Recent advances in graphene based polymer composites

Progress in Polymer Science - Tập 35 - Trang 1350-1375 - 2010
Tapas Kuilla1, Sambhu Bhadra2, Dahu Yao1, Nam Hoon Kim3, Saswata Bose4, Joong Hee Lee1,4
1BIN Fusion Research Team, Department of Polymer & Nano Engineering, Chonbuk National University, Jeonju, Jeonbuk, 561-756, Republic of Korea
2School of Polymers and High Performance Materials, The University of Southern Mississippi, 118 College Drive #10076, Hattiesburg, MS 39406-0001, USA
3Department of Hydrogen and Fuel Cell Engineering, Chonbuk National University, Jeonju, Jeonbuk, 561-756, Republic of Korea
4Department of BIN Fusion Technology, Chonbuk National University, Jeonju, Jeonbuk 561-756, Republic of Korea

Tài liệu tham khảo

David, 2005, Synthesis and optical properties of silver nanoparticles and arrays, Chem Phys Chem, 6, 1221, 10.1002/cphc.200500113 Stankovich, 2006, Graphene-based composite materials, Nature, 442, 282, 10.1038/nature04969 Okada A, Kawasumi M, Usuki A, Kojima Y, Kurauchi T, Kamigaito O. Synthesis and properties of nylon-6/clay hybrids. In: Schaefer DW, Mark JE, editors. Polymer based molecular composites. vol. 171. MRS symposium proceedings. Pittsburgh PA: Materials Research Society; 1990. p. 45–50. Godovsky, 2000, Device applications of polymer-nanocomposites, Adv Polym Sci, 153, 163, 10.1007/3-540-46414-X_4 Alexandre, 2000, Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials, Mater Sci Eng:R, 28, 1, 10.1016/S0927-796X(00)00012-7 Ray, 2003, Polymer/layered silicate nanocomposites: a review from preparation to processing, Prog Polym Sci, 28, 1539, 10.1016/j.progpolymsci.2003.08.002 Zhiaho, 2006, Partial delamination of the organo-monmorillonite with surfactant containing hydroxyl groups in maleated poly(propylene carbonate), Polymer, 47, 8548, 10.1016/j.polymer.2006.09.041 Peng Li, 2009, Electroresponsive property of novel poly(acrylate-acryloyloxyethyl trimethyl ammoniumchloride)/clay nanocomposite hydrogels, Adv Mater Res, 79, 2263 Peng Li, 2009, Improved mechanical and swelling behavior of the composite hydrogels prepared by ionic monomer and acid-activated laponite, Appl Surf Sci, 46, 414 Leroux, 2001, Polymer intercalated layered double hydroxide: a new emerging class of nanocomposites, Chem Mater, 13, 3507, 10.1021/cm0110268 Kuila, 2008, Thermoplastic polyolefin based polymer-blend-layered double hydroxide nanocomposites, Compos Sci Technol, 68, 3234, 10.1016/j.compscitech.2008.08.003 Giannelis, 1996, Polymer layered silicate nanocomposites, Adv Mater, 8, 29, 10.1002/adma.19960080104 Giannelis, 1999, Polymer-silicate nanocomposites: model systems for confined polymers and polymer brushes, Adv Polym Sci, 138, 107, 10.1007/3-540-69711-X_3 Zanetti, 2001, Thermal behaviour of poly(propylene) layered silicate nanocomposites, Macromol Rapid Commun, 22, 176, 10.1002/1521-3927(200102)22:3<176::AID-MARC176>3.0.CO;2-C Pavlidou, 2008, A review on polymer layered silicate nanocomposites, Prog Polym Sci, 33, 1119, 10.1016/j.progpolymsci.2008.07.008 Acharya, 2007, Synthesis of partially exfoliated EPDM/LDH nanocomposites by solution intercalation: structural characterization and properties, Compos Sci Technol, 67, 2807, 10.1016/j.compscitech.2007.01.030 Costa, 2006, Morphology and fracture behaviour of polyethylene/Mg-Al layered double hydroxide (LDH) nanocomposites, Eur Polym J, 42, 2140, 10.1016/j.eurpolymj.2006.04.005 Garcia, 2009, Electrical conductivity of montmorillonite as a function of relative humidity: La-montmorillonite, Clay Miner, 44, 81, 10.1180/claymin.2009.044.1.81 Uddin, 2008, Clays, nanoclays, and montmorillonite minerals, Metall Mater Trans A, 39, 2805, 10.1007/s11661-008-9603-5 Bao, 2008, Preparation and proton conductivity of poly(vinylidene fluoride)/layered double hydroxide nanocomposite gel electrolytes, J Mater Sci, 43, 390, 10.1007/s10853-007-2100-1 Li, 2009, Positive temperature coefficient behavior of HDPE/EVA blends filled with carbon black, Adv Mater Res, 79, 2267, 10.4028/www.scientific.net/AMR.79-82.2267 Jeevananda, 2009, Investigation of multi-walled carbon nanotube reinforced high-density polyethylene/carbon black nanocomposites using electrical DSC and positron lifetime spectroscopy techniques, Polym Int, 58, 755, 10.1002/pi.2591 Li, 2009, Positive temperature coefficient characteristic and structure of graphite nanofibers reinforced high-density polyethylene/carbon black nanocomposites, Compos Part B, 40, 218, 10.1016/j.compositesb.2008.11.002 Renukappa, 2009, Dielectric properties of carbon black: SBR composites, J Mater Sci: Mater Electron, 20, 648 Li, 2008, Positive temperature coefficient behavior of the graphite nanofibre and carbon black filled high-density polyethylene hybrid composites, Adv Mater Res, 47, 226, 10.4028/www.scientific.net/AMR.47-50.226 Zhang, 2007, Electrical conductivity of epoxy resin-carbon black-silica nanocomposites: effect of silica concentration and analysis of polymer curing reaction by FTIR, Scripta Mater, 57, 949, 10.1016/j.scriptamat.2007.07.030 Chrissafis, 2007, Characterization and thermal degradation mechanism of isotactic polypropylene/carbon black nanocomposites, Thermochim Acta, 465, 6, 10.1016/j.tca.2007.08.007 Wang, 2008, Preparation of polymer/oriented graphite nanosheet composite by electric field-inducement, Compos Sci Technol, 68, 238, 10.1016/j.compscitech.2007.04.012 Yu, 2007, Graphite nanoplatelet-epoxy composite thermal interface materials, J Phys Chem C, 111, 7565, 10.1021/jp071761s Debelak, 2007, Use of exfoliated graphite filler to enhance polymer physical properties, Carbon, 45, 1727, 10.1016/j.carbon.2007.05.010 Chen, 2006, Preparation and structure analysis of carbon/carbon composite made from phenolic resin impregnation into exfoliated graphite, J Phys Chem Solids, 67, 1141, 10.1016/j.jpcs.2006.01.087 Mazinani, 2009, Morphology, structure and properties of conductive PS/CNT nanocomposite electrospun mat, Polymer, 50, 3329, 10.1016/j.polymer.2009.04.070 Geng, 2008, Effects of surfactant treatment on mechanical and electrical properties of CNT/epoxy nanocomposites, Compos Part A, 39, 1876, 10.1016/j.compositesa.2008.09.009 Liao, 2008, Preparation and properties of carbon nanotube/polypropylene nanocomposite bipolar plates for polymer electrolyte membrane fuel cells, J Power Sources, 185, 1225, 10.1016/j.jpowsour.2008.06.097 Spitalsky, 2010, Carbon nanotube–polymer composites: chemistry, processing, mechanical and electrical properties, Prog Polym Sci, 35, 357, 10.1016/j.progpolymsci.2009.09.003 Park, 2009, Effects of surface modification on the dispersion and electrical conductivity of carbon nanotube/polyaniline composites, Script Mater, 60, 551, 10.1016/j.scriptamat.2008.12.005 Jeevananda, 2008, Synthesis and characterization of polyaniline-multiwalled carbon nanotube nanocomposites in the presence of sodium dodecyl sulfate, Polym Adv Technol, 19, 1, 10.1002/pat.1191 Jeevananda, 2008, Polyaniline-multiwalled carbon nanotubes composites: chracterization by WAXS and TGA, J Appl Polym Sci, 108, 25 Hong, 2007, Effects of oxidative conditions on properties of multi-wall carbon nanotubes of polymer nanocomposites, Compos Sci Technol, 67, 1027, 10.1016/j.compscitech.2006.06.003 Kim, 2006, Effects of the addition of multi-walled carbon nanotubes on the positive temperature coefficient characteristics of carbon-black-filled high density polyethylene nanocomposites, Scripta Mater, 55, 1119, 10.1016/j.scriptamat.2006.08.051 Khanna, 2009, Carbon nanofiber polymer composites: evaluation of life cycle energy use, Environ Sci Technol, 43, 2078, 10.1021/es802101x Tibbetts, 2007, A review of the fabrication and properties of vapor-grown carbon nanofiber/polymer composites, Compos Sci Technol, 67, 1709, 10.1016/j.compscitech.2006.06.015 Chipara, 2008, TGA analysis of polypropylene-carbon nanofibers composites, Polym Degrad Stab, 93, 871, 10.1016/j.polymdegradstab.2008.01.001 Ansari, 2009, Functionalized graphene sheet-poly(vinylidene fluoride) conductive nanocomposites, J Polym Sci Part B Polym Phys, 47, 888, 10.1002/polb.21695 Ramanathan, 2008, Functionalized graphene sheets for polymer nanocomposites, Nat Nanotechnol, 3, 327, 10.1038/nnano.2008.96 Lee, 2009, Properties of waterborne polyurethane/functionalized graphene sheet nanocomposites prepared by an in situ method, Macromol Chem Phys, 210, 1247, 10.1002/macp.200900157 Xu, 2009, A hybrid material of graphene and poly(3,4-ethyldioxythiophene) with high conductivity, flexibility, and transparency, Nano Res, 2, 343, 10.1007/s12274-009-9032-9 Liu, 2008, One step ionic-liquid-assisted electrochemical synthesis of ionic-liquid-functionalized graphene sheets directly from graphene, Adv Funct Mater, 18, 1518, 10.1002/adfm.200700797 Kotov, 2006, Carbon sheet solutions, Nature, 442, 254, 10.1038/442254a Geim, 2007, Graphene: exploring carbon flatland, Phys Today, 60, 35, 10.1063/1.2774096 Si, 2008, Synthesis of water soluble graphene, Nano Lett, 8, 1679, 10.1021/nl080604h Dreyer, 2010, The chemistry of graphene oxide, Chem Soc Rev, 39, 228, 10.1039/B917103G Wang, 2008, Facile synthesis and characterization of graphene nanosheets, J Phys Chem C, 112, 8192, 10.1021/jp710931h Wang, 2009, Synthesis and characterization of hydrophilic and organophilic graphene nanosheets, Carbon, 47, 1359, 10.1016/j.carbon.2009.01.027 Li, 2008, Chemically derived, ultrasmooth graphene nanoribon semiconductor, Science, 319, 1229, 10.1126/science.1150878 Blake, 2008, Graphene-based liquid crystal device, Nano Lett, 8, 1704, 10.1021/nl080649i Allen, 2010, Honeycomb carbon: a review of graphene, Chem Rev, 110, 132, 10.1021/cr900070d Sundaram, 2008, Electrochemical modification of graphene, Adv Mater, 20, 3050, 10.1002/adma.200800198 Cui, 2009, Synthesis and separation of mellitic acid and graphite oxide colloid through electrochemical oxidation of graphite in deionized water, Electrochem Commun, 11, 409, 10.1016/j.elecom.2008.12.003 Matsuo, 1999, Selective intercalation of aromatic molecules into alkyltrimethylammonium ion-intercalated graphite oxide, Chem Lett, 28, 1109, 10.1246/cl.1999.1109 Cassagneau, 1998, High density rechargeable lithium-ion batteries self-assembled from graphite oxide nanoplatelets and polyelectrolytes, Adv Mater, 10, 877, 10.1002/(SICI)1521-4095(199808)10:11<877::AID-ADMA877>3.0.CO;2-1 Navarro, 2007, Electronic transport properties of individual chemically reduced graphene oxide Sheets, Nano Lett, 7, 3499, 10.1021/nl072090c Hirata, 2005, Thin-film particles of graphite oxide. 2: Preliminary studies for internal micro fabrication of single particle and carbonaceous electronic circuits, Carbon, 43, 503, 10.1016/j.carbon.2004.10.009 Kotov, 1996, Ultrathin graphite oxide-polyelectrolyte composites prepared by self-assembly: transition between conductive and non-conductive states, Adv Mater, 8, 637, 10.1002/adma.19960080806 Geim, 2007, The rise of graphene, Nat Mater, 6, 183, 10.1038/nmat1849 Zhang, 2005, Experimental observation of the quantum hall effect and Berry's phase in graphene, Nature, 438, 201, 10.1038/nature04235 Kim, 2009, Large-scale pattern growth of graphene films for stretchable transparent electrodes, Nature, 457, 706, 10.1038/nature07719 Becerril, 2008, Evaluation of solution-processed reduced graphene oxide films as transparent conductors, ACS Nano, 2, 463, 10.1021/nn700375n Wu, 2010, Organic light-emitting diodes on solution-processed graphene transparent electrodes, ACS Nano, 4, 43, 10.1021/nn900728d Li, 2009, Electrochemiluminescence from tris(2,2′-bipyridyl)ruthenium(II)-graphene-nafion modified electrode, Talanta, 79, 165, 10.1016/j.talanta.2009.03.020 Wang, 2008, Transparent, conductive graphene electrodes for dye-sensitized solar cells, Nano Lett, 8, 323, 10.1021/nl072838r Rodolfo, 2009, Surfing ripples towards new devices, Nat Nanotechnol, 4, 549, 10.1038/nnano.2009.250 Liang, 2009, Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites, Adv Funct Mater, 19, 2297, 10.1002/adfm.200801776 Lee, 2008, Measurement of the elastic properties and intrinsic strength of monolayer graphene, Science, 321, 385, 10.1126/science.1157996 Balog, 2010, Bandgap opening in graphene induced by patterned hydrogen adsorption, Nat Mater, 9, 315, 10.1038/nmat2710 Zhao, 2009, Size and chirality dependent elastic properties of graphene nanoribbons under uniaxial tension, Nano Lett, 9, 3012, 10.1021/nl901448z Balandin, 2008, Superior thermal conductivity of single-layer graphene, Nano Lett, 8, 902, 10.1021/nl0731872 Scarpa1, 2009, Effective elastic mechanical properties of single layer graphene sheets, Nanotechnology, 20 Kudin, 2001, Oxygen-driven unzipping graphite materials, Phys Rev B, 64 Lier, 2000, Ab initio study of the elastic properties of single-walled carbon nanotubes and graphene, Chem Phys Lett, 326, 181, 10.1016/S0009-2614(00)00764-8 Robertson, 1992, Energetics of nanoscale graphitic tubules, Phys Rev B, 45, 12592, 10.1103/PhysRevB.45.12592 Brenner, 2002, A second-generation reactive empirical bond order (REBO) potential energy expression for hydrocarbons, J Phys Condens Matter, 14, 783, 10.1088/0953-8984/14/4/312 Park, 2009, Chemical methods for the production of graphenes, Nat Nanotechnol, 4, 217, 10.1038/nnano.2009.58 Li, 2007, Processable aqueous dispersions of graphene nanosheets, Nat Nanotechnol, 3, 101, 10.1038/nnano.2007.451 Yu, 2000, Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load, Science, 287, 637, 10.1126/science.287.5453.637 Li, 2005, Tensile properties of long alligned double-walled carbon nanotube, Carbon, 43, 31, 10.1016/j.carbon.2004.08.017 Yuen, 2007, Silane-modified MWCNT/PMMA composites-preparation, electrical resistivity, thermal conductivity and thermal stability, Compos Part A, 38, 2527, 10.1016/j.compositesa.2007.07.015 Itkis, 2007, Thermal conductivity measurements of semitransparent single-walled carbon nanotube films by a bolometric technique, Nano Lett, 7, 900, 10.1021/nl062689x Lewandowska, 2009, Structure and properties of nano-sized Eurofer 97 steel obtained by hydrostatic extrusion, J Nucl Mater, 386-8, 499, 10.1016/j.jnucmat.2008.12.166 Shin, 2007, Thermal property evolution of metal based thermal barrier coatings with heat treatments, J Mater Sci, 42, 5915, 10.1007/s10853-007-1772-x Chrissafisa, 2009, Thermal degradation mechanism of HDPE nanocomposites containing fumed silica nanoparticles, Thermochim Acta, 485, 65, 10.1016/j.tca.2008.12.011 Li, 2007, HDPE/expanded graphite nanocomposites prepared via masterbatch process, Polym Eng Sci, 47, 882, 10.1002/pen.20772 Woo, 1995, Melting behavior and thermal properties of high density polyethylene, Polym Eng Sci, 35, 151, 10.1002/pen.760350205 Sun, 2008, Preparation and properties of natural rubber nanocomposites with solid-state organomodified montmorillonite, J Appl Polym Sci, 107, 2786, 10.1002/app.26539 Matbase VOF. Natural rubber properties. http://www.matbase.com/material/polymers/elastomers/natural-rubber/properties. Accessed 2010. About.Com. Composites: Kevlar®. http://composite.about.com/od/aboutcompositesplastics/l/aa050597.htm. Accessed 2010. Ventura, 2009, Thermal conductivity of Kevlar 49 between 7 and 290K, Cryogenics, 49, 735, 10.1016/j.cryogenics.2009.08.001 Quan, 2009, Facile preparation and thermal degradation studies of graphite nanoplatelets (GNPs) filled thermoplastic polyurethane (TPU) nanocomposites, Compos Part A, 40, 1506, 10.1016/j.compositesa.2009.06.012 Eda, 2009, Graphene-based composite thin films for electronics, Nano Lett, 9, 814, 10.1021/nl8035367 Liang, 2009, Infrared-triggered actuators from graphene-based nanocomposites, J Phys Chem, 113, 9921 Kim, 2009, Processing–property relationships of polycarbonate/graphene nanocomposites, Polymer, 50, 3797, 10.1016/j.polymer.2009.05.038 Dikin, 2007, Preparation and characterization of graphene oxide paper, Nature, 448, 457, 10.1038/nature06016 Vickery, 2009, Fabrication of graphene-polymer nanocomposites with higher-order three-dimensional architectures, Adv Mater, 21, 2180, 10.1002/adma.200803606 McAllister, 2007, Single sheet functionalized graphene by oxidation and thermal expansion of graphite, Chem Mater, 19, 4396, 10.1021/cm0630800 Bourlinos, 2003, Graphite oxide: chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids, Chem Mater, 19, 6050 Stankovich, 2007, Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide, Carbon, 45, 1558, 10.1016/j.carbon.2007.02.034 Nethravathi, 2008, Graphite oxide-intercalated anionic clay and its decomposition to graphene-inorganic material nanocomposites, Langmuir, 24, 8240, 10.1021/la8000027 Szabo, 2005, Composite graphitic nanolayers prepared by self-assembly between finely dispersed graphite oxide and a cationic polymer, Carbon, 43, 87, 10.1016/j.carbon.2004.08.025 Neto, 2009, The electronic properties of graphene, Rev Mod Phys, 81, 109, 10.1103/RevModPhys.81.109 Neto, 2006, Drawing conclusions from graphene, Phys World, 19, 33, 10.1088/2058-7058/19/11/34 Wallace, 1947, The band theory of graphite, Phys Rev, 71, 622, 10.1103/PhysRev.71.622 Novoselov, 2004, Electric field effect in atomically thin carbon films, Science, 306, 666, 10.1126/science.1102896 Landau, 1980 Mermin, 1968, Crystalline order in two dimensions, Phys Rev, 176, 250, 10.1103/PhysRev.176.250 Eizenberg, 1979, Carbon monolayer phase condensation on Ni(III), Surf Sci, 82, 228, 10.1016/0039-6028(79)90330-3 Aizawa, 1990, Anomalous bond of monolayer graphite on transition metal carbide surfaces, Phys Rev Lett, 64, 768, 10.1103/PhysRevLett.64.768 Lu, 1990, Tailoring graphite with the goal of achieving single sheets, Nanotechnology, 10, 269, 10.1088/0957-4484/10/3/308 Berger, 2006, Electronic confinement and coherence in patterned epitaxial graphene, Science, 312, 1191, 10.1126/science.1125925 Reddy, 2006, Equilibrium configuration and continuum elastic properties of finite sized graphene, Nanotechnology, 17, 864, 10.1088/0957-4484/17/3/042 Boukhvalov, 2008, Hydrogen on graphene: electronic structure, total energy, structural distortions and magnetism from first-principles calculations, Phys Rev B, 77, 10.1103/PhysRevB.77.035427 Andres, 2008, Strong covalent bonding between two graphene layers, Phys Rev B, 77, 10.1103/PhysRevB.77.045403 Nemes-Incze, 2008, Anomalies in thickness measurements of graphene and few layer graphite crystals by tapping mode atomic force microscopy, Carbon, 46, 1435, 10.1016/j.carbon.2008.06.022 Geng, 2009, Preparation of graphite nanoplatelets and graphene sheets, J Colloid Interface Sci, 336, 592, 10.1016/j.jcis.2009.04.005 Wei, 2009, Preparation of graphene nanosheet/polymer composites using in situ reduction-extractive dispersion, Carbon, 47, 2290, 10.1016/j.carbon.2009.04.030 Bekyarova, 2009, Chemical modification of epitaxial graphene: spontaneous grafting of aryl groups, J Am Chem Soc, 131, 1336, 10.1021/ja8057327 Shan, 2009, Water soluble graphene covalently functionalized by biocompatible poly-l-lysine, Langmuir, 25, 12030, 10.1021/la903265p Schniepp, 2006, Functionalized single graphene sheets derived from splitting graphite oxide, J Phys Chem C, 110, 8535, 10.1021/jp060936f Bai, 2009, Non-covalent functionalization of graphene sheets by sulfonated polyaniline, Chem Commun, 1667, 10.1039/b821805f Salavagione, 2009, Polymeric modification of graphene through esterification of graphite oxide and poly(vinyl alcohol), Macromolecules, 42, 6331, 10.1021/ma900845w Stankovich, 2006, Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate), J Mater Chem, 16, 155, 10.1039/B512799H Worsley, 2007, Soluble graphene derived from graphite fluoride, Chem Phys Lett, 445, 51, 10.1016/j.cplett.2007.07.059 Niyogi, 2006, Solution properties of graphite and graphene, J Am Chem Soc, 128, 7720, 10.1021/ja060680r Stankovich, 2006, Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets, Carbon, 44, 3342, 10.1016/j.carbon.2006.06.004 Hummers, 1958, Preparation of graphitic oxide, J Am Chem Soc, 80, 1339, 10.1021/ja01539a017 Park, 2008, Aqueous suspension and characterization of chemically modified graphene sheets, Chem Mater, 20, 6592, 10.1021/cm801932u Lomeda, 2008, Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets, J Am Chem Soc, 130, 16201, 10.1021/ja806499w Zhang, 2009, Inorganic–organic hybrid porous materials based on graphite oxide sheets, Carbon, 47, 2993, 10.1016/j.carbon.2009.06.052 Xu, 2009, A graphene hybrid material covalently functionalized with porphyrin: synthesis and optical limiting property, Adv Mater, 21, 1275, 10.1002/adma.200801617 Hao, 2008, Aqueous dispersions of TCNQ-anion-stabilized graphene sheets, Chem Commun, 6576, 10.1039/b816971c Xu, 2008, Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets, J Am Chem Soc, 130, 5856, 10.1021/ja800745y Katz, 1994, Application of bifunctional reagents for immobilization of proteins on a carbon electrode surface: oriented immobilization of photosynthetic reaction centers, J Electroanal Chem, 365, 157, 10.1016/0022-0728(93)02975-N Jaegfeldt, 1983, Electrochemical stability of catechols with a pyrene side chain strongly adsorbed on graphite electrodes for catalytic oxidation of dihydronicotinamide adenine dinucleotide, J Am Chem Soc, 105, 1805, 10.1021/ja00345a021 Kovtyukhova, 1999, Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations, Chem Mater, 11, 771, 10.1021/cm981085u Berger, 2004, Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics, J Phys Chem B, 108, 19912, 10.1021/jp040650f Liu, 2010, Thermosensitive graphene nanocomposites formed using pyrene-terminal polymers made by RAFT polymerization, J Polym Sci Part A Polym Chem, 48, 425, 10.1002/pola.23802 Iroh, 1994, Electrochemical process for preparing continuous graphite fiber thermoplastic composites, Polymer, 35, 1306, 10.1016/0032-3861(94)90028-0 Xu, 2001, Thermal analysis of poly(vinyl alcohol)/graphite oxide intercalated composites, Polym Degrad Stab, 73, 29, 10.1016/S0141-3910(01)00046-5 Dub, 2004, Novel synthesis of conductive poly(arylene disulfide)/graphite nanocomposite, Synth Met, 143, 129, 10.1016/j.synthmet.2003.10.023 Yasmin, 2006, Processing of expanded graphite reinforced polymer nanocomposites, Compos Sci Technol, 66, 1182, 10.1016/j.compscitech.2005.10.014 Park, 2008, Electrodeposition of exfoliated graphite nanoplatelets onto carbon fibers and properties of their epoxy composites, Compos Sci Technol, 68, 1734, 10.1016/j.compscitech.2008.02.002 Li, 2007, Morphology and properties of UV/ozone treated graphite nanoplatelet/epoxy nanocomposites, Comp Sci Technol, 67, 296, 10.1016/j.compscitech.2006.08.009 Jovic, 2008, Temperature dependence of the electrical conductivity of epoxy/expanded graphite nanosheet composites, Scripta Mater, 58, 846, 10.1016/j.scriptamat.2007.12.041 Celzard, 1996, Composites based on micron-sized exfoliated graphite particles: electrical conduction, critical exponents and anisotropy, J Phys Chem Solids, 57, 715, 10.1016/0022-3697(95)00337-1 Li, 2007, Br treated graphite nanoplatelets for improved electrical conductivity of polymer composites, Carbon, 45, 744, 10.1016/j.carbon.2006.11.031 Yu, 2008, Enhanced thermal conductivity in a hybrid graphite nanoplatelet-carbon nanotube filler for epoxy composites, Adv Mater, 20, 4740, 10.1002/adma.200800401 Ganguli, 2008, Improved thermal conductivity for chemically functionalized exfoliated graphite/epoxy composites, Carbon, 46, 806, 10.1016/j.carbon.2008.02.008 Chen, 2003, Exfoliation of graphite flakes and its nanocomposites, Carbon, 41, 619, 10.1016/S0008-6223(02)00409-8 Chen, 2003, PMMA/graphite nanosheets composite and its conducting properties, Eur Polym J, 39, 2329, 10.1016/j.eurpolymj.2003.08.005 Zheng, 2003, Electrical conductivity and dielectric properties of PMMA/expanded graphite composites, Compos Sci Technol, 63, 225, 10.1016/S0266-3538(02)00201-4 Ramanathan, 2007, Graphitic nanofillers in PMMA nanocomposites-an investigation of particle size and dispersion and their influence on nanocomposite properties, J Polym Sci Part B Polym Phys, 45, 2097, 10.1002/polb.21187 Jang, 2009, Graphite oxide/poly(methyl methacrylate) nanocomposites prepared by a novel method utilizing macroazoinitiator, Compos Sci Technol, 69, 186, 10.1016/j.compscitech.2008.09.039 Wang, 2006, Synthesis and characteristics of poly(methyl methacrylate)/expanded graphite nanocomposites, J Appl Polym Sci, 100, 1427, 10.1002/app.23471 Ye, 2009, Synthesis and characterization of expandable graphite-poly(methyl methacrylate) composite particles and their application to flame retardation of rigid polyurethane foams, Polym Degrad Stab, 94, 971, 10.1016/j.polymdegradstab.2009.03.016 Zheng, 2002, Transport behavior of PMMA/expanded graphite nanocomposites, Polymer, 43, 6767, 10.1016/S0032-3861(02)00599-2 Kalaitzidou, 2007, A new compounding method for exfoliated graphite-polypropylene nanocomposites with enhanced flexural properties and lower percolation threshold, Compos Sci Technol, 67, 2045, 10.1016/j.compscitech.2006.11.014 Kalaitzidou, 2007, Mechanical properties and morphological characterization of exfoliated graphite-polypropylene nanocomposites, Compos Part A, 38, 1675, 10.1016/j.compositesa.2007.02.003 Kalaitzidou, 2007, Multifunctional polypropylene composites produced by incorporation of exfoliated graphite nanoplatelets, Carbon, 45, 1446, 10.1016/j.carbon.2007.03.029 Wakabayashi, 2008, Polymer-graphite nanocomposites: effective dispersion and major property enhancement via solid-state shear pulverization, Macromolecules, 41, 1905, 10.1021/ma071687b Chen, 2002, Novel electrically conductive polypropylene/graphite nanocomposites, J Mater Sci Lett, 21, 213, 10.1023/A:1014708808230 Gopakumar, 2004, Polypropylene/graphite nanocomposites by thermo-kinetic mixing, Polym Eng Sci, 44, 1162, 10.1002/pen.20109 Causin, 2006, Morphological and structural characterization of polypropylene/conductive graphite nanocomposites, Eur Polym J, 42, 3153, 10.1016/j.eurpolymj.2006.08.017 Kim, 2009, Multifunctional xGnP/LLDPE nanocomposites prepared by solution compounding using various screw rotating systems, Macromol Mater Eng, 294, 196, 10.1002/mame.200800319 Kim, 2010, Improvement of electric conductivity of LLDPE based nanocomposite by paraffin coating on exfoliated graphite nanoplatelets, Compos Part A, 41, 581, 10.1016/j.compositesa.2009.05.002 Kim, 2009, Thermal stability and dynamic mechanical behavior of exfoliated graphite nanoplatelets-LLDPE nanocomposites, Polym Compos, 31, 755, 10.1002/pc.20781 Zheng, 2004, Electrical and mechanical properties of expanded graphite-reinforced high-density polyethylene, J Appl Polym Sci, 91, 2781, 10.1002/app.13460 Zou, 2002, Conductive mechanism of polymer/graphite conducting composites with low percolation threshold, J Polym Sci Part B Polym Phys, 40, 954, 10.1002/polb.10141 Wanga, 2004, Preparation and characterization of polystyrene/graphite composite prepared by cationic grafting polymerization, Polymer, 45, 3987, 10.1016/j.polymer.2004.04.023 Xiao, 2002, Synthesis and properties of polystyrene/graphite nanocomposites, Polymer, 43, 2245, 10.1016/S0032-3861(02)00022-8 Kim, 2007, Electrical conductivity of graphite/polystyrene composites made from potassium intercalated graphite, Carbon, 45, 1578, 10.1016/j.carbon.2007.02.035 Xiao, 2001, Preparation of exfoliated graphite/polystyrene composite by polymerization-filling technique, Polymer, 42, 4813, 10.1016/S0032-3861(00)00819-3 Chen, 2003, Preparation of polystyrene/graphite nanosheet composites, Polymer, 44, 1781, 10.1016/S0032-3861(03)00050-8 Zhao, 2007, Preparation and properties of electrically conductive PPS/expanded graphite nanocomposites, Compos Sci Technol, 67, 2528, 10.1016/j.compscitech.2006.12.009 Pan, 2000, A new process of fabricating electrically conducting nylon 6/graphite nanocompositesvia intercalation polymerization, J Polym Sci Part B Polym Phys, 38, 1626, 10.1002/(SICI)1099-0488(20000615)38:12<1626::AID-POLB80>3.0.CO;2-R Weng, 2004, Fabrication and characterization of nylon 6/foliated graphite electrically conducting nanocomposite, J Polym Sci Part B Polym Phys, 42, 2842, 10.1002/polb.20140 Weng, 2005, Transport properties of electrically conducting nylon 6/foliated graphite nanocomposites, Polymer, 46, 6250, 10.1016/j.polymer.2005.05.071 Uhla, 2005, Expandable graphite/polyamide-6 nanocomposites, Polym Degrad Stab, 89, 70, 10.1016/j.polymdegradstab.2005.01.004 Scully, 2009, Decomposition kinetics of nylon-6/graphite and nylon-6/graphite oxide composites, Thermochim Acta, 490, 32, 10.1016/j.tca.2009.01.029 Weng, 2003, Crystallization kinetics and melting behaviors of nylon 6/foliated graphite nanocomposites, Polymer, 44, 8119, 10.1016/j.polymer.2003.10.028 Fukushima, 2006, Thermal conductivity of exfoliated graphite nanocomposites, J Therm Anal Calorim, 85, 235, 10.1007/s10973-005-7344-x Chen, 2004, Nonlinear conduction in nylon-6/foliated graphite nanocomposites above the percolation threshold, J Polym Sci Part B Polym Phys, 42, 155, 10.1002/polb.10682 Du, 2004, Facile synthesis of highly conductive polyaniline/graphite nanocomposites, Eur Polym J, 40, 1489, 10.1016/j.eurpolymj.2004.02.009 Du, 2004, Synthesis and characterization of polyaniline/graphite conducting nanocomposites, J Polym Sci Part B Polym Phys, 42, 1972, 10.1002/polb.20102 Cho, 2005, Dynamic mechanical and thermal properties of phenylethynyl-terminated polyimide composites reinforced with expanded graphite nanoplatelets, Macromol Mater Eng, 290, 179, 10.1002/mame.200400281 Mu, 2007, Thermal conductivity of graphite/silicone rubber prepared by solution intercalation, Thermochim Acta, 462, 70, 10.1016/j.tca.2007.06.006 Zhao, 2010, Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites, Macromolecules, 43, 2357, 10.1021/ma902862u Yu, 2007, Characterization of conductive multiwall carbon nanotube/polystyrene composites prepared by latex technology, Carbon, 45, 2897, 10.1016/j.carbon.2007.10.005 Lianga, 2009, Electromagnetic interference shielding of graphene/epoxy composites, Carbon, 47, 922, 10.1016/j.carbon.2008.12.038 Hu, 2010, Preparation and properties of graphene nanosheets-polystyrene nanocomposites via in situ emulsion polymerization, Chem Phys Lett, 484, 247, 10.1016/j.cplett.2009.11.024 Wang, 2009, Graphene oxide doped polyaniline for supercapacitors, Electrochem Commun, 11, 1158, 10.1016/j.elecom.2009.03.036 Yu, 2008, Morphology and properties of conducting polyvinyl alcohol hydrosulfate/graphite nanosheet composites, J Compos Mater, 42, 1491, 10.1177/0021998308092200 Zhang, 2010, Electrically conductive polyethylene terephthalate/graphene nanocomposites prepared by melt compounding, Polymer, 51, 1191, 10.1016/j.polymer.2010.01.027 Kornmann, X. Synthesis and characterization of thermoset-layered silicate nanocomposites. PhD thesis. Sweden: Lulea Tekniska Universitet; 2001. Moujahid, 2003, Poly(styrene sulfonate) layered double hydroxide nanocomposites Stability and subsequent structural transformation with changes in temperature, J Mater Chem, 13, 258, 10.1039/b208551h Hsueh, 2003, Preparation and properties of LDHs/polyimide nanocomposites, Polymer, 44, 1151, 10.1016/S0032-3861(02)00887-X Lee, 2007, Thermomechanical properties and crystallization behavior of layered double hydroxide/poly(ethylene terephthalate) nanocomposites prepared by in-situ polymerization, J Polym Sci Part B Polym Phys, 45, 28, 10.1002/polb.20993 Hussain, 2006, Review article: polymer–matrix nanocomposites, processing, manufacturing, and application: an overview, J Compos Mater, 40, 1511, 10.1177/0021998306067321 Shen, 2005, Polyethylene/grafted polyethylene/graphite nanocomposites: preparation, structure, and electrical properties, J Appl Polym Sci, 97, 51, 10.1002/app.21729 Hsueh, 2003, Preparation and properties of LDHs/epoxy nanocomposites, Polymer, 44, 5275, 10.1016/S0032-3861(03)00579-2 Zammarano, 2005, Preparation and flame resistance properties of revolutionary self-extinguishing epoxy nanocomposites based on layered double hydroxides, Polymer, 46, 9314, 10.1016/j.polymer.2005.07.050 Broza, 2007, Nanocomposites of poly(vinyl chloride) with carbon nanotubes (CNT), Compos Sci Technol, 67, 890, 10.1016/j.compscitech.2006.01.033 Kuilla, 2009, Rubber/LDH nanocomposites by solution blending, J Appl Polym Sci, 111, 635, 10.1002/app.29117 Wang, 2009, Thermal expansion of graphene composites, Macromolecules, 42, 5251, 10.1021/ma900631c Garboczi, 1995, Geometrical percolation-threshold of overlapping ellipsoids, Phys Rev E, 52, 819, 10.1103/PhysRevE.52.819 Peponi, 2009, Confinement of functionalized graphene sheets by triblock copolymers, J Phys Chem, 113, 17973 Wang, 2009, Fabrication of graphene/polyaniline composite paper via in situ anodic electropolymerization for high-performance flexible electrode, ACS Nano, 7, 1745, 10.1021/nn900297m Zhao, 2009, Polyaniline electrochromic devices with transparent graphene electrodes, Electrochim Acta, 55, 491, 10.1016/j.electacta.2009.08.063 Yan, 2010, Preparation of graphene nanosheet/carbon nanotube/polyaniline composite as electrode material for supercapacitors, J Power Sources, 195, 3041, 10.1016/j.jpowsour.2009.11.028 Wang, 2006, Ordered whiskerlike polyaniline grown on the surface of mesoporous carbon and its electrochemical capacitance performance, Adv Mater, 18, 2619, 10.1002/adma.200600445 Zhang, 2009, Influence of microstructure on the capacitive performance of polyaniline/carbon nanotube array composite electrodes, Electrochim Acta, 54, 1153, 10.1016/j.electacta.2008.09.004 Zhang, 2010, Graphene/polyaniline nanofiber composites as supercapacitor electrodes, Chem Mater, 22, 1392, 10.1021/cm902876u Bhadra S, Khstagir D, Singh AK, Lee JH. Progress in preparation, processing and applications of polyaniline. Prog Polym Sci 2009; 34:783–810. Halperin, 1985, Differences between lattice and continuum percolation transport exponents, Phys Rev Lett, 54, 2391, 10.1103/PhysRevLett.54.2391 Cussler, 1988, Barrier membrane, J Membr Sci, 38, 161, 10.1016/S0376-7388(00)80877-7