Recent advances in understanding secondary organic aerosol: Implications for global climate forcing

Reviews of Geophysics - Tập 55 Số 2 - Trang 509-559 - 2017
Manish Shrivastava1, Christopher D. Cappa2, Jiwen Fan1, A. H. Goldstein3, Alex Guenther4, J. L. Jiménez5, Alexander Laskin6, Scot T. Martin7, N. L. Ng8, Tuukka Petäjä9, Jeffrey R. Pierce10, Philip J. Rasch1, Pontus Roldin11, John H. Seinfeld12, B. Schmid1, James N. Smith4, Joel A. Thornton13, Rainer Volkamer5, Jian Wang6, Douglas R. Worsnop14, R. A. Zaveri1, Alla Zelenyuk1, Qi Zhang15
1Pacific Northwest National Laboratory, Richland, Washington, USA
2Department of Civil and Environmental Engineering, University of California Davis, California, USA
3Department of Environmental Science, Policy and Management and Department of Civil and Environmental Engineering, University of California, Berkeley, California, USA
4Department of Earth System Science, University of California, Irvine, California, USA
5Cooperative Institute for Research in Environmental Sciences and Department of Chemistry and Biochemistry, University of Colorado Boulder, Boulder, Colorado, USA
6Brookhaven National Laboratory, Upton, New York USA
7School of Engineering and Applied Sciences and Department of Earth and Planetary Sciences, Harvard University, Cambridge, Massachusetts, USA
8School of Chemical and Biomolecular Engineering and School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, Georgia, USA
9Department of Physics, University of Helsinki, Helsinki, Finland
10Department of Atmospheric Science, Colorado State University, Fort Collins, Colorado, USA
11Department of Physics, Lund University, Lund, Sweden
12Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California, USA
13Department of Atmospheric sciences, University of Washington, Seattle, Washington, USA
14Aerodyne Research, Inc., Billerica, Massachusetts, USA
15Department of Environmental Toxicology, University of California, Davis, California, USA

Tóm tắt

AbstractAnthropogenic emissions and land use changes have modified atmospheric aerosol concentrations and size distributions over time. Understanding preindustrial conditions and changes in organic aerosol due to anthropogenic activities is important because these features (1) influence estimates of aerosol radiative forcing and (2) can confound estimates of the historical response of climate to increases in greenhouse gases. Secondary organic aerosol (SOA), formed in the atmosphere by oxidation of organic gases, represents a major fraction of global submicron‐sized atmospheric organic aerosol. Over the past decade, significant advances in understanding SOA properties and formation mechanisms have occurred through measurements, yet current climate models typically do not comprehensively include all important processes. This review summarizes some of the important developments during the past decade in understanding SOA formation. We highlight the importance of some processes that influence the growth of SOA particles to sizes relevant for clouds and radiative forcing, including formation of extremely low volatility organics in the gas phase, acid‐catalyzed multiphase chemistry of isoprene epoxydiols, particle‐phase oligomerization, and physical properties such as volatility and viscosity. Several SOA processes highlighted in this review are complex and interdependent and have nonlinear effects on the properties, formation, and evolution of SOA. Current global models neglect this complexity and nonlinearity and thus are less likely to accurately predict the climate forcing of SOA and project future climate sensitivity to greenhouse gases. Efforts are also needed to rank the most influential processes and nonlinear process‐related interactions, so that these processes can be accurately represented in atmospheric chemistry‐climate models.

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Reviews of Geophysics

Tập 55 Số 2

509-559

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