Recent development in emerging phosphorene based novel materials: Progress, challenges, prospects and their fascinating sensing applications

Progress in Solid State Chemistry - Tập 65 - Trang 100336 - 2022
Ayesha Khan Tareen1,2, Karim Khan1,3,2, Sarish Rehman4, Muhammad Iqbal5, Jian Yu1, Nasir mahmood6, Zewen Zhou7, Jinde Yin7,8, Chuan li1, Han Zhang2
1School of Mechanical Engineering, Dongguan University of Technology, Dongguan, 523808, China
2Shenzhen Engineering Laboratory of Phosphorene and Optoelectronics, International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Engineering, Shenzhen University, Shenzhen, 518060, China
3School of Electrical Engineering & Intelligentization, Dongguan University of Technology, Dongguan, 523808, China
4Chemistry Department, McGill University, 801 Sherbrooke St. W, Montreal, Quebec, Canada
5Department of Bio-Chemistry, Abdul Wali Khan University Mardan, Khyber Pakhtunkhwa (K.P.K.), 23200, Pakistan
6School of Engineering, The Royal Melbourne Institute of Technology (RMIT) University, Melbourne, Victoria, Australia
7Shenzhen Nuoan Environmental & Safety Inc., Shenzhen, 518107, China
8College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China

Tài liệu tham khảo

Khan, 2020, Sensing applications of atomically thin group IV carbon siblings xenes: progress, challenges, and prospects, Adv Funct Mater Khan, 2021, Novel emerging graphdiyne based two dimensional materials: synthesis, properties and renewable energy applications, Nano Today, 39, 10.1016/j.nantod.2021.101207 Khan, 2021, Recent development in Graphdiyne and its derivative materials for novel biomedical applications, J Mater Chem B, 10.1039/D1TB01794B Khan, 2021, Novel synthesis, properties and applications of emerging group VA two-dimensional monoelemental materials (2D-Xenes), Mater Chem Front, 5, 6333, 10.1039/D1QM00629K Bo, 2007, Phase diagrams of the KF-K2TaF7and KF-Ta2O5systems, J Thermal Anal, 90, 159, 10.1007/s10973-006-7700-5 Hirsch, 2010, The era of carbon allotropes, Nat Mater, 9, 868, 10.1038/nmat2885 Meyer, 1964, Solid allotropes of sulfur, Chem Rev, 64, 429, 10.1021/cr60230a004 Khan, 2021, Navigating recent advances in monoelemental materials (Xenes)-fundamental to biomedical applications, Prog Solid State Chem, 10.1016/j.progsolidstchem.2021.100326 Ma, 2021, Broadband nonlinear photonics in few‐layer borophene, Small, 17, 10.1002/smll.202006891 Wang, 2021, Advanced devices for tumor diagnosis and therapy, Small Shi, 2021, Two-dimensional selenium and its composites for device applications, Nano Res, 1 Ahmad, 2021, Application of two-dimensional materials in perovskite solar cells; recent progress, challenges and prospective solutions, J Mater Chem C Tareen, 2021, Recent progress, challenges, and prospects in emerging group-VIA Xenes: synthesis, properties and novel applications, Nanoscale, 13, 510, 10.1039/D0NR07444F Tareen, 2021, Confinement in two-dimensional materials: major advances and challenges in the emerging renewable energy conversion and other applications, Prog Solid State Chem, 61, 10.1016/j.progsolidstchem.2020.100294 Ahmad, 2021, Evolution of low-dimensional material-based field-effect transistors, Nanoscale, 13, 5162, 10.1039/D0NR07548E Peruzzini, 2019, A perspective on recent advances in Phosphorene functionalization and its applications in devices, Eur J Inorg Chem, 2019, 1476, 10.1002/ejic.201801219 Shi, 2020, Two-dimensional tellurium: progress, challenges, and prospects, Nano-Micro Lett, 12, 1, 10.1007/s40820-020-00427-z Khan, 2020, Recent progress, challenges, and prospects in two-dimensional photo-catalyst materials and environmental remediation, Nano-Micro Lett, 12, 1, 10.1007/s40820-020-00504-3 Khan, 2020, Recent developments in emerging two-dimensional materials and their applications, J Mater Chem C, 8, 387, 10.1039/C9TC04187G Chen, 2020, Recent advances of low-dimensional materials in Mid-and Far-infrared photonics, Appl Mater Today, 21 Khan, 2019, Recent advances in two-dimensional materials and their nanocomposites in sustainable energy conversion applications, Nanoscale, 11, 21622, 10.1039/C9NR05919A Zhang, 2019, Recent advances in emerging 2D material‐based gas sensors: potential in disease diagnosis, Adv Mater Interfaces, 6, 10.1002/admi.201901329 Hu, 2020, Recent advances in doping engineering of black phosphorus, J Mater Chem, 8, 5421, 10.1039/D0TA00416B Khan, 2019, Going green with batteries and supercapacitor: two dimensional materials and their nanocomposites based energy storage applications, Prog Solid State Chem Tareen, 2020, Confinement in two-dimensional materials: major advances and challenges in the emerging renewable energy conversion and other applications, Prog Solid State Chem Dai, 2018, Electrochemical mechanism and structure simulation of 2D lithium‐ion battery, Adv Theory Simul, 1, 10.1002/adts.201800023 Dinh, 2018, Ultrathin porous NiFeV ternary layer hydroxide nanosheets as a highly efficient bifunctional electrocatalyst for overall water splitting, Small, 14, 10.1002/smll.201703257 Iqbal MW, Iqbal MZ, Khan MF, Shehzad MA, Seo Y, Park JH, et al. High-mobility and air-stable single-layer WS2 field-effect transistors sandwiched between chemical vapor deposition-grown hexagonal BN films. Sci Rep.5:10699. Khan, 2020, Synthesis, properties and novel electrocatalytic applications of the 2D-borophene Xenes, Prog Solid State Chem, 10.1016/j.progsolidstchem.2020.100283 Khan, 2019, Novel two dimensional carbon-chromium nitride based composite as an electrocatalyst for Oxygen Reduction Reaction, Front Chem, 7, 738, 10.3389/fchem.2019.00738 Khan, 2018, A comprehensive review on synthesis of pristine and doped inorganic room temperature stable mayenite electride, [Ca24Al28O64]4+(e−)4 and its applications as a catalyst, Prog Solid State Chem, 54, 1, 10.1016/j.progsolidstchem.2018.12.001 Khan, 2020, Recent developments in emerging two-dimensional materials and their applications, J Mater Chem C, 10.1039/C9TC04187G Khan, 2020, Facile synthesis of mayenite electride nanoparticles encapsulated in graphitic shells like carbon nano onions: non-noble-metal electrocatalysts for oxygen reduction reaction (ORR), Front Chem, 7, 934, 10.3389/fchem.2019.00934 Khan, 2018, Facile metal-free reduction-based synthesis of pristine and cation-doped conductive mayenite, RSC Adv, 8, 24276, 10.1039/C8RA02790K Khan, 2018, Facile synthesis of a cationic-doped [Ca24Al28O64] 4+(4e−) composite via a rapid citrate sol-gel method, Dalton Trans, 47, 3819, 10.1039/C7DT04543C Khan, 2018, Single step synthesis of highly conductive room-temperature stable cation-substituted mayenite electride target and thin film, Sci Rep Khan, 2018, Synthesis and low temperature magnetic measurements of polycrystalline Gadolinium nanowires, Mater Lett, 228, 266, 10.1016/j.matlet.2018.06.030 Khan, 2013, Polymer reinforcement using liquid-exfoliated boron nitride nanosheets, Nanoscale, 5, 10.1039/C2NR33049K Li, 2020, Recent progress of two-dimensional thermoelectric materials, Nano-Micro Lett, 12, 36, 10.1007/s40820-020-0374-x Tareen, 2019, Nickel-based transition metal nitride electrocatalysts for the oxygen evolution reaction, ChemSusChem, 12, 3941, 10.1002/cssc.201900553 Song, 2010, Large scale growth and characterization of atomic hexagonal boron nitride layers, Nano Lett, 10, 3209, 10.1021/nl1022139 Guang-Ming, 2008, Optimum municipal wastewater treatment plant design with consideration of uncertainty, J Environ Sci Tpa, 2021 S Ca Lise, 2014 Dávila, 2014, Germanene: a novel two-dimensional germanium allotrope akin to graphene and silicene, New J Phys, 16, 3579, 10.1088/1367-2630/16/9/095002 Liu, 2014, Phosphorene: an unexplored 2D semiconductor with a high hole mobility, ACS Nano, 8, 4033, 10.1021/nn501226z Kiani, 2021, A first principle study: effect of tin substitution on magnetic properties of bismuth ferrite nanoparticles prepared by sol-gel synthesis method, Inorg Chem Commun, 127, 10.1016/j.inoche.2021.108483 Aslam, 2021, Mixed-dimensional niobium disulfide-graphene foam heterostructures as an efficient catalyst for hydrogen production, Int J Hydrogen Energy, 46, 33679, 10.1016/j.ijhydene.2021.07.170 Khan, 2021, Nanoscale CuTe electrocatalyst immobilized at conductor surface for remarkable hydrogen evolution reaction, Int J Hydrogen Energy, 46, 18729, 10.1016/j.ijhydene.2021.03.031 Xia, 2021, Nonlinear optical properties and ultrafast photonics of 2D BP/Ti3C2 heterostructures, Opt Mater, 112, 10.1016/j.optmat.2021.110809 Saeed, 2021, Structural, electronic, optical and thermoelectric analysis of perovskites XRuO3 (X= Ca, Sr), Phys B Condens Matter, 614, 10.1016/j.physb.2021.412962 Tang, 2021, Graphene foam–polymer based electronic skin for flexible tactile sensor, Sensor Actuator Phys, 327, 10.1016/j.sna.2021.112697 Jamil, 2021, The role of nitrogen in transition-metal nitrides in electrochemical water splitting, Chem Catal, 10.1016/j.checat.2021.06.014 Tareen, 2021, A novel MnO–CrN nanocomposite based non-enzymatic hydrogen peroxide sensor, RSC Adv, 11, 19316, 10.1039/D1RA01485D Ahmad, 2021, Introduction, production, characterization and applications of defects in graphene, J Mater Sci Mater Electron, 1 Shah, 2021, Application of MXenes in perovskite solar cells: a short review, Nanomaterials, 11, 2151, 10.3390/nano11082151 Khan, 2021, Sensing applications of atomically thin group IV carbon siblings Xenes: progress, challenges, and prospects, Adv Funct Mater, 31, 10.1002/adfm.202005957 Xidong, 2015 Shi, 2020, Two-dimensional tellurium: progress, challenges, and prospects, Nano-Micro Lett, 12, 1, 10.1007/s40820-020-00427-z Khan, 2020, Synthesis, properties and novel electrocatalytic applications of the 2D-borophene Xenes, Prog Solid State Chem, 59, 10.1016/j.progsolidstchem.2020.100283 Khatoon, 2020, Facile synthesis of α-Fe2O3/Nb2O5 heterostructure for advanced Li-Ion batteries, J Alloys Compd, 837, 10.1016/j.jallcom.2020.155294 Elahi, 2020, Enhanced electrical and broad spectral (UV-Vis-NIR) photodetection in a Gr/ReSe 2/Gr heterojunction, Dalton Trans, 49, 10017, 10.1039/D0DT01164A Kang, 2020, Two dimensional nanomaterials-enabled smart light regulation technologies: recent advances and developments, Optik, 220, 10.1016/j.ijleo.2020.165191 Khan, 2020, New physical insight into crystal structure, luminescence and optical properties of YPO4: Dy3+∖ Eu3+∖ Tb3+ single-phase white-light-emitting phosphors, J Alloys Compd, 817, 10.1016/j.jallcom.2019.152687 Khan, 2020, Going green with batteries and supercapacitor: two dimensional materials and their nanocomposites based energy storage applications, Prog Solid State Chem, 58, 10.1016/j.progsolidstchem.2019.100254 Khan, 2019, Novel two-dimensional carbon–chromium nitride-based composite as an electrocatalyst for oxygen reduction reaction, Front Chem, 7, 738, 10.3389/fchem.2019.00738 Khan, 2019, Fe-doped mayenite electride composite with 2D reduced graphene oxide: as a non-platinum based, highly durable electrocatalyst for Oxygen Reduction Reaction, Sci Rep, 9, 1, 10.1038/s41598-019-55207-6 Khan, 2019, A comprehensive review on synthesis of pristine and doped inorganic room temperature stable mayenite electride,[Ca24Al28O64] 4+(e−) 4 and its applications as a catalyst, Prog Solid State Chem, 54, 1, 10.1016/j.progsolidstchem.2018.12.001 Sorkin, 2016, 1 Fei, 2014, Strain-Engineering the anisotropic electrical conductanceof few-layer black phosphorus, Nano Lett, 10.1021/nl500935z Khan, 2019, Single step synthesis of highly conductive room-temperature stable cation-substituted mayenite electride target and thin film, Sci Rep, 9, 1 Tareen, 2019, Nickel‐based transition metal nitride electrocatalysts for the oxygen evolution reaction, Chemsuschem, 12, 3941, 10.1002/cssc.201900553 Castellanos-Gomez, 2015, Black phosphorus: narrow gap, wide applications, J Phys Chem Lett Tongay, 2014 Chhowalla, 2013, The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets, Nat Chem, 5, 263, 10.1038/nchem.1589 Castellanos-Gomez, 2014, Isolation and characterization of few-layer black phosphorus, 2D Mater, 1, 10.1088/2053-1583/1/2/025001 Kumar, 2016, Thickness and electric field dependent polarizability and dielectric constant in phosphorene, Phys Rev B, 93, 10.1103/PhysRevB.93.195428 Le, 2012, Folded graphene nanoribbons with single and double closed edges, Phys Rev B, 85, 10.1103/PhysRevB.85.035403 2000, Coexistence of negative photoconductivity and hysteresis in semiconducting graphene, AIP Adv Dipan, 2014, The emerging chemistry of sodium ion batteries for electrochemical energy storage, Angew Chem Int Ed Batmunkh, 2016, Phosphorene and phosphorene‐based materials – prospects for future applications, Adv Mater, 28, 8586, 10.1002/adma.201602254 Bibbò, 2019, High-speed amplitude modulator with a high modulation index based on a plasmonic resonant tunable metasurface, Appl Opt, 58, 2687, 10.1364/AO.58.002687 Elshahat, 2019, High-capability micro-optical buffer based on coupled hexagonal cavity in photonic crystal waveguide, Appl Nanosci, 9, 1963, 10.1007/s13204-019-00999-2 Bibbò, 2019, Radiation-direction steerable nanoantennae, SN Appl Sci, 1, 1, 10.1007/s42452-019-0882-9 Saleemi, 2019, Structural and magnetoresistance properties of transfer-free amorphous carbon thin films, Crystals, 9, 124, 10.3390/cryst9030124 Ouyang Z. High speed amplitude modulator with high modulation index based on plasmonic resonant tunable metasurface. Iqbal, 2019, Synthesis and characterization of transition metals doped CuO nanostructure and their application in hybrid bulk heterojunction solar cells, SN Appl Sci, 1, 1, 10.1007/s42452-019-0663-5 Khan, 2019, Controlled synthesis of ammonium manganese tri-fluoride nanoparticles with enhanced electrochemical performance, Mater Res Express, 6 Abood, 2019, Slow light with high normalized delay-bandwidth product in low-dispersion photonic-crystal coupled-cavity waveguide, Opt Commun, 439, 181, 10.1016/j.optcom.2019.01.063 Gu, 2010, Corrosion fatigue behavior of two typical biomedical Mg alloys-AZ91D and WE43 in simulated body fluid (vol 6, pg 4605, Acta Biomater, 10.1016/j.actbio.2010.07.026 Jia, 2017, Highly sensitive fluorescence detection of mercury (II) ions based on WS 2 nanosheets and T7 exonuclease assisted cyclic enzymatic amplification, Sensor Actuator B Chem, 249, 189, 10.1016/j.snb.2017.04.094 Li, 2016, Low‐dimensional transition metal dichalcogenide nanostructures based sensors, Adv Funct Mater, 26, 7034, 10.1002/adfm.201602136 Cho, 2016, Superior chemical sensing performance of black phosphorus: comparison with MoS2and graphene, Adv Mater, 10.1002/adma.201601167 Kolarovic, 2009, Interplay of structure, hydration and thermal stability in formacetal modified oligonucleotides: RNA may tolerate nonionic modifications better than DNA, J Am Chem Soc, 131, 14932, 10.1021/ja904926e Rodin, 2014, Strain-induced gap modification in black phosphorus, Phys Rev Lett, 112, 10.1103/PhysRevLett.112.176801 Xue B. Báo cáo khoa học: protein tandem repeats – the more perfect, the less structured pptx. Scott, 2000, Isolation and characterization of microcystins, cyclic heptapeptide hepatotoxins from a lake erie strain of microcystis aeruginosa, J Great Lake Res Radisavljevic, 2013, Reply to 'Measurement of mobility in dual-gated MoS2 transistors, Nat Nanotechnol, 8, 147, 10.1038/nnano.2013.31 Takao, 1981, Electronic structure of black phosphorus in tight binding approach, J Phys Soc Jpn, 10.1143/JPSJ.50.3362 Khan, 2019, Enhancement of mechanical and electrical properties for in-situ compatibilization of immiscible polypropylene/polystyrene blends, Mater Res Express, 6 Khan, 2018, Facile synthesis of tin-doped mayenite electride composite as a non-noble metal durable electrocatalyst for oxygen reduction reaction (ORR), Dalton Trans, 47, 13498, 10.1039/C8DT02548G Khan, 2018, Facile synthesis of a cationic-doped [Ca 24 Al 28 O 64] 4+(4e−) composite via a rapid citrate sol–gel method, Dalton Trans, 47, 3819, 10.1039/C7DT04543C Lin, 2017, Liquid-phase exfoliation of black phosphorus and its applications, FlatChem, 2, 15, 10.1016/j.flatc.2017.03.001 Jain, 2015, Strongly anisotropic in-plane thermal transport in single-layer black phosphorene, Sci Rep, 5, 1, 10.1038/srep08501 Wu, 2015, Nine new phosphorene polymorphs with non-honeycomb structures: a much extended family, Nano Lett, 15, 3557, 10.1021/acs.nanolett.5b01041 Guo, 2015, Pristine and defect-containing phosphorene as promising anode materials for rechargeable Li batteries, J Mater Chem, 3 Akahama, 1983, Electrical properties of black phosphorus single crystals, J Phys Soc Jpn, 52, 2148, 10.1143/JPSJ.52.2148 Fei, 2014, Lattice vibrational modes and Raman scattering spectra of strained phosphorene, Appl Phys Lett, 105, 199, 10.1063/1.4894273 Barros JM, Christensen KT. Spatial characteristics of large-scale motions in smooth and rough turbulent boundary layers. 64th Annual Meeting of the APS Division of Fluid Dynamics2011. Ameen, 2015 Zhu, 2014, Coexistence of size-dependent and size-independent thermal conductivities in phosphorene, Phys Rev B, 90, 10.1103/PhysRevB.90.214302 Cai, 2015, Giant phononic anisotropy and unusual anharmonicity of phosphorene: interiayer coupling and strain engineering, Adv Funct Mater, 25, 2230, 10.1002/adfm.201404294 Jang, 2016, Anisotropic thermal conductivity of exfoliated black phosphorus, Adv Mater, 27, 8017, 10.1002/adma.201503466 Dresselhaus, 2016, Anisotropic electron-photon and electron-phonon interactions in black phosphorus (vol 16, pg 2260, 2016), Nano Lett, 16, 4731 Bianca Clausen, 2011, Corruption and condence in public institutions, World Bank Econ Rev, 25, 212, 10.1093/wber/lhr018 Akhtar, 2017, Recent advances in synthesis, properties, and applications of phosphorene, NPJ 2D Mater Appl, 1, 1, 10.1038/s41699-017-0007-5 Xin, 2018, In-situ reduction and deposition of Ag nanoparticles on black phosphorus nanosheets co-loaded with graphene oxide as a broad spectrum photocatalyst for enhanced photocatalytic performance, J Alloys Compd Bridgman, 1914, J Franklin Inst, 178, 644 Zhang, 2012, Inuence of VC precipitation on the shape-memory effect and corrosion resistance on an Fe–Mn–Si–Cr–Ni alloy, Adv Mater Res, 562–564, 134 Xia, 2016, Visualizing the electrochemical lithiation/delithiation behaviors of black phosphorus by in situ transmission electron microscopy, J Phys Chem C Yang, 2018, Three-electrode flexible zinc-nickel battery with black phosphorus modified polymer electrolyte, Mater Lett, 233, 118, 10.1016/j.matlet.2018.08.104 Köpf, 2014, Access and in situ growth of phosphorene-precursor black phosphorus, J Cryst Growth, 405, 6, 10.1016/j.jcrysgro.2014.07.029 Li, 2017, Phosphorene as a polysulfide immobilizer and catalyst in high‐performance lithium–sulfur batteries, Adv Mater, 29 Liang, 2014, Electronic bandgap and edge reconstruction in phosphorene materials, Nano Lett, 14, 6400, 10.1021/nl502892t Kang, 2017, Ionic intercalation in two-dimensional van der Waals materials: in situ characterization and electrochemical control of the anisotropic thermal conductivity of black phosphorus, Nano Lett, 17, 1431, 10.1021/acs.nanolett.6b04385 Zhou, 2019, Growth mechanism of black phosphorus synthesized by different ball milling techniques, J Alloys Compd, 784, 339, 10.1016/j.jallcom.2019.01.023 Yasaei, 2015, High‐quality black phosphorus atomic layers by liquid‐phase exfoliation, Adv Mater, 27, 1887, 10.1002/adma.201405150 Yuan, 2019, Ultrathin black phosphorus-on-nitrogen doped graphene for efficient overall water splitting: dual modulation roles of directional interfacial charge transfer, J Am Chem Soc, 141, 4972, 10.1021/jacs.9b00154 Zhao, 2016, Growth mechanism and enhanced yield of black phosphorus microribbons, Cryst Growth Des, 16, 1096, 10.1021/acs.cgd.5b01709 Tian, 2018, Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution, Proc Natl Acad Sci Unit States Am, 115, 4345, 10.1073/pnas.1800069115 Jiang, 2016, Facile synthesis of black phosphorus: an efficient electrocatalyst for the oxygen evolving reaction, Angew Chem, 128, 14053, 10.1002/ange.201607393 Li, 2014, Black phosphorus field-effect transistors, Nat Nanotechnol, 9, 372, 10.1038/nnano.2014.35 Bridgman, 1914, Two new modifications of phosphorus, J Am Chem Soc, 36, 1344, 10.1021/ja02184a002 Li, 2015, Polarization and thickness dependent absorption properties of black phosphorus: new saturable absorber for ultrafast pulse generation, Sci Rep, 5, 1 Brown, 1965, Refinement of the crystal structure of black phosphorus, Acta Crystallogr, 19, 684, 10.1107/S0365110X65004140 Maruyama, 1981, Synthesis and some properties of black phosphorus single crystals, Phys B+C, 105, 99, 10.1016/0378-4363(81)90223-0 Baba, 1989, Preparation of black phosphorus single crystals by a completely closed bismuth-flux method and their crystal morphology, Jpn J Appl Phys, 28, 1019, 10.1143/JJAP.28.1019 Sofer, 2016, Few-layer black phosphorus nanoparticles, Chem Commun, 52, 1563, 10.1039/C5CC09150K Lange, 2007, Au3SnP7@ black phosphorus: an easy access to black phosphorus, Inorg Chem, 46, 4028, 10.1021/ic062192q Nagao, 2011, All-solid-state lithium secondary batteries with high capacity using black phosphorus negative electrode, J Power Sources, 196, 6902, 10.1016/j.jpowsour.2010.12.055 Sun, 2014, Formation of stable phosphorus–carbon bond for enhanced performance in black phosphorus nanoparticle–graphite composite battery anodes, Nano Lett, 14, 4573, 10.1021/nl501617j Wang, 2015, Black phosphorus nanoelectromechanical resonators vibrating at very high frequencies, Nanoscale, 7, 877, 10.1039/C4NR04829F Sun, 2012, Electrochemical activity of black phosphorus as an anode material for lithium-ion batteries, J Phys Chem C, 116, 14772, 10.1021/jp302265n Zhang, 2015, Black phosphorus quantum dots, Angew Chem Int Ed, 54, 3653, 10.1002/anie.201409400 Ge, 2015, Dynamical evolution of anisotropic response in black phosphorus under ultrafast photoexcitation, Nano Lett, 15, 4650, 10.1021/acs.nanolett.5b01409 Nilges, 2008, A fast low-pressure transport route to large black phosphorus single crystals, J Solid State Chem, 181, 1707, 10.1016/j.jssc.2008.03.008 Lee, 2015, Anisotropic in-plane thermal conductivity of black phosphorus nanoribbons at temperatures higher than 100 K, Nat Commun, 6, 1, 10.1038/ncomms9573 Wang, 2015, Ultrathin black phosphorus nanosheets for efficient singlet oxygen generation, J Am Chem Soc, 137, 11376, 10.1021/jacs.5b06025 Radisavljevic, 2013, Response to comment "Measurement of mobility in dual-gated MoS2 transistors, Physics Wen, 2015, Direction dependent thermal conductivity of monolayer phosphorene: parameterization of Stillinger-Weber potential and molecular dynamics study, J Appl Phys, 117 2004 Ienco, 2020, On the comparison of oxygen and sulfur transfer reactivities in phosphine and phosphorene: the case of R 3 Sb(X) carriers (X = O or S), Dalton Trans, 49, 15072, 10.1039/D0DT02860F Guo, 2019, Two-dimensional black phosphorus: a new star in energy applications and the barrier to stability, Appl Mater Today, 14, 51, 10.1016/j.apmt.2018.11.002 Luo, 2019, 2D black phosphorus–based biomedical applications, Adv Funct Mater, 29, 10.1002/adfm.201808306 Caporali, 2017, Decoration of exfoliated black phosphorus with nickel nanoparticles and its application in catalysis, Chem Commun, 53, 10946, 10.1039/C7CC05906J Tian, 2018, Supported black phosphorus nanosheets as hydrogen-evolving photocatalyst achieving 5.4% energy conversion efficiency at 353 K, Nat Commun, 9, 1, 10.1038/s41467-018-03737-4 Bae, 2010, 30 inch roll-based production of high-quality graphene films for flexible transparent electrodes, Physics, 5, 574 Strudwick, 2015, Chemical vapor deposition of high quality graphene films from carbon dioxide atmospheres, ACS Nano, 9, 31, 10.1021/nn504822m Lee, 2012, Synthesis of large-area MoS 2 atomic layers with chemical vapor deposition, Adv Mater Lee, 2014 Duan, 2013, Transparent and electrical properties of Ga-doped Zn1x Cd x O films post-annealed in vacuum and nitrogen, J Mater Sci Mater Electron, 24, 2116, 10.1007/s10854-013-1067-8 Tiwary, 2015, ChemInform abstract: chemical vapor deposition of monolayer rhenium disulfide (ReS2), ChemInform, 46, 10.1002/chin.201542220 Enze, 2015, ReS2-Based field-effect transistors and photodetectors, Adv Funct Mater Lu, 2007, Magneto-electronic properties of the AA- and ABC-stacked graphites, Euro Phys J B, 60, 161, 10.1140/epjb/e2007-00339-4 Radisavljevic, 2011 Fan, 2015, ChemInform abstract: thin metal nanostructures: synthesis, properties and applications, ChemInform, 46, 10.1002/chin.201532235 Barillaro, 2014 Ruan, 2020, Novel variants in AP4B1 cause spastic tetraplegia, moderate psychomotor development delay and febrile seizures in a Chinese patient: a case report, BMC Med Genet, 21, 10.1186/s12881-020-0988-3 Gorbachev, 2011, Hunting for monolayer boron nitride: optical and Raman signatures, Small, 7, 10.1002/smll.201001628 Hai, 2014, Preparation and applications of mechanically exfoliated single-layer and multilayer MoS and WSe nanosheets, Acc Chem Res, 47 Tayari, 2015, Two-dimensional magnetotransport in a black phosphorus naked quantum well, Nat Commun, 6, 1, 10.1038/ncomms8702 Cui, 2015, Ultrahigh sensitivity and layer-dependent sensing performance of phosphorene-based gas sensors, Nat Commun, 6, 1, 10.1038/ncomms9632 Wood, 2014, Effective passivation of exfoliated black phosphorus transistors against ambient degradation, Nano Lett, 14, 6964, 10.1021/nl5032293 Kim, 2015, Dual gate black phosphorus field effect transistors on glass for NOR logic and organic light emitting diode switching, Nano Lett, 15, 5778, 10.1021/acs.nanolett.5b01746 Saito, 2015, Ambipolar insulator-to-metal transition in black phosphorus by ionic-liquid gating, ACS Nano, 9, 3192, 10.1021/acsnano.5b00497 Luo, 2015, Anisotropic in-plane thermal conductivity observed in few-layer black phosphorus, Nat Commun, 6, 1, 10.1038/ncomms9572 Mu, 2015, The mechanical exfoliation mechanism of black phosphorus to phosphorene: a first-principles study, EPL (Europhys Lett), 112, 10.1209/0295-5075/112/37003 Fa Vron, 2014, Exfoliating pristine black phosphorus down to the monolayer: photo-oxidation and electronic confinement effects, Physics, 1, 708 Anugrah, 2015, Determination of the Schottky barrier height of ferromagnetic contacts to few-layer phosphorene, Appl Phys Lett, 106, 10.1063/1.4914978 Koenig, 2014, Electric field effect in ultrathin black phosphorus, Appl Phys Lett, 104, 10.1063/1.4868132 Favron, 2014 Wang, 2015, Highly anisotropic and robust excitons in monolayer black phosphorus, Nat Nanotechnol, 10, 517, 10.1038/nnano.2015.71 Liu, 2015, In situ thermal decomposition of exfoliated two-dimensional black phosphorus, J Phys Chem Lett, 6, 773, 10.1021/acs.jpclett.5b00043 Wang, 2015, Highly anisotropic and robust excitons in monolayer black phosphorus, Nat Nanotechnol, 10, 10.1038/nnano.2015.71 Zhe, 2015, Anisotropic in-plane thermal conductivity observed in few-layer black phosphorus, Nat Commun Kang, 2013, Calyx abscission in pear (pyrus spp.) cultivars and its inheritance, Korean J Horticultural Sci Technol, 31, 10.7235/hort.2013.12224 Koenig, 2014, Electric field effect in ultrathin black phosphorus, Appl Phys Lett, 104, 10451, 10.1063/1.4868132 Li, 2014, Black phosphorus field-effect transistors, Nat Nanotechnol Du, 2014, De novo assembled transcriptome analysis and SSR marker development of a mixture of six tissues from lilium oriental hybrid 'sorbonne, Plant Mol Biol Rep, 33, 281, 10.1007/s11105-014-0746-9 Lu, 2014, Nano Res, 7, 853, 10.1007/s12274-014-0446-7 Qu, 2017, Angew Chem Int Ed, 56, 14488, 10.1002/anie.201706228 Kou, 2015, Phosphorene: fabrication, properties, and applications, J Phys Chem Lett, 6, 2794, 10.1021/acs.jpclett.5b01094 Nina, 2018, L-type calcium channel blockers and substance P induce angiogenesis of cortical vessels associated with beta-amyloid plaques in an Alzheimer mouse model, Neurobiol Aging Island, 2014, Environmental instability of few-layer black phosphorus, 2D Mater, 2 Castellanos-Gomez, 2014, Isolation and characterization of few-layer black phosphorus, 2D Mater, 1, 10.1088/2053-1583/1/2/025001 Zhao, 2014, Progress of nanoscience in China, 物理学前沿., 9, 257 Kim, 2006, Synthesis and characteristics of microcapsules containing electrophoretic particle suspensions, Colloid Polym Sci, 284, 813, 10.1007/s00396-006-1465-z Lee, 2016, Tuning the thickness of black phosphorus via ion bombardment-free plasma etching for device performance improvement, J Mater Chem C, 4, 6234, 10.1039/C6TC01514J Zhang, 2014, Extraordinary photoluminescence and strong temperature/angle-dependent Raman responses in few-layer phosphorene, ACS Nano, 8, 9590, 10.1021/nn503893j Li, 2012, From bulk to monolayer MoS2: evolution of Raman scattering, Adv Funct Mater, 22, 1385, 10.1002/adfm.201102111 Yang, 2015, Optical tuning of exciton and trion emissions in monolayer phosphorene, Light Sci Appl, 4, 10.1038/lsa.2015.85 Tayari, 2015, Two-dimensional magnetotransport in a black phosphorus naked quantum well, Nat Commun, 6, 7702, 10.1038/ncomms8702 Shen, 2009, Liver-specific ZP domain-containing protein (LZP) as a new partner of Tamm-Horsfall protein harbors on renal tubules, Mol Cell Biochem, 321, 73, 10.1007/s11010-008-9921-3 Wang, 2014, Black phosphorus nanoelectromechanical resonators vibrating at very high frequencies, Nanoscale, 7 Yu, 2015, Ambipolar insulator-to-metal transition in black phosphorus by ionic-liquid gating, ACS Nano, 9, 3192, 10.1021/acsnano.5b00497 Xu, 2015, Extraordinarily bound quasi-one-dimensional trions in two-dimensional phosphorene atomic semiconductors, ACS Nano Yang, 2015, Optical tuning of exciton and trion emissions in monolayer phosphorene, Light Sci Appl, 4, 10.1038/lsa.2015.85 Diao, 2015, Polarization and thickness dependent absorption properties of black phosphorus: new saturable absorber for ultrafast pulse generation, Sci Rep, 5, 15899, 10.1038/srep15899 Dfae, 2021, The state of diabetes treatment coverage in 55 low-income and middle-income countries: a cross-sectional study of nationally representative, individual-level data in 680102 adults, Lancet Healthy Long Wood JD, Wells S, Jariwala D, Chen KS, Liu X, Sangwan V, et al. Ambient oxidation and alumina passivation of exfoliated black phosphorus transistors. Cho, 2010, Enhanced light extraction in light-emitting diodes with photonic crystal structure selectively grown on p-GaN, Appl Phys Lett, 96, 181110, 10.1063/1.3427352 Chen, 2015, Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and Mode-locking laser operation, Opt Express, 23, 12823, 10.1364/OE.23.012823 Cui, 2015, Ultrahigh sensitivity and layer-dependent sensing performance of phosphorene-based gas sensors, Nat Commun, 6, 8632, 10.1038/ncomms9632 Wang, 2009, Broadband nonlinear optical response of graphene dispersions, Adv Mater, 21, 2430+, 10.1002/adma.200803616 Edward, 2014, Production of few-layer phosphorene by liquid exfoliation of black phosphorus, Chem Commun Bkk, 2021 Hanlon, 2015, Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics, Sci Rep, 6, 8563 Agrawal, 2013 Yasaei, 2015, High-quality black phosphorus atomic layers by liquid-phase exfoliation, Adv Mater, 27, 1887, 10.1002/adma.201405150 Wang, 2013, Pneumatic mold-aided construction of a three-dimensional hydrogel microvascular network in an integrated microfluidics and assay of cancer cell adhesion onto the endothelium, Microfluid Nanofluidics, 15, 519, 10.1007/s10404-013-1172-2 Coleman, 2013, Liquid exfoliation of defect-free graphene, Acc Chem Res, 46, 14, 10.1021/ar300009f Forbes, 1967 Duong, 2015, Ab initio computation of the transition temperature of the charge density wave transition in TiSe2, Phys Rev B, 92, 109, 10.1103/PhysRevB.92.245131 Joensen, 1986, Single-layer MoS/sub 2, Mater Res Bull, 21, 4, 10.1016/0025-5408(86)90011-5 Coleman, 2011, Two-dimensional nanosheets produced by liquid exfoliation of layered materials, Science, 331, 568, 10.1126/science.1194975 Wang, 2015, Ultrafast recovery time and broadband saturable absorption properties of black phosphorus suspension, Appl Phys Lett, 107, 93 Emmanuel, 2014, Improving the efficiency of organic photovoltaics by tuning the work function of graphene oxide hole transporting layers, Nanoscale, 6, 6925, 10.1039/C4NR01539H Conroy, 2014 Eda, 2012, Coherent atomic and electronic heterostructures of single-layer MoS2, ACS Nano, 6, 7311, 10.1021/nn302422x Lj, 2021, Efficacy and safety of chiglitazar, a novel peroxisome proliferator-activated receptor pan-agonist, in patients with type 2 diabetes: a randomized, double-blind, placebo-controlled, phase 3 trial (CMAP), Sci Bull Goki, 2011, Photoluminescence from chemically exfoliated MoS2, Nano Lett Chen, 2016, Scalable clean exfoliation of high‐quality few‐layer black phosphorus for a flexible lithium ion battery, Adv Mater, 28, 510, 10.1002/adma.201503678 Hernandez, 2010, Measurement of multicomponent solubility parameters for graphene facilitates solvent discovery, Langmuir ACS J Surf Colloids, 26, 3208, 10.1021/la903188a Mu, 2015, Black phosphorus-polymer composites for pulsed lasers, Adv Opt Mater, 3, 1447, 10.1002/adom.201500336 Lu, 2015, Broadband nonlinear optical response in multi-layer black phosphorus: an emerging infrared and mid-infrared optical material, Opt Express, 23, 11183, 10.1364/OE.23.011183 Zheng, 2015, Characterization of nonlinear properties of black phosphorus nanoplatelets with femtosecond pulsed Z-scan measurements, Opt Lett, 40, 3480, 10.1364/OL.40.003480 Zhang, 2015, Exfoliated layers of black phosphorus as saturable absorber for ultrafast solid-state laser, Opt Lett, 40, 3691, 10.1364/OL.40.003691 Ma, 2015, Few-layer black phosphorus based saturable absorber mirror for pulsed solid-state lasers, Opt Express, 23, 22643, 10.1364/OE.23.022643 Yang, 2010, Manipulation of droplets in microfluidic systems, Trac Trends Anal Chem, 29, 141, 10.1016/j.trac.2009.11.002 Guo, 2016, From black phosphorus to phosphorene: basic solvent exfoliation, evolution of Raman scattering, and applications to ultrafast photonics, Adv Funct Mater, 25, 6996, 10.1002/adfm.201502902 Yasaei, 2015, Stable and selective humidity sensing using stacked black phosphorus flakes, ACS Nano, 9, 9898, 10.1021/acsnano.5b03325 Luo, 2015, Microfiber-based few-layer black phosphorus saturable absorber for ultra-fast fiber laser, Opt Express, 23, 20030, 10.1364/OE.23.020030 Kong, 2016, Black phosphorus as broadband saturable absorber for pulsed lasers from 1 μm to 2.7 μm wavelength, Laser Phys Lett, 13, 10.1088/1612-2011/13/4/045801 Sun, 2015, A phosphorene–graphene hybrid material as a high-capacity anode for sodium-ion batteries, Nat Nanotechnol, 10, 980, 10.1038/nnano.2015.194 Brent, 2014, Production of few-layer phosphorene by liquid exfoliation of black phosphorus, Chem Commun, 50, 13338, 10.1039/C4CC05752J Woomer, 2015, Phosphorene: synthesis, scale-up, and quantitative optical spectroscopy, ACS Nano, 9, 8869, 10.1021/acsnano.5b02599 Lee, 2016, Black phosphorus (BP) nanodots for potential biomedical applications, Small, 12, 214, 10.1002/smll.201502756 Chen, 2016, Scalable clean exfoliation of high‐quality few‐layer black phosphorus for a flexible lithium ion battery, Adv Mater, 28, 510, 10.1002/adma.201503678 Kang, 2015, Solvent exfoliation of electronic-grade, two-dimensional black phosphorus, ACS Nano, 9, 3596, 10.1021/acsnano.5b01143 Sun, 2015, Ultrasmall black phosphorus quantum dots: synthesis and use as photothermal agents, Angew Chem Int Ed, 54, 11526, 10.1002/anie.201506154 Zhao, 2015, Large-scale, highly efficient, and green liquid-exfoliation of black phosphorus in ionic liquids, ACS Appl Mater Interfaces, 7, 27608, 10.1021/acsami.5b10734 Xu, 2016, Scalable shear-exfoliation of high-quality phosphorene nanoflakes with reliable electrochemical cycleability in nano batteries, 2D Mater, 3, 10.1088/2053-1583/3/2/025005 O'Neill, 2011, Graphene dispersion and exfoliation in low boiling point solvents, J Phys Chem C, 115, 5422, 10.1021/jp110942e Hanlon, 2015, Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics, Nat Commun, 6, 1, 10.1038/ncomms9563 2015, Stable and selective humidity sensing using stacked black phosphorus flakes, ACS Nano, 9, 9898, 10.1021/acsnano.5b03325 Yang, 2015, Atom-thin SnS2–xSex with adjustable compositions by direct liquid exfoliation from single crystals, ACS Nano, 10, 755, 10.1021/acsnano.5b05823 Zalk, 2020, The codevelopment of extraversion and friendships: bonding and behavioral interaction mechanisms in friendship networks, J Pers Soc Psychol O'Neill, 2011, Graphene dispersion and exfoliation in low boiling point solvents, J Phys Chem C, 115, 5422, 10.1021/jp110942e Tiouitchi, 2020, Efficient production of few-layer black phosphorus by liquid-phase exfoliation, Royal Soc Open Sci, 7, 10.1098/rsos.201210 Xiao, 2018, Electrochemical cathode exfoliation of bulky black phosphorus into few-layer phosphorene nanosheets, Electrochem Commun, 89, 10, 10.1016/j.elecom.2018.02.010 Erande, 2016, Humidity sensing and photodetection behavior of electrochemically exfoliated atomically thin-layered black phosphorus nanosheets, ACS Appl Mater Interfaces, 8, 11548, 10.1021/acsami.5b10247 Mayorga-Martinez, 2016, Black phosphorus nanoparticle labels for immunoassays via hydrogen evolution reaction mediation, Anal Chem, 88, 10074, 10.1021/acs.analchem.6b02422 Wang, 2019, Black phosphorous quantum dots sandwiched organic solar cells, Small, 15, 10.1002/smll.201903977 Jia, 2019, Surface coordination modification and electrical properties of few-layer black phosphorus exfoliated by the liquid-phase method, J Alloys Compd, 799, 99, 10.1016/j.jallcom.2019.05.346 Manisha, 2016, Humidity sensing and photodetection behavior of electrochemically exfoliated atomically thin-layered black phosphorus nanosheets, ACS Appl Mater Interfaces, 8, 11548, 10.1021/acsami.5b10247 Erande, 2015, Electrochemically exfoliated black phosphorus nanosheets – prospective field emitters, Eur J Inorg Chem, 2015, 10.1002/ejic.201500145 Mayorga-Martinez, 2016, Black phosphorus nanoparticle labels for immunoassays via hydrogen evolution reaction mediation, Anal Chem, 10.1021/acs.analchem.6b02422 Korotcenkov, 2019, Black phosphorus-new nanostructured material for humidity sensors: achievements and limitations, Sensors, 19, 1010, 10.3390/s19051010 Dhanabalan, 2017, Emerging trends in phosphorene fabrication towards next generation devices, Adv Sci, 4, 1600305, 10.1002/advs.201600305 Zhao, 2017, A novel mild phase‐transition to prepare black phosphorus nanosheets with excellent energy applications, Small, 13, 1602243, 10.1002/smll.201602243 Lu, 2014, Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization, Nano Res, 7, 853, 10.1007/s12274-014-0446-7 Smith, 2016, Growth of 2D black phosphorus film from chemical vapor deposition, Nanotechnology, 27, 215602, 10.1088/0957-4484/27/21/215602 Yang, 2015, Field‐effect transistors based on amorphous black phosphorus ultrathin films by pulsed laser deposition, Adv Mater, 27, 3748, 10.1002/adma.201500990 Novoselov, 2005, Two-dimensional gas of massless Dirac fermions in graphene, Nature, 438, 197, 10.1038/nature04233 Osgood, 2016, Transition metal (Fe, Co, Ni, and Mn) oxides for oxygen reduction and evolution bifunctional catalysts in alkaline media, Nano Today, 11, 601, 10.1016/j.nantod.2016.09.001 Lu, 2014, Nano Res, 7, 853, 10.1007/s12274-014-0446-7 Jia, 2015, ACS Nano, 9, 8729, 10.1021/acsnano.5b04265 Jia, 2015, ACS Nano, 9, 8729, 10.1021/acsnano.5b04265 Li, 2014, Nat Nanotechnol, 9, 372, 10.1038/nnano.2014.35 Zu, 2019, Electrochemical prepared phosphorene as a cathode for supercapacitors, J Alloys Compd, 770, 26, 10.1016/j.jallcom.2018.07.265 Zhang, 2016, Two-step heating synthesis of sub-3 millimeter-sized orthorhombic black phosphorus single crystal by chemical vapor transport reaction method, Sci China Mater, 59, 122, 10.1007/s40843-016-0122-1 Lu, 2014, Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization, 纳米研究:英文版. Favron, 2015, Photooxidation and quantum confinement effects in exfoliated black phosphorus, Nat Mater, 14, 826, 10.1038/nmat4299 Luo, 2014, Temporal and thermal stability of Al 2 O 3-passivated phosphorene MOSFETs, IEEE Electron Device Lett, 35, 1314, 10.1109/LED.2014.2362841 Choi, 2017, Low-voltage 2D material field-effect transistors enabled by ion gel capacitive coupling, Chem Mater, 29, 4008, 10.1021/acs.chemmater.7b00573 Xu, 2017, Odd-integer quantum Hall states and giant spin susceptibility in p-type few-layer WSe 2, Phys Rev Lett, 118, 10.1103/PhysRevLett.118.067702 Fortin-Desche^nes, 2016, Dynamics and mechanisms of exfoliated black phosphorus sublimation, J Phys Chem Lett, 7, 1667, 10.1021/acs.jpclett.6b00584 Lin, 2019, Emerging opportunities for black phosphorus in energy applications, Mater Today Energy, 12, 1, 10.1016/j.mtener.2018.12.004 Luo, 2017, Thermal sublimation: a scalable and controllable thinning method for the fabrication of few-layer black phosphorus, Nanotechnology, 28, 285301, 10.1088/1361-6528/aa76ae Pei, 2016, Producing air-stable monolayers of phosphorene and their defect engineering, Nat Commun, 7, 1, 10.1038/ncomms10450 Dickerson, 2018, Phosphorus oxide gate dielectric for black phosphorus field effect transistors, Appl Phys Lett, 112, 173101, 10.1063/1.5011424 Zhao, 2018, Facile synthesis of SnO2 hierarchical porous nanosheets from graphene oxide sacrificial scaffolds for high-performance gas sensors, Sensor Actuator B Chem, 258, 492, 10.1016/j.snb.2017.11.167 Wu, 2007, Improving blood compatibility of intravascular oxygen sensors via catalytic decomposition of S-nitrosothiols to generate nitric oxide in situ, Sensor Actuator B Chem, 121, 36, 10.1016/j.snb.2006.09.025 Varghese, 2015, Two-dimensional materials for sensing: graphene and beyond, Electronics, 4, 651, 10.3390/electronics4030651 Nomani, 2010, Highly sensitive and selective detection of NO2 using epitaxial graphene on 6H-SiC, Sensor Actuator B Chem, 150, 301, 10.1016/j.snb.2010.06.069 Xilan, 2009 Perkins, 2013, Chemical vapor sensing with monolayer MoS2, Nano Lett, 13, 668, 10.1021/nl3043079 Guo, 2010, Increased expression of calcium-sensing receptors induced by ox-LDL amplifies apoptosis of cardiomyocytes during simulated ischaemia–reperfusion, Clin Exp Pharmacol Physiol, 10.1111/j.1440-1681.2010.05345.x Late, 2014, Single-layer MoSe2 based NH3 gas sensor, Appl Phys Lett, 105, 25, 10.1063/1.4903358 Lei, 2016 Suvansinpan, 2016, Substitutionally doped phosphorene: electronic properties and gas sensing, Nanotechnology, 27, 10.1088/0957-4484/27/6/065708 Kou, 2014, Phosphorene as a superior gas sensor: selective adsorption and distinct I-V response, J Phys Chem Lett, 5, 10.1021/jz501188k Tang, 2021, A new sensing material design based on chemically passivated phosphorene/porous two-dimensional polymer: highly sensitive and selective detection of NO2, Sensor Actuator B Chem, 329, 129233, 10.1016/j.snb.2020.129233 Mayorga-Martinez, 2016, Layered black phosphorus as a selective vapor sensor, Angew Chem, 54, 14317, 10.1002/anie.201505015 Late, 2013, Sensing behavior of atomically thin-layered MoS2 transistors, ACS Nano, 7, 4879, 10.1021/nn400026u Cho, 2016, Superior chemical sensing performance of black phosphorus: comparison with MoS2 and graphene, Adv Mater, 28, 7020, 10.1002/adma.201601167 Donarelli, 2016, Exfoliated black phosphorus gas sensing properties at room temperature, 2D Mater, 3, 10.1088/2053-1583/3/2/025002 Lee, 2017, Suspended black phosphorus nanosheet gas sensors, Sensor Actuator B Chem, 250, 569, 10.1016/j.snb.2017.04.176 Feng, 2012, Temperature reconstruction from tree-ring maximum latewood density of Qinghai spruce in middle Hexi Corridor, China, Theor Appl Climatol, 107, 633, 10.1007/s00704-011-0512-y Li, 2007, Application of steel thin film electrical resistance sensor for in situ corrosion monitoring, Sensor Actuator B Chem, 120, 368, 10.1016/j.snb.2006.02.029 Monthioux, 2014 Abbas, 2015, Black phosphorus gas sensors, ACS Nano, 9, 5618, 10.1021/acsnano.5b01961 Mayorga‐Martinez, 2015, Layered black phosphorus as a selective vapor sensor, Angew Chem Int Ed, 54, 14317, 10.1002/anie.201505015 Feng, 2016, Chemical sensing by band modulation of a black phosphorus/molybdenum diselenide van der Waals hetero-structure, 2D Mater, 3, 10.1088/2053-1583/3/3/035021 Favron, 2015, Photooxidation and quantum confinement effects in exfoliated black phosphorus, Nat Mater, 14, 826, 10.1038/nmat4299 Kerelsky, 2017, Absence of a band gap at the interface of a metal and highly doped monolayer MoS2, Nano Lett, 10.1021/acs.nanolett.7b01986 Late, 2016, Liquid exfoliation of black phosphorus nanosheets and its application as humidity sensor, Microporous Mesoporous Mater: Off J Int Zeolite Assoc, 10.1016/j.micromeso.2016.01.031 Miao, Jinshui, Zhang, Suoming, Junghyo, Yeom, et al. Air-stable humidity sensor using few-layer black phosphorus. Poya, 2015, Stable and selective humidity sensing using stacked black phosphorus flakes, ACS Nano, 9, 9898, 10.1021/acsnano.5b03325 Miao, 2017, Air-stable humidity sensor using few-layer black phosphorus, ACS Appl Mater Interfaces, 9, 10019, 10.1021/acsami.7b01833 Zhu, 2016, Ultrafast preparation of black phosphorus quantum dots for efficient humidity sensing, Chem Euro J, 22, 7357, 10.1002/chem.201600719 Jiang, 2006, Variable frequency microwave synthesis of silver nanoparticles, J Nanoparticle Res, 8, 117, 10.1007/s11051-005-7522-6 Yao, 2017, Novel QCM humidity sensors using stacked black phosphorus nanosheets as sensing film, Sensor Actuator B Chem, 244, 259, 10.1016/j.snb.2017.01.010 Late, 2016, Liquid exfoliation of black phosphorus nanosheets and its application as humidity sensor, Microporous Mesoporous Mater, 225, 494, 10.1016/j.micromeso.2016.01.031 Chen, 2017, SIW resonator humidity sensor based on layered black phosphorus, Electron Lett, 53, 249, 10.1049/el.2016.3844 Wild, 2020, Quantifying the covalent functionalization of black phosphorus, Angew Chem Int Ed, 59, 20230, 10.1002/anie.202008646 Phan, 2017, Black P/graphene hybrid: a fast response humidity sensor with good reversibility and stability, Sci Rep, 7, 1, 10.1038/s41598-017-10848-3 Yao, 2017, Novel QCM humidity sensors using stacked black phosphorus nanosheets as sensing film, Sensor Actuator B Chem, 244, 259, 10.1016/j.snb.2017.01.010 Walia, 2016, Defining the role of humidity in the ambient degradation of few-layer black phosphorus, 2D Mater, 4, 10.1088/2053-1583/4/1/015025 He, 2018, Fully printed high performance humidity sensors based on two-dimensional materials, Nanoscale, 10, 5599, 10.1039/C7NR08115D Chen, 2018, A miniaturized evanescent mode HMSIW humidity sensor, Int J Microwave Wireless Technol, 10, 87, 10.1017/S175907871700126X Avouri, 2008 Zhao, 2016 Wenjing, 2013, High-Gain phototransistors based on a CVD MoS2 monolayer, Adv Mater Chang, 2014, Monolayer MoSe2 grown by chemical vapor deposition for fast photodetection, ACS Nano, 8, 8582, 10.1021/nn503287m Abderrahmane, 2014, High photosensitivity few-layered MoSe2 back-gated field-effect phototransistors, Nanotechnology, 25, 365202, 10.1088/0957-4484/25/36/365202 Elías, 2013, Controlled synthesis and transfer of large-area WS2 sheets: from single layer to few layers, ACS Nano, 10.1021/nn400971k Zhang, 2014, Role of metal contacts in high-performance phototransistors based on WSe2 monolayers, ACS Nano, 8, 8653, 10.1021/nn503521c Buscema, 2014, Fast and broadband photoresponse of few-layer black phosphorus field-effect transistors, Nano Lett, 14, 3347, 10.1021/nl5008085 Buscema, 2014, Fast and broadband photoresponse of few-layer black phosphorus field-effect transistors, Nano Lett, 14, 3347, 10.1021/nl5008085 Wu, 2015, Colossal ultraviolet photoresponsivity of few-layer black phosphorus, ACS Nano, 9, 8070, 10.1021/acsnano.5b01922 2015, Colossal ultraviolet photoresponsivity of few-layer black phosphorus, ACS Nano, 9, 8070, 10.1021/acsnano.5b01922 Guo, 2016, Black phosphorus mid-infrared photodetectors with high gain, Nano Lett, 16, 4648, 10.1021/acs.nanolett.6b01977 Leonardo, 2015, Black phosphorus terahertz photodetectors, Adv Mater, 27, 5567, 10.1002/adma.201502052 2016, Efficient Terahertz detection in black-phosphorus nano-transistors with selective and controllable plasma-wave, bolometric and thermoelectric response, Sci Rep, 6, 20474, 10.1038/srep20474 Viti, 2016, Heterostructured hBN‐BP‐hBN nanodetectors at terahertz frequencies, Adv Mater, 10.1002/adma.201601736 Buscema M, Groenendijk DJ, Steele GA, Zant H, Castellanos-Gomez A. Photovoltaic effect in few-layer black phosphorus PN junctions defined by local electrostatic gating. Nat Commun. Deng, 2014, Black phosphorus–monolayer MoS <sub/>2 van der Waals heterojunction p–n diode, ACS Nano, 8, 8292, 10.1021/nn5027388 Miao, 2016, Black phosphorus Schottky diodes: channel Length scaling and application as photodetectors, Adv Electronic Mater, 2, 1500346, 10.1002/aelm.201500346 Hong, 2014, Polarized photocurrent response in black phosphorus field-effect transistors, Nanoscale, 6, 8978, 10.1039/C4NR02164A Hongtao, 2015, Polarization-sensitive broadband photodetector using a black phosphorus vertical p-n junction, Nat Nanotechnol Yuan, 2015, Polarization-sensitive broadband photodetector using a black phosphorus vertical p–n junction, Nat Nanotechnol, 10, 707, 10.1038/nnano.2015.112 Youngblood, 2015, Waveguide-integrated black phosphorus photodetector with high responsivity and low dark current, Nat Photonics, 9, 247, 10.1038/nphoton.2015.23 Chen, 2017, Three-dimensional integration of black phosphorus photodetector with silicon photonics and nanoplasmonics, Nano Lett, 17, 985, 10.1021/acs.nanolett.6b04332 Youngblood, 2015, Waveguide-integrated black phosphorus photodetector with high responsivity and low dark current, Nat Photonics, 9, 331, 10.1038/nphoton.2015.23 Chen, 2017, Three-dimensional integration of black phosphorus photodetector with silicon photonics and nanoplasmonics, Nano Lett, 17, 985, 10.1021/acs.nanolett.6b04332 Sultana, 2009, Tying biological activity to changes in sea spray aerosol chemical composition via single particle analyses, EURASIP J Wirel Commun Netw, 2009, 1 Wang, 2013, New RIC and myeloablative regimen of Bu(9.6mg/kg)Flu, suitable for old or intolerant patients with malignant diseases, 骨髓移植术. Liu, 2017, Gate-tunable giant Stark effect in few-layer black phosphorus, Nano Lett Na, 2017, Air-stable few-layer black phosphorus phototransistor for near-infrared detection, Nanotechnology, 28, 10.1088/1361-6528/aa55e4 Ren, 2017, Environmentally robust black phosphorus nanosheets in solution: application for self-powered photodetector, Adv Funct Mater, 27, 1606834, 10.1002/adfm.201606834 Chen, 2019, In situ preparation of a CsPbBr3/black phosphorus heterostructure with an optimized interface and photodetector application, Nanoscale, 11, 16852, 10.1039/C9NR06488E Deng, 2014, Black phosphorus–monolayer MoS2 van der Waals heterojunction p–n diode, ACS Nano, 8, 8292, 10.1021/nn5027388 Engel, 2014, Black phosphorus photodetector for multispectral, high-resolution imaging, Nano Lett, 14, 6414, 10.1021/nl502928y Liu, 2015, Thickness-dependent Raman spectra, transport properties and infrared photoresponse of few-layer black phosphorus, J Mater Chem C, 3, 10974, 10.1039/C5TC01809A Viti, 2015, Black phosphorus terahertz photodetectors, Adv Mater, 27, 5567, 10.1002/adma.201502052 Guo, 2016, Black phosphorus mid-infrared photodetectors with high gain, Nano Lett, 16, 4648, 10.1021/acs.nanolett.6b01977 Xiang, 2015, Surface transfer doping induced effective modulation on ambipolar characteristics of few-layer black phosphorus, Nat Commun, 6, 1, 10.1038/ncomms7485 Xu, 2016, Selenium‐doped black phosphorus for high‐responsivity 2D photodetectors, Small, 12, 5000, 10.1002/smll.201600692 Holzinger, 2014, Nanomaterials for biosensing applications: a review, Front Chem, 2, 10.3389/fchem.2014.00063 Noor, 2014, Silicon nanowires as field-effect transducers for biosensor development: a review, Anal Chim Acta, 10.1016/j.aca.2014.03.016 Bonanni, 2012, Graphene for impedimetric biosensing, Trac Trends Anal Chem, 37, 12, 10.1016/j.trac.2012.02.011 2015, The cytotoxicity of layered black phosphorus, Chemistry, 21 Guo, 2015 Wang, 2015, Voltammetry of layered black phosphorus: electrochemistry of multilayer phosphorene, ChemElectroChem, 2 Shancheng, Wang, Bojun, Zhulan, Dong, Junzhuan. Supercritical carbon dioxide-assisted rapid synthesis of few-layer black phosphorus for hydrogen peroxide sensing. 2016, Nanostructured aptamer-functionalized black phosphorus sensing platform for label-free detection of myoglobin, a cardiovascular disease biomarker, ACS Appl Mater Interfaces, 22860 Sarswat, 2017, Fabrication and response of alpha-hydroxybutyrate sensors for rapid assessment of cardiometabolic disease risk, Biosens Bioelectron, 89, 334, 10.1016/j.bios.2016.07.019 Ying, 2017, Black phosphorus nanoparticles as a novel fluorescent sensing platform for nucleic acid detection, Mater. Chem. Front., 1 Kumar, 2016, Nanostructured aptamer-functionalized black phosphorus sensing platform for label-free detection of myoglobin, a cardiovascular disease biomarker, ACS Appl Mater Interfaces, 8, 22860, 10.1021/acsami.6b06488 Yew, 2017, Black phosphorus nanoparticles as a novel fluorescent sensing platform for nucleic acid detection, Mater. Chem. Front., 1, 1130, 10.1039/C6QM00341A Chen, 2017, Field-effect transistor biosensors with two-dimensional black phosphorus nanosheets, Biosens Bioelectron, 89, 505, 10.1016/j.bios.2016.03.059 Liu, 2017, Freestanding transparent metallic network based ultrathin, foldable and designable supercapacitors, Energy Environ Sci, 10, 2534, 10.1039/C7EE02390A Wei, 2017, Fluorescent black phosphorus quantum dots as label-free sensing probes for evaluation of acetylcholinesterase activity, Sensor Actuator B Chem, 250 Chen, 2017, Field-effect transistor biosensors with two-dimensional black phosphorus nanosheets, Biosens Bioelectron, 89, 505, 10.1016/j.bios.2016.03.059 Gao, 2013, Magnetic bead-based reverse colorimetric immunoassay strategy for sensing biomolecules, Anal Chem, 85, 6945, 10.1021/ac401433p Lai, 2017, Mg(OMe)2 promoted allylic isomerization of gamma-hydroxy-alpha,beta-alkenoic esters to synthesize gamma-ketone esters, Org Biomol Chem, 15, 10.1039/C7OB00131B Yan, 2016, Supercritical carbon dioxide-assisted rapid synthesis of few-layer black phosphorus for hydrogen peroxide sensing, Biosens Bioelectron, 80, 34, 10.1016/j.bios.2016.01.043 Gu, 2017, Fluorescent black phosphorus quantum dots as label-free sensing probes for evaluation of acetylcholinesterase activity, Sensor Actuator B Chem, 250, 601, 10.1016/j.snb.2017.05.017 R, 2015 Xie, 2008, Solid phase extraction of lead (II), copper (II), cadmium (II) and nickel (II) using gallic acid-modified silica gel prior to determination by flame atomic absorption spectrometry, Talanta, 74, 836, 10.1016/j.talanta.2007.07.018 Wang, 2012, Cover picture: biomimetic graphene surfaces with superhydrophobicity and iridescence, Chem Asian J, 7, 245, 10.1002/asia.201290000 Raj, 2016, Surface Plasmon Resonance based fiber optic sensor for mercury detection using gold nanoparticles PVA hybrid, Opt Commun, 367, 102, 10.1016/j.optcom.2016.01.027 2015, Air-stable black phosphorus devices for ion sensing, ACS Appl Mater Interfaces, 7 Yuan R, Yuan X, Chai Y. Improved potentiometric response of solid-contact lanthanum (III) selective electrode. Li, 2017, Ultra-sensitive suspended atomically thin-layered black phosphorus mercury sensors, Biosens Bioelectron, 98, 68, 10.1016/j.bios.2017.06.027 Liu, 2016, An efficient quinoline-based fluorescence sensor for zinc(II) and its application in live-cell imaging, Sensor Actuator B Chem, 234, 616, 10.1016/j.snb.2016.04.175 Lu, 2012, Economical, green synthesis of fluorescent carbon nanoparticles and their use as probes for sensitive and selective detection of mercury(II) ions, Anal Chem, 84, 5351, 10.1021/ac3007939 Li, 2015, Air-stable black phosphorus devices for ion sensing, ACS Appl Mater Interfaces, 7, 24396, 10.1021/acsami.5b07712 Rantanen, 2013 Yang, 2018, Recent advances in phosphorene as a sensing material, Nano Today, 20, 13, 10.1016/j.nantod.2018.04.001 Gu, 2017, Black phosphorus quantum dots as the ratiometric fluorescence probe for trace mercury ion detection based on inner filter effect, ACS Sens, 2, 576, 10.1021/acssensors.7b00102 Wang, 2018, Black phosphorus-based field effect transistor devices for Ag ions detection, Chin Phys B, 27 Robertson AW, Allen CS, Wu YA, He K, Olivier J, Neethling J, et al. Spatial control of defect creation in graphene at the nanoscale. Nat Commun. Wang, 2015, Native point defects in few-layer phosphorene, Phys Rev B, 91 Ziletti, 2015, Oxygen defects in phosphorene, Phys Rev Lett, 114, 10.1103/PhysRevLett.114.046801 Guo, 2016, Design, synthesis and biological evaluation of novel tetrahydroprotoberberine derivatives (THPBs) as selective α1a-adrenoceptor antagonists, J Med Chem, 9489, 10.1021/acs.jmedchem.6b01217 Jwx, 2021, Large reversible magnetic entropy change of R 3 Ni 6 Al 2 (R=Dy, Ho and Er) compounds, J Alloys Compd Mahabal, 2016, Sensing characteristics of phosphorene monolayers toward PH3 and AsH3 gases upon the introduction of vacancy defects, J Phys Chem C, 10.1021/acs.jpcc.6b06791 Ran, 2017, Strongly interactive 0D/2D hetero-structure of a Zn x Cd 1− x S nano-particle decorated phosphorene nano-sheet for enhanced visible-light photocatalytic H 2 production, Chem Commun, 53, 9882, 10.1039/C7CC05466A Zhou, 2016, Light‐induced ambient degradation of few‐layer black phosphorus: mechanism and protection, Angew Chem Int Ed, 55, 11437, 10.1002/anie.201605168 Pei, 2016, Producing air-stable monolayers of phosphorene and their defect engineering, Nat Commun, 7, 10.1038/ncomms10450 Pu, 2017, Field-effect transistor biosensors with two-dimensional black phosphorus nanosheets, Biosens Bioelectron: Int J Professional Involved Res Technol Appl Biosensers Related Dev Gong, 2014, Facile in situ synthesis of nickel/cellulose nanocomposites: mechanisms, properties and perspectives, Cellulose, 21, 4359, 10.1007/s10570-014-0453-6 Guo, 2017, Metal-ion-modified black phosphorus with enhanced stability and transistor performance, Adv Mater, 29, 10.1002/adma.201703811