132 Gao, 2013, A surfactant-thermal method to prepare four new three-dimensional heterometal-organic frameworks, Dalton Trans., 42, 11367, 10.1039/c3dt51103k Grządka, 2020, CMC as a stabiliser of metal oxide suspensions, Cellulose, 27, 2225, 10.1007/s10570-019-02930-y Muhammad, 2020, Volumetric buffering of manganese dioxide nanotubes by employing ‘as is’ graphene oxide: an approach towards stable metal oxide anode material in lithium-ion batteries, J. Alloys Compd., 842, 10.1016/j.jallcom.2020.155803